The determination of the gases released during heating of a flame retardant for polymers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1997-08

AUTHORS

J. Mullens, G. Reggers, M. Ruysen, R. Carleer, J. Yperman, D. Franco, L. C. Van Poucke

ABSTRACT

The oxidative degradation of HET-acid (1,4,5,6,7,7-hexachlorobicyclo [2.2.1] hept-5-en-2, 3-dicarboxylic acid) is studied by the combination of TG, FTIR, MS and GC-MS. The gases evolved during the decomposition of this flame retardant are investigated on-line by FTIR and by MS. Simultaneously the evolved gases are collected by an adsorbent and, after the thermal experiment, desorbed to release the volatile products for identification using GC-MS. The combination of these techniques offers the unambiguous identification of the evolved products as a function of temperature. The main identified products are CO2, H2O, Cl2, HCl, C2Cl4, maleic acid anhydride, HET-acid anhydride, chlorinated cyclic hydrocarbons and chlorinated unsaturated linear hydrocarbons. More... »

PAGES

1061-1067

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01996794

DOI

http://dx.doi.org/10.1007/bf01996794

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034484289


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