Hyperfine interactions and site population in the spinel compounds CaxCo1−xFe2O4 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1994-12

AUTHORS

P. M. A. de Bakker, R. E. Vandenberghe, E. De Grave

ABSTRACT

Mössbauer spectra of the spinel series CaxCo1−xFe2O4, withx=0.0, 0.05 and 0.10, have been collected between 80 and 300 K and in an applied field of 6 T at 4.2 K. From the shape-independent hyperfine field distribution fits of the external field spectra, and from the binomial distribution fits of the temperature-dependent spectra, the hyperfine field and the center shift could be unambiguously assigned to octahedrally and tetrahedrally coordinated ferric ions. The importance of the application of an external field in conjunction with a reasonable physical model to obtain a correct assignment of hyperfine parameters to a specific site is demonstrated. More... »

PAGES

2023-2027

Journal

TITLE

Hyperfine Interactions

ISSUE

1

VOLUME

94

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf02063734

DOI

http://dx.doi.org/10.1007/bf02063734

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036363703


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