Mössbauer spectroscopic and magnetic properties of iron/III/ pheophytins View Full Text


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Article Info

DATE

1989-05

AUTHORS

H. Hori, K. Kadono, H. Inoue, T. Shirai, E. Fluck

ABSTRACT

Mössbauer spectra of /pheophytinato a/ iron/III/ chloride [Fe/Pheo-a/Cl] and /pheophytinato b/ iron/III/ chloride [Fe/Pheo-b/Cl] have revealed that the central iron/III/ ion is in a high-spin state and axially coordinated by chloride ions in solid phase. Temperature-dependent asymmetry observed for the quadrupole splitting doublet of iron/III/ pheophytins, i.e., Fe/Pheo-a/Cl and Fe/Pheo-b/Cl, is interpreted on the basis of the zero-field splitting. The structural difference between iron/III/ pheophytins and iron/III/ porphyrins is reflected in the quadrupole splitting more than in the isomer shift. Magnetic behaviour of iron/III/ pheophytins near 4.2 K is very similar to that of iron/III/ porphyrins. More... »

PAGES

159-168

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02164106

DOI

http://dx.doi.org/10.1007/bf02164106

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041340732


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