Mössbauer and susceptibility studies of FeMoVO7 View Full Text


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Article Info

DATE

1994-12

AUTHORS

G. F. Goya, R. C. Mercader, M. B. Vassallo, I. L. Botto, R. Sáez Puche

ABSTRACT

The oxidic phase FeMoVO7 of the Fe2O3-V2O5-MoO3 system has been synthesized. Susceptibility measurements from 4.2 K to room temperature display an antiferromagnetic behaviour with an effective magnetic moment of 5.80ώb. This value, and the measured Mössbauer isomer shift of 0.40±0.02 mm/s, are characteristic of high-spin Fe(III). The lowTn value of 15 K suggests a weak interaction among the Fe-O polyhedra. The relative small QS=0.28±0.02 mm/s found in this compound shows that the Fe-O polyhedra symmetry is close to octahedral and almost undistorted. More... »

PAGES

199-201

References to SciGraph publications

  • 1986-03. The FeVO4-MoO3 system in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf02074272

    DOI

    http://dx.doi.org/10.1007/bf02074272

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1003167242


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