Sulfur-containing spirocyclic compounds based on 3-methyl-(amino)-1-phenylpyrazol-5-ones View Full Text


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Article Info

DATE

2000-02

AUTHORS

Yu. G. Shermolovich, S. V. Emets

ABSTRACT

3-Methyl(amino)-1-phenylpyrazol-5-ones react with N-chlorosulfenylphthalimide to give 4-phthalimidothiopyrazoles which decompose to form 3-methyl(amino)-1-phenylpyrazol-5-one-4-thiones. They were identified as their spirocyclic adducts with dienes. Oxidation of the latter with m-chloroperbenzoic acid gives spirocyclic sulfoxides and sulfones.

PAGES

152-156

References to SciGraph publications

  • 1990-03. MOPAC: A semiempirical molecular orbital program in JOURNAL OF COMPUTER-AIDED MOLECULAR DESIGN
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    http://scigraph.springernature.com/pub.10.1007/bf02283543

    DOI

    http://dx.doi.org/10.1007/bf02283543

    DIMENSIONS

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