Possibilities of two non-isothermal procedures (temperature- or rate-controlled) for kinetical studies View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1992-01

AUTHORS

J. Málek, J. šesták, F. Rouquerol, J. Rouquerol, J. M. Criado, A. Ortega

ABSTRACT

The applicability of both conventional Thermal Analysis (TA) and Controlled Rate Thermal Analysis (CRTA) for kinetic analysis is discussed. It is shown that TA method can give a reliable kinetic information and meaningful kinetic parameters especially for solid state transformation. On the other hand the CRTA method is more suitable for decomposition process where one or more gasses are evolved. A consistent and reliable method of kinetic analysis is proposed for both techniques. This method is illustrated to analyze the crystallization process of chalcogenide glass and the decomposition of dolomite. More... »

PAGES

71-87

References to SciGraph publications

  • 1983-05. Some suggestions for improving the utilization of the functiong(α) andp(x) to identify the mechanism of a thermal transformation in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1990-05. Kinetical possibilities of controlled transformation Rate Thermal Analysis (CRTA) in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1977-06. Rational approximations of the integral of the Arrhenius function in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1970-09. Kinetic analysis of derivative curves in thermal analysis in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
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    http://scigraph.springernature.com/pub.10.1007/bf02109109

    DOI

    http://dx.doi.org/10.1007/bf02109109

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