1994-12
AUTHORSA. E. Goeta, G. F. Goya, R. C. Mercader, G. Punte, H. Falcón, R. Carbonio
ABSTRACTThe distributoin of oxidation states in perovskites of the type LaA1−xBxO3 (A and B transition metal ions) can be “tailored” byx variation. In paticular, in LaNiO3 it has been shown that Fe substitution for Ni foces some Ni3+ into Ni2+, while some Fe3+ changes into the unusual Fe4+ state. In addition, the existence of mixed oxidation states of Fe and/or Ni in LaNi1−xFexO3 has been related to its catalytic activity in hydrogen peroxide decomposition. The Fe4+ population, obtained using Mössbauer spectroscopy, was found to be constant for all the analyzed annealing temperatures forx=0.25 concentration, where the isomer shift difference for both states is the highest and the catalytic activity is maximum. More... »
PAGES371-375
http://scigraph.springernature.com/pub.10.1007/bf02069141
DOIhttp://dx.doi.org/10.1007/bf02069141
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