Isothermal melt crystallization kinetics of poly(L-lactic acid) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1996-10

AUTHORS

E. Urbanovici, H. A. Schneider, D. Brizzolara, H. J. Cantow

ABSTRACT

A DSC study was carried out of the isothermal melt crystallization kinetics of poly(L-lactic acid), PLLA, at 110, 115, 120, 125 and 130‡C. The experimental data were evaluated within the framework of the well-known Avrami kinetic model and an extended model involving an additional third kinetic parameter [8]. In order to perform the necessary numerical calculations, a number of functions built into the Mathematica® software system were used. The results showed that the isothermal melt crystallization kinetics of PLLA can be described adequately by both these kinetic models. It should also be stressed that the kinetic model of Urbanovici and Segal offers a better description of the experimental melt crystallization data of PLLA than the classical Avrami model. More... »

PAGES

931-939

References to SciGraph publications

  • 1993-08. Polymer crystallization in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1973-11. Investigation of the structure of solution grown crystals of lactide copolymers by means of chemical reactions in COLLOID AND POLYMER SCIENCE
  • 1994-08. Dual-mechanism kinetics of polyphenylene sulfide (PPS) melt-crystallization in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf01979440

    DOI

    http://dx.doi.org/10.1007/bf01979440

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1023016612


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0403", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Geology", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/04", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Earth Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "name": [
                "Freiburger Materialforschungszentrum FMF and Institut f\u00fcr Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Urbanovici", 
            "givenName": "E.", 
            "id": "sg:person.015667360715.20", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015667360715.20"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "name": [
                "Freiburger Materialforschungszentrum FMF and Institut f\u00fcr Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Schneider", 
            "givenName": "H. A.", 
            "id": "sg:person.013064167343.15", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013064167343.15"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "name": [
                "Freiburger Materialforschungszentrum FMF and Institut f\u00fcr Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Brizzolara", 
            "givenName": "D.", 
            "id": "sg:person.016016420371.48", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016016420371.48"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "name": [
                "Freiburger Materialforschungszentrum FMF and Institut f\u00fcr Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Cantow", 
            "givenName": "H. J.", 
            "id": "sg:person.016424175517.06", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016424175517.06"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/bf02548529", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005536168", 
              "https://doi.org/10.1007/bf02548529"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02548529", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005536168", 
              "https://doi.org/10.1007/bf02548529"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/pol.1984.180220401", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1006957378"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1351/pac198961040769", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1011511200"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0032-3861(80)90315-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1027793552"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0032-3861(80)90315-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1027793552"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0040-6031(93)80252-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1030110043"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02546633", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1032907045", 
              "https://doi.org/10.1007/bf02546633"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0032-3861(83)90129-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034290350"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0032-3861(83)90129-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034290350"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf01498927", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1036949714", 
              "https://doi.org/10.1007/bf01498927"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0040-6031(90)87010-a", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1037508751"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0032-3861(95)93647-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1037925576"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/app.1991.070430109", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1051111580"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1063/1.1696442", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1057767658"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1063/1.1750380", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1057812375"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "1996-10", 
        "datePublishedReg": "1996-10-01", 
        "description": "A DSC study was carried out of the isothermal melt crystallization kinetics of poly(L-lactic acid), PLLA, at 110, 115, 120, 125 and 130\u2021C. The experimental data were evaluated within the framework of the well-known Avrami kinetic model and an extended model involving an additional third kinetic parameter [8]. In order to perform the necessary numerical calculations, a number of functions built into the Mathematica\u00ae software system were used. The results showed that the isothermal melt crystallization kinetics of PLLA can be described adequately by both these kinetic models. It should also be stressed that the kinetic model of Urbanovici and Segal offers a better description of the experimental melt crystallization data of PLLA than the classical Avrami model.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1007/bf01979440", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1294862", 
            "issn": [
              "1388-6150", 
              "1572-8943"
            ], 
            "name": "Journal of Thermal Analysis and Calorimetry", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "4", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "47"
          }
        ], 
        "name": "Isothermal melt crystallization kinetics of poly(L-lactic acid)", 
        "pagination": "931-939", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "6da7ffac9bc8186d3396b034ca4dca0b261976d4466aeb3fc2bed20cb39ae192"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/bf01979440"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1023016612"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/bf01979440", 
          "https://app.dimensions.ai/details/publication/pub.1023016612"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-11T11:23", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000355_0000000355/records_52991_00000000.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1007/BF01979440"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01979440'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01979440'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01979440'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01979440'


     

    This table displays all metadata directly associated to this object as RDF triples.

    129 TRIPLES      21 PREDICATES      40 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/bf01979440 schema:about anzsrc-for:04
    2 anzsrc-for:0403
    3 schema:author Nd396bd3fab7c4e7f805680d143982a2e
    4 schema:citation sg:pub.10.1007/bf01498927
    5 sg:pub.10.1007/bf02546633
    6 sg:pub.10.1007/bf02548529
    7 https://doi.org/10.1002/app.1991.070430109
    8 https://doi.org/10.1002/pol.1984.180220401
    9 https://doi.org/10.1016/0032-3861(80)90315-8
    10 https://doi.org/10.1016/0032-3861(83)90129-5
    11 https://doi.org/10.1016/0032-3861(95)93647-5
    12 https://doi.org/10.1016/0040-6031(90)87010-a
    13 https://doi.org/10.1016/0040-6031(93)80252-6
    14 https://doi.org/10.1063/1.1696442
    15 https://doi.org/10.1063/1.1750380
    16 https://doi.org/10.1351/pac198961040769
    17 schema:datePublished 1996-10
    18 schema:datePublishedReg 1996-10-01
    19 schema:description A DSC study was carried out of the isothermal melt crystallization kinetics of poly(L-lactic acid), PLLA, at 110, 115, 120, 125 and 130‡C. The experimental data were evaluated within the framework of the well-known Avrami kinetic model and an extended model involving an additional third kinetic parameter [8]. In order to perform the necessary numerical calculations, a number of functions built into the Mathematica® software system were used. The results showed that the isothermal melt crystallization kinetics of PLLA can be described adequately by both these kinetic models. It should also be stressed that the kinetic model of Urbanovici and Segal offers a better description of the experimental melt crystallization data of PLLA than the classical Avrami model.
    20 schema:genre research_article
    21 schema:inLanguage en
    22 schema:isAccessibleForFree false
    23 schema:isPartOf N564c8bcc7a8c4fa6be397cc29d2dd5a4
    24 N6665a585349a40e3b101656f6437f588
    25 sg:journal.1294862
    26 schema:name Isothermal melt crystallization kinetics of poly(L-lactic acid)
    27 schema:pagination 931-939
    28 schema:productId N49b3b14fa0774382969be0bbe0fbad55
    29 Na48e682c00484b2aa06d2e43c3107b71
    30 Nd1fab57e36124367b235d71dfe1ec42d
    31 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023016612
    32 https://doi.org/10.1007/bf01979440
    33 schema:sdDatePublished 2019-04-11T11:23
    34 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    35 schema:sdPublisher Nae4199417bda4f4b88fb173829c6515f
    36 schema:url http://link.springer.com/10.1007/BF01979440
    37 sgo:license sg:explorer/license/
    38 sgo:sdDataset articles
    39 rdf:type schema:ScholarlyArticle
    40 N49b3b14fa0774382969be0bbe0fbad55 schema:name dimensions_id
    41 schema:value pub.1023016612
    42 rdf:type schema:PropertyValue
    43 N514c1641d2d8497a843c2cb8becfc93a rdf:first sg:person.016016420371.48
    44 rdf:rest Nd389447d34cd496f8aeb4d429f6b3375
    45 N564c8bcc7a8c4fa6be397cc29d2dd5a4 schema:issueNumber 4
    46 rdf:type schema:PublicationIssue
    47 N64550357be6f489b965060b1e19a1e02 schema:name Freiburger Materialforschungszentrum FMF and Institut für Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany
    48 rdf:type schema:Organization
    49 N6665a585349a40e3b101656f6437f588 schema:volumeNumber 47
    50 rdf:type schema:PublicationVolume
    51 N8d9dd7d32c2644cbab83340942efcaf6 rdf:first sg:person.013064167343.15
    52 rdf:rest N514c1641d2d8497a843c2cb8becfc93a
    53 N9226eb9d98ba449e96ff5b8244350adf schema:name Freiburger Materialforschungszentrum FMF and Institut für Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany
    54 rdf:type schema:Organization
    55 Na48e682c00484b2aa06d2e43c3107b71 schema:name doi
    56 schema:value 10.1007/bf01979440
    57 rdf:type schema:PropertyValue
    58 Nae4199417bda4f4b88fb173829c6515f schema:name Springer Nature - SN SciGraph project
    59 rdf:type schema:Organization
    60 Nd1fab57e36124367b235d71dfe1ec42d schema:name readcube_id
    61 schema:value 6da7ffac9bc8186d3396b034ca4dca0b261976d4466aeb3fc2bed20cb39ae192
    62 rdf:type schema:PropertyValue
    63 Nd389447d34cd496f8aeb4d429f6b3375 rdf:first sg:person.016424175517.06
    64 rdf:rest rdf:nil
    65 Nd396bd3fab7c4e7f805680d143982a2e rdf:first sg:person.015667360715.20
    66 rdf:rest N8d9dd7d32c2644cbab83340942efcaf6
    67 Nf5183ed358044957bd0936c483ac43cf schema:name Freiburger Materialforschungszentrum FMF and Institut für Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany
    68 rdf:type schema:Organization
    69 Nfbb4a741ab8a45069732afec5eacc8fb schema:name Freiburger Materialforschungszentrum FMF and Institut für Makromolekulare Chemie of the University, Stefan-Meier-Str. 21, D-79104, Freiburg, Germany
    70 rdf:type schema:Organization
    71 anzsrc-for:04 schema:inDefinedTermSet anzsrc-for:
    72 schema:name Earth Sciences
    73 rdf:type schema:DefinedTerm
    74 anzsrc-for:0403 schema:inDefinedTermSet anzsrc-for:
    75 schema:name Geology
    76 rdf:type schema:DefinedTerm
    77 sg:journal.1294862 schema:issn 1388-6150
    78 1572-8943
    79 schema:name Journal of Thermal Analysis and Calorimetry
    80 rdf:type schema:Periodical
    81 sg:person.013064167343.15 schema:affiliation N9226eb9d98ba449e96ff5b8244350adf
    82 schema:familyName Schneider
    83 schema:givenName H. A.
    84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013064167343.15
    85 rdf:type schema:Person
    86 sg:person.015667360715.20 schema:affiliation Nfbb4a741ab8a45069732afec5eacc8fb
    87 schema:familyName Urbanovici
    88 schema:givenName E.
    89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015667360715.20
    90 rdf:type schema:Person
    91 sg:person.016016420371.48 schema:affiliation Nf5183ed358044957bd0936c483ac43cf
    92 schema:familyName Brizzolara
    93 schema:givenName D.
    94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016016420371.48
    95 rdf:type schema:Person
    96 sg:person.016424175517.06 schema:affiliation N64550357be6f489b965060b1e19a1e02
    97 schema:familyName Cantow
    98 schema:givenName H. J.
    99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016424175517.06
    100 rdf:type schema:Person
    101 sg:pub.10.1007/bf01498927 schema:sameAs https://app.dimensions.ai/details/publication/pub.1036949714
    102 https://doi.org/10.1007/bf01498927
    103 rdf:type schema:CreativeWork
    104 sg:pub.10.1007/bf02546633 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032907045
    105 https://doi.org/10.1007/bf02546633
    106 rdf:type schema:CreativeWork
    107 sg:pub.10.1007/bf02548529 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005536168
    108 https://doi.org/10.1007/bf02548529
    109 rdf:type schema:CreativeWork
    110 https://doi.org/10.1002/app.1991.070430109 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051111580
    111 rdf:type schema:CreativeWork
    112 https://doi.org/10.1002/pol.1984.180220401 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006957378
    113 rdf:type schema:CreativeWork
    114 https://doi.org/10.1016/0032-3861(80)90315-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027793552
    115 rdf:type schema:CreativeWork
    116 https://doi.org/10.1016/0032-3861(83)90129-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034290350
    117 rdf:type schema:CreativeWork
    118 https://doi.org/10.1016/0032-3861(95)93647-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037925576
    119 rdf:type schema:CreativeWork
    120 https://doi.org/10.1016/0040-6031(90)87010-a schema:sameAs https://app.dimensions.ai/details/publication/pub.1037508751
    121 rdf:type schema:CreativeWork
    122 https://doi.org/10.1016/0040-6031(93)80252-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030110043
    123 rdf:type schema:CreativeWork
    124 https://doi.org/10.1063/1.1696442 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057767658
    125 rdf:type schema:CreativeWork
    126 https://doi.org/10.1063/1.1750380 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057812375
    127 rdf:type schema:CreativeWork
    128 https://doi.org/10.1351/pac198961040769 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011511200
    129 rdf:type schema:CreativeWork
     




    Preview window. Press ESC to close (or click here)


    ...