Crystal-field interpretation of the temperature dependence of the57Fe Mössbauer quadrupole splitting in two orthopyroxenes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1994-12

AUTHORS

A. Van Alboom, E. De Grave, R. E. Vandenberghe

ABSTRACT

The temperature dependences of the M2 and the M1 ferrous quadrupole splittings in two orthopyroxenes have been studied. The valence contributions to the EFG were calculated from the Boltzmann averages of the expectation values of the EFG components over the corresponding5D levels, while the lattice contributions were obtained from lattice summations. The proper5D level schemes were each determined by diagonalization of the full crystal-field Hamiltonian, for which the operator coefficients were calculated so as to take into account the real C1 symmetry of the FeO610− clusters. The calculations were based on the lattice and the charge data related to ferrosilite. More... »

PAGES

703-707

References to SciGraph publications

Journal

TITLE

Hyperfine Interactions

ISSUE

1

VOLUME

91

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02064594

DOI

http://dx.doi.org/10.1007/bf02064594

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032624427


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