Far-infrared self-broadening and pressure shift measurements of methyl cyanide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-08

AUTHORS

G. W. Schwaab, K. M. Evenson, L. R. Zink

ABSTRACT

Pressure shifts and self-broadening parameters of the J=43←42, J=44←43, J=56←55 and J=68←67 sub-bands of the1A1 ground state of CH3C14N up to K=10 were determined using the NIST tunable far-infrared (TuFIR) spectrometer. The pressure shift agrees well with theoretical predictions made using Anderson-Tsao-Curnutte theory. The self-broadening parameter shows the expected K depencence. However, the predictions are systematically too large for decreasing J. The influence of the TuFIR power spectrum on the derived experimental parameters was evaluated and a comparison was made between two-wave and three-wave mixing spectroscopy. More... »

PAGES

1643-1655

References to SciGraph publications

  • 1988. Tunable Far Infrared Laser Spectroscopy in FRONTIERS OF LASER SPECTROSCOPY OF GASES
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02096222

    DOI

    http://dx.doi.org/10.1007/bf02096222

    DIMENSIONS

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