Synthesis, redox properties, and X-ray diffraction structure of the platinum catecholate complex Pt(1,5-COD)(1,2-O2C6H4) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1996-05

AUTHORS

Ming-Jaw Don, Kaiyuan Yang, Simon G. Bott, Michael G. Richmond

ABSTRACT

The new compound Pt(1,5-COD)(1,2-O2C6H4)(1) (where COD=cyclooctadiene) has been prepared from the reaction between Pt(1,5-COD)Cl2 and the disodium salt of catechol. Pt(1,5-COD)(1,2-O2C6H4) has been isolated and structurally characterized by X-ray diffraction analysis, which confirms the monomeric nature of this compound and the chelating mode adopted by the ancillary 1,5-COD and catecholate ligands. Pt(1,5-COD)(1,2-O2C6H4) crystallized in the monoclinic space groupP21/n,a=10.208(1) Å,b=10.3829(8) Å,c=11.473(2) Å, β=103.817(9)°,V=1180.9(2) Å3,Z=4,dcalc=2.314 g·cm−3;R=0.0307,Rw=0.0445 for 1216 observed reflections withI>3σ(I). Cyclic voltammetric studies on1 reveal an irreversible oxidation (Epa=0.78 V) and an irreversible reduction (Epc=−1.99 V) in CH2Cl2 solution. The nature of the HOMO and LUMO in Pt(1,5-COD)(1,2-O2C6H4) was examined by using the model compound Pt(ethylene)2(1,2-O2C6H4), with the results discussed relative to compound1. More... »

PAGES

335-340

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01677097

DOI

http://dx.doi.org/10.1007/bf01677097

DIMENSIONS

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