Synthesis of heterocyclic derivatives of 3,6-di-tert-butyl-o-benzoquinone by catalytic dehydrocondensation with ethylene glycol, glycerol, and diethanolamine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2000-08

AUTHORS

T. I. Prokof'eva, V. B. Vol'eva, A. I. Prokof'ev, S. Belostotskaya, N. L. Komissarov, V. V. Ershov

ABSTRACT

The dehydrocondensation of 3,6-di-tert-butyl-o-benzoquinone with ethylene glycol, glycerol, its chlorhydrin, and with diethanolamine, catalyzed by MnO2−NaOH, has been carried out in an alcohol-DMF medium with the formation of 7,10-di-tert-butyl-2,5-dioxabicyclo[4.4.0]deca-1,6-diene-8.9-dione, its 4-hydroxymethyl and 4-chloromethyl derivatives, and 7,10-di-tert-butyl-5-(β-hydroxyethyl)-2-oxa-5-azabicyclo[4.4.0]deca-1,6-diene-8,9-dione.

PAGES

923-930

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02256976

DOI

http://dx.doi.org/10.1007/bf02256976

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012738835


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "familyName": "Prokof'eva", 
        "givenName": "T. I.", 
        "id": "sg:person.014725443103.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014725443103.31"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Vol'eva", 
        "givenName": "V. B.", 
        "id": "sg:person.014515631207.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014515631207.10"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Prokof'ev", 
        "givenName": "A. I.", 
        "id": "sg:person.014130062503.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014130062503.25"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Belostotskaya", 
        "givenName": "S.", 
        "id": "sg:person.015062760411.33", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015062760411.33"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Komissarov", 
        "givenName": "N. L.", 
        "id": "sg:person.015660341011.98", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015660341011.98"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Ershov", 
        "givenName": "V. V.", 
        "id": "sg:person.010414742241.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010414742241.10"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2000-08", 
    "datePublishedReg": "2000-08-01", 
    "description": "The dehydrocondensation of 3,6-di-tert-butyl-o-benzoquinone with ethylene glycol, glycerol, its chlorhydrin, and with diethanolamine, catalyzed by MnO2\u2212NaOH, has been carried out in an alcohol-DMF medium with the formation of 7,10-di-tert-butyl-2,5-dioxabicyclo[4.4.0]deca-1,6-diene-8.9-dione, its 4-hydroxymethyl and 4-chloromethyl derivatives, and 7,10-di-tert-butyl-5-(\u03b2-hydroxyethyl)-2-oxa-5-azabicyclo[4.4.0]deca-1,6-diene-8,9-dione.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf02256976", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1429545", 
        "issn": [
          "0132-6244", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "8", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "36"
      }
    ], 
    "keywords": [
      "OXA-5", 
      "heterocyclic derivatives", 
      "glycerol", 
      "chlorhydrin", 
      "derivatives", 
      "butyl-5", 
      "dione", 
      "glycol", 
      "ethylene glycol", 
      "medium", 
      "formation", 
      "synthesis", 
      "butyl", 
      "diene", 
      "benzoquinone", 
      "diethanolamine", 
      "dehydrocondensation", 
      "catalytic dehydrocondensation"
    ], 
    "name": "Synthesis of heterocyclic derivatives of 3,6-di-tert-butyl-o-benzoquinone by catalytic dehydrocondensation with ethylene glycol, glycerol, and diethanolamine", 
    "pagination": "923-930", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1012738835"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf02256976"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf02256976", 
      "https://app.dimensions.ai/details/publication/pub.1012738835"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-10T09:52", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220509/entities/gbq_results/article/article_340.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf02256976"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf02256976'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf02256976'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf02256976'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf02256976'


 

This table displays all metadata directly associated to this object as RDF triples.

102 TRIPLES      21 PREDICATES      44 URIs      36 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf02256976 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N2a4c4a4c87ad44788fb18c0947b90f01
4 schema:datePublished 2000-08
5 schema:datePublishedReg 2000-08-01
6 schema:description The dehydrocondensation of 3,6-di-tert-butyl-o-benzoquinone with ethylene glycol, glycerol, its chlorhydrin, and with diethanolamine, catalyzed by MnO2−NaOH, has been carried out in an alcohol-DMF medium with the formation of 7,10-di-tert-butyl-2,5-dioxabicyclo[4.4.0]deca-1,6-diene-8.9-dione, its 4-hydroxymethyl and 4-chloromethyl derivatives, and 7,10-di-tert-butyl-5-(β-hydroxyethyl)-2-oxa-5-azabicyclo[4.4.0]deca-1,6-diene-8,9-dione.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N735df441364e4bc294bb41f854c4eb8d
11 Ncf4cc7fb29494cc98262f151453ce37b
12 sg:journal.1429545
13 schema:keywords OXA-5
14 benzoquinone
15 butyl
16 butyl-5
17 catalytic dehydrocondensation
18 chlorhydrin
19 dehydrocondensation
20 derivatives
21 diene
22 diethanolamine
23 dione
24 ethylene glycol
25 formation
26 glycerol
27 glycol
28 heterocyclic derivatives
29 medium
30 synthesis
31 schema:name Synthesis of heterocyclic derivatives of 3,6-di-tert-butyl-o-benzoquinone by catalytic dehydrocondensation with ethylene glycol, glycerol, and diethanolamine
32 schema:pagination 923-930
33 schema:productId N5e0375ce14ff4453baac0a5b4897cde2
34 Nc9f84e008b3644ad95c6a7e21f700b36
35 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012738835
36 https://doi.org/10.1007/bf02256976
37 schema:sdDatePublished 2022-05-10T09:52
38 schema:sdLicense https://scigraph.springernature.com/explorer/license/
39 schema:sdPublisher Na1eb26f250ff4950969c984d801f5aa7
40 schema:url https://doi.org/10.1007/bf02256976
41 sgo:license sg:explorer/license/
42 sgo:sdDataset articles
43 rdf:type schema:ScholarlyArticle
44 N2670ab44ae314e769cf96c27bbaef45d rdf:first sg:person.010414742241.10
45 rdf:rest rdf:nil
46 N2a4c4a4c87ad44788fb18c0947b90f01 rdf:first sg:person.014725443103.31
47 rdf:rest N8edb0f8dd4624dc2b096b4299065a6f9
48 N5e0375ce14ff4453baac0a5b4897cde2 schema:name doi
49 schema:value 10.1007/bf02256976
50 rdf:type schema:PropertyValue
51 N735df441364e4bc294bb41f854c4eb8d schema:issueNumber 8
52 rdf:type schema:PublicationIssue
53 N8c4dc7a39d7f4f528875f491d9bdeb98 rdf:first sg:person.015660341011.98
54 rdf:rest N2670ab44ae314e769cf96c27bbaef45d
55 N8edb0f8dd4624dc2b096b4299065a6f9 rdf:first sg:person.014515631207.10
56 rdf:rest Nccde7c1adca94710aab4aad0ba78c1aa
57 Na1eb26f250ff4950969c984d801f5aa7 schema:name Springer Nature - SN SciGraph project
58 rdf:type schema:Organization
59 Nc9f84e008b3644ad95c6a7e21f700b36 schema:name dimensions_id
60 schema:value pub.1012738835
61 rdf:type schema:PropertyValue
62 Nccde7c1adca94710aab4aad0ba78c1aa rdf:first sg:person.014130062503.25
63 rdf:rest Nd13fd647d2d646bb9e1ea57aaadabdf1
64 Ncf4cc7fb29494cc98262f151453ce37b schema:volumeNumber 36
65 rdf:type schema:PublicationVolume
66 Nd13fd647d2d646bb9e1ea57aaadabdf1 rdf:first sg:person.015062760411.33
67 rdf:rest N8c4dc7a39d7f4f528875f491d9bdeb98
68 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
69 schema:name Chemical Sciences
70 rdf:type schema:DefinedTerm
71 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
72 schema:name Organic Chemistry
73 rdf:type schema:DefinedTerm
74 sg:journal.1429545 schema:issn 0132-6244
75 1573-8353
76 schema:name Chemistry of Heterocyclic Compounds
77 schema:publisher Springer Nature
78 rdf:type schema:Periodical
79 sg:person.010414742241.10 schema:familyName Ershov
80 schema:givenName V. V.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010414742241.10
82 rdf:type schema:Person
83 sg:person.014130062503.25 schema:familyName Prokof'ev
84 schema:givenName A. I.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014130062503.25
86 rdf:type schema:Person
87 sg:person.014515631207.10 schema:familyName Vol'eva
88 schema:givenName V. B.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014515631207.10
90 rdf:type schema:Person
91 sg:person.014725443103.31 schema:familyName Prokof'eva
92 schema:givenName T. I.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014725443103.31
94 rdf:type schema:Person
95 sg:person.015062760411.33 schema:familyName Belostotskaya
96 schema:givenName S.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015062760411.33
98 rdf:type schema:Person
99 sg:person.015660341011.98 schema:familyName Komissarov
100 schema:givenName N. L.
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015660341011.98
102 rdf:type schema:Person
 




Preview window. Press ESC to close (or click here)


...