Isothermal melt crystallization kinetics of poly(L-lactic acid) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1996-10

AUTHORS

E. Urbanovici, H. A. Schneider, D. Brizzolara, H. J. Cantow

ABSTRACT

A DSC study was carried out of the isothermal melt crystallization kinetics of poly(L-lactic acid), PLLA, at 110, 115, 120, 125 and 130‡C. The experimental data were evaluated within the framework of the well-known Avrami kinetic model and an extended model involving an additional third kinetic parameter [8]. In order to perform the necessary numerical calculations, a number of functions built into the Mathematica® software system were used. The results showed that the isothermal melt crystallization kinetics of PLLA can be described adequately by both these kinetic models. It should also be stressed that the kinetic model of Urbanovici and Segal offers a better description of the experimental melt crystallization data of PLLA than the classical Avrami model. More... »

PAGES

931-939

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01979440

DOI

http://dx.doi.org/10.1007/bf01979440

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1023016612


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0403", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Geology", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/04", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Earth Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "name": [
            "Freiburger Materialforschungszentrum FMF and Institut f\u00fcr Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Urbanovici", 
        "givenName": "E.", 
        "id": "sg:person.015667360715.20", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015667360715.20"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Freiburger Materialforschungszentrum FMF and Institut f\u00fcr Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Schneider", 
        "givenName": "H. A.", 
        "id": "sg:person.013064167343.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013064167343.15"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Freiburger Materialforschungszentrum FMF and Institut f\u00fcr Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Brizzolara", 
        "givenName": "D.", 
        "id": "sg:person.016016420371.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016016420371.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Freiburger Materialforschungszentrum FMF and Institut f\u00fcr Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Cantow", 
        "givenName": "H. J.", 
        "id": "sg:person.016424175517.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016424175517.06"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf02548529", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005536168", 
          "https://doi.org/10.1007/bf02548529"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02548529", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005536168", 
          "https://doi.org/10.1007/bf02548529"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pol.1984.180220401", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006957378"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1351/pac198961040769", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011511200"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(80)90315-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027793552"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(80)90315-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027793552"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0040-6031(93)80252-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030110043"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02546633", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032907045", 
          "https://doi.org/10.1007/bf02546633"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(83)90129-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034290350"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(83)90129-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034290350"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01498927", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1036949714", 
          "https://doi.org/10.1007/bf01498927"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0040-6031(90)87010-a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037508751"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(95)93647-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037925576"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/app.1991.070430109", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051111580"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1696442", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057767658"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1750380", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057812375"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1996-10", 
    "datePublishedReg": "1996-10-01", 
    "description": "A DSC study was carried out of the isothermal melt crystallization kinetics of poly(L-lactic acid), PLLA, at 110, 115, 120, 125 and 130\u2021C. The experimental data were evaluated within the framework of the well-known Avrami kinetic model and an extended model involving an additional third kinetic parameter [8]. In order to perform the necessary numerical calculations, a number of functions built into the Mathematica\u00ae software system were used. The results showed that the isothermal melt crystallization kinetics of PLLA can be described adequately by both these kinetic models. It should also be stressed that the kinetic model of Urbanovici and Segal offers a better description of the experimental melt crystallization data of PLLA than the classical Avrami model.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf01979440", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294862", 
        "issn": [
          "1388-6150", 
          "1572-8943"
        ], 
        "name": "Journal of Thermal Analysis and Calorimetry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "47"
      }
    ], 
    "name": "Isothermal melt crystallization kinetics of poly(L-lactic acid)", 
    "pagination": "931-939", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "6da7ffac9bc8186d3396b034ca4dca0b261976d4466aeb3fc2bed20cb39ae192"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01979440"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1023016612"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01979440", 
      "https://app.dimensions.ai/details/publication/pub.1023016612"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T11:23", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000355_0000000355/records_52991_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/BF01979440"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01979440'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01979440'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01979440'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01979440'


 

This table displays all metadata directly associated to this object as RDF triples.

129 TRIPLES      21 PREDICATES      40 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01979440 schema:about anzsrc-for:04
2 anzsrc-for:0403
3 schema:author N21857e91c99b404598e6e9ca9232183b
4 schema:citation sg:pub.10.1007/bf01498927
5 sg:pub.10.1007/bf02546633
6 sg:pub.10.1007/bf02548529
7 https://doi.org/10.1002/app.1991.070430109
8 https://doi.org/10.1002/pol.1984.180220401
9 https://doi.org/10.1016/0032-3861(80)90315-8
10 https://doi.org/10.1016/0032-3861(83)90129-5
11 https://doi.org/10.1016/0032-3861(95)93647-5
12 https://doi.org/10.1016/0040-6031(90)87010-a
13 https://doi.org/10.1016/0040-6031(93)80252-6
14 https://doi.org/10.1063/1.1696442
15 https://doi.org/10.1063/1.1750380
16 https://doi.org/10.1351/pac198961040769
17 schema:datePublished 1996-10
18 schema:datePublishedReg 1996-10-01
19 schema:description A DSC study was carried out of the isothermal melt crystallization kinetics of poly(L-lactic acid), PLLA, at 110, 115, 120, 125 and 130‡C. The experimental data were evaluated within the framework of the well-known Avrami kinetic model and an extended model involving an additional third kinetic parameter [8]. In order to perform the necessary numerical calculations, a number of functions built into the Mathematica® software system were used. The results showed that the isothermal melt crystallization kinetics of PLLA can be described adequately by both these kinetic models. It should also be stressed that the kinetic model of Urbanovici and Segal offers a better description of the experimental melt crystallization data of PLLA than the classical Avrami model.
20 schema:genre research_article
21 schema:inLanguage en
22 schema:isAccessibleForFree false
23 schema:isPartOf Nc2e0f495891a4db3bc6c614ed70c436e
24 Nf6f3150b75b24cd3b20cf5ce03ece5db
25 sg:journal.1294862
26 schema:name Isothermal melt crystallization kinetics of poly(L-lactic acid)
27 schema:pagination 931-939
28 schema:productId N61b75a8b7d524d389d3dfde78c7a287f
29 N634e31ff641247249a31ac031e60a946
30 N641e156c9528489e9b1bfbd4d80c677f
31 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023016612
32 https://doi.org/10.1007/bf01979440
33 schema:sdDatePublished 2019-04-11T11:23
34 schema:sdLicense https://scigraph.springernature.com/explorer/license/
35 schema:sdPublisher Ndba42f621ed14d039bdeea0bbceda033
36 schema:url http://link.springer.com/10.1007/BF01979440
37 sgo:license sg:explorer/license/
38 sgo:sdDataset articles
39 rdf:type schema:ScholarlyArticle
40 N21857e91c99b404598e6e9ca9232183b rdf:first sg:person.015667360715.20
41 rdf:rest N2982838705864992abf9f338e67fdc90
42 N2982838705864992abf9f338e67fdc90 rdf:first sg:person.013064167343.15
43 rdf:rest Nfa4f2e1e16fe411c927509c47a3585e5
44 N61b75a8b7d524d389d3dfde78c7a287f schema:name readcube_id
45 schema:value 6da7ffac9bc8186d3396b034ca4dca0b261976d4466aeb3fc2bed20cb39ae192
46 rdf:type schema:PropertyValue
47 N634e31ff641247249a31ac031e60a946 schema:name doi
48 schema:value 10.1007/bf01979440
49 rdf:type schema:PropertyValue
50 N641e156c9528489e9b1bfbd4d80c677f schema:name dimensions_id
51 schema:value pub.1023016612
52 rdf:type schema:PropertyValue
53 N75ceefd82c2d4551a1ec461852e6c2ff schema:name Freiburger Materialforschungszentrum FMF and Institut für Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany
54 rdf:type schema:Organization
55 N926e9545cd2a43a5a04757e2ad0d5698 schema:name Freiburger Materialforschungszentrum FMF and Institut für Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany
56 rdf:type schema:Organization
57 Nbbb275ca1575487ea7d72a44dd6a167d schema:name Freiburger Materialforschungszentrum FMF and Institut für Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany
58 rdf:type schema:Organization
59 Nc2e0f495891a4db3bc6c614ed70c436e schema:volumeNumber 47
60 rdf:type schema:PublicationVolume
61 Ndba42f621ed14d039bdeea0bbceda033 schema:name Springer Nature - SN SciGraph project
62 rdf:type schema:Organization
63 Ndf6f528bcda7456ab96d4f40b3e038f0 schema:name Freiburger Materialforschungszentrum FMF and Institut für Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany
64 rdf:type schema:Organization
65 Nf533efccd3854306a58bfcd5e83217ac rdf:first sg:person.016424175517.06
66 rdf:rest rdf:nil
67 Nf6f3150b75b24cd3b20cf5ce03ece5db schema:issueNumber 4
68 rdf:type schema:PublicationIssue
69 Nfa4f2e1e16fe411c927509c47a3585e5 rdf:first sg:person.016016420371.48
70 rdf:rest Nf533efccd3854306a58bfcd5e83217ac
71 anzsrc-for:04 schema:inDefinedTermSet anzsrc-for:
72 schema:name Earth Sciences
73 rdf:type schema:DefinedTerm
74 anzsrc-for:0403 schema:inDefinedTermSet anzsrc-for:
75 schema:name Geology
76 rdf:type schema:DefinedTerm
77 sg:journal.1294862 schema:issn 1388-6150
78 1572-8943
79 schema:name Journal of Thermal Analysis and Calorimetry
80 rdf:type schema:Periodical
81 sg:person.013064167343.15 schema:affiliation N75ceefd82c2d4551a1ec461852e6c2ff
82 schema:familyName Schneider
83 schema:givenName H. A.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013064167343.15
85 rdf:type schema:Person
86 sg:person.015667360715.20 schema:affiliation Nbbb275ca1575487ea7d72a44dd6a167d
87 schema:familyName Urbanovici
88 schema:givenName E.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015667360715.20
90 rdf:type schema:Person
91 sg:person.016016420371.48 schema:affiliation N926e9545cd2a43a5a04757e2ad0d5698
92 schema:familyName Brizzolara
93 schema:givenName D.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016016420371.48
95 rdf:type schema:Person
96 sg:person.016424175517.06 schema:affiliation Ndf6f528bcda7456ab96d4f40b3e038f0
97 schema:familyName Cantow
98 schema:givenName H. J.
99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016424175517.06
100 rdf:type schema:Person
101 sg:pub.10.1007/bf01498927 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036949714
102 https://doi.org/10.1007/bf01498927
103 rdf:type schema:CreativeWork
104 sg:pub.10.1007/bf02546633 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032907045
105 https://doi.org/10.1007/bf02546633
106 rdf:type schema:CreativeWork
107 sg:pub.10.1007/bf02548529 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005536168
108 https://doi.org/10.1007/bf02548529
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1002/app.1991.070430109 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051111580
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1002/pol.1984.180220401 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006957378
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1016/0032-3861(80)90315-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027793552
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1016/0032-3861(83)90129-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034290350
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1016/0032-3861(95)93647-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037925576
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1016/0040-6031(90)87010-a schema:sameAs https://app.dimensions.ai/details/publication/pub.1037508751
121 rdf:type schema:CreativeWork
122 https://doi.org/10.1016/0040-6031(93)80252-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030110043
123 rdf:type schema:CreativeWork
124 https://doi.org/10.1063/1.1696442 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057767658
125 rdf:type schema:CreativeWork
126 https://doi.org/10.1063/1.1750380 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057812375
127 rdf:type schema:CreativeWork
128 https://doi.org/10.1351/pac198961040769 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011511200
129 rdf:type schema:CreativeWork
 




Preview window. Press ESC to close (or click here)


...