Chemistry of furazano[3,4-b]pyrazine. 1. Synthesis and thermodynamic appraisal of 4,8-dihydrodifurazano[3,4-b,e]pyrazine and its derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1997-02

AUTHORS

I. B. Starchenkov, V. G. Andrianov, A. F. Mishnev

ABSTRACT

The thermodynamic stability of the antiaromatic 4,8-dihydrodifurazano[3,4-b,e]pyrazine (I) was studied by a quantum-chemical method. The molecular structure was investigated by x-ray crystallographic analysis, and the aromaticity index of the compound was calculated. It was shown that the oxidation or nitration of compound (I) leads to a stable aromatic radical.

PAGES

216-228

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02256764

DOI

http://dx.doi.org/10.1007/bf02256764

DIMENSIONS

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