The formation of the Ba(CuOx)1−y(CO3)y View Full Text


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Article Info

DATE

1996-07

AUTHORS

A. Tomasi, P. Scardi, F. C. Matacotta, P. Nozar

ABSTRACT

Carbocuprate compounds are generally described as multiple perovskites with CO32- and Cu-O alternating layers containing Ba and/or Sr; they have gained an unexpected importance in the high temperature superconductivity field, because many compounds with transition temperature above 100 K belong to this class of materials. We have started a systematic study on phase formation and stabilisation in the Ba-Cu-C-O system in the temperature range 20-600°C, by using thermal analysis techniques. Starting from a BaCO3-BaO2-CuO mixture (3∶1∶1 mol), a new phase isomorphic with BaCO3 formed after heat treatment above 390°C in air. TG, DSC, EGA and high temperature XRD were employed to follow the complex interaction of the reactants with the atmosphere and the formation of the new phase. More... »

PAGES

27-34

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01982683

DOI

http://dx.doi.org/10.1007/bf01982683

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1045570287


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