Crystal and molecular structure of potassium 2-amino-6-sulfinato-purine monohydrate View Full Text


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Article Info

DATE

1995-08

AUTHORS

Ernst Horn, Edward R. T. Tiekink

ABSTRACT

The crystal and molecular structure of the title compound, K[C5H4N5O2S]H2O, has been determined at room temperature. The structure determination reveals that the negative charge on the anion is localised on the sulfinate group which results in significant rearrangement of π-electron density within the purine ring. The K+ cation exists in a N3O4 donor set which defines a distorted trigonal prismatic geometry. Crystals of K[C5H4N5O2S]H2O are triclinic with space group and unit cell dimensionsa=8.248(2),b=8.710(2),c=6.988(6) Å, α=99.87(4), β=102.84(5), and γ=78.35(2)°,Z=2. More... »

PAGES

459-462

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01665701

DOI

http://dx.doi.org/10.1007/bf01665701

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018975285


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