Molecular structure of [CpRu(PPh3)2(tht)]BF4, tht=tetrahydrothiophene View Full Text


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Article Info

DATE

1996-10

AUTHORS

Yanjing Jiang, M. Draganjac, A. W. Cordes

ABSTRACT

The title compound [CpRu(PPh3)2(tht)]BF4,1, tht=tetrahydrothiophene, is obtained by the reaction of CpRu(PPh3)2Cl, tht and AgBF4 in CH2Cl2 solution. Yellow crystals of [CpRu(PPh3)2(tht)]BF4 were grown by the slow diffusion of pentane into a CH2Cl2 solution of1 and have been studied by X-ray crystallography: space group is P21/n,a=9.507(2),b=18.336(3),c=22.372(6) Å, β=94.28(2)°,V=3889(1) Å3,Z=4. The tht ligand binds to the Ru atom through the sulfur atom at a distance of 2.395(2) Å. The tht ring is in the puckered configuration. More... »

PAGES

657-660

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01991960

DOI

http://dx.doi.org/10.1007/bf01991960

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043074480


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