On the reaction of 2-aminopropionitrile in aqueous media View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-06

AUTHORS

Katsuhiro Kawashiro, Shigeaki Seno, Shigeru Sugiyama, Hiromu Hayashi

ABSTRACT

The reactions of 2- and 3-aminopropionitrile (APN), and 2,2′-iminodipropionitrile (IDPN) were carried out in aqueous ammoniacal media. 2-APN was found to give IDPN, N-(1-cyanoethyl)alanine amide, N-(1-cyanoethyl)alanine, N-(1-carbamoylethyl)alanine, 2,2′-iminodipropionic acid, alanine amide, and alanine. Compounds of biological significance such as peptides and amino acids other than alanine were not formed. The results were well consistent with those obtained for aminoacetonitrile. IDPN which can be formed easily from 2-APN in aqueous media, also yielded the same products as with 2-APN. On the other hand, 3-APN gave 3-alanine via 3-alanine amide under similar conditions. 3-APN was found to be more stable than 2-APN in aqueous media. More... »

PAGES

153-165

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01581835

DOI

http://dx.doi.org/10.1007/bf01581835

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032022420


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of Tokushima", 
          "id": "https://www.grid.ac/institutes/grid.267335.6", 
          "name": [
            "Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima, Minamijosanjima, 770, Tokushima, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kawashiro", 
        "givenName": "Katsuhiro", 
        "id": "sg:person.07511302563.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07511302563.25"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Tokushima", 
          "id": "https://www.grid.ac/institutes/grid.267335.6", 
          "name": [
            "Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima, Minamijosanjima, 770, Tokushima, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Seno", 
        "givenName": "Shigeaki", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Tokushima", 
          "id": "https://www.grid.ac/institutes/grid.267335.6", 
          "name": [
            "Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima, Minamijosanjima, 770, Tokushima, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sugiyama", 
        "givenName": "Shigeru", 
        "id": "sg:person.015541720521.46", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015541720521.46"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Tokushima", 
          "id": "https://www.grid.ac/institutes/grid.267335.6", 
          "name": [
            "Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima, Minamijosanjima, 770, Tokushima, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hayashi", 
        "givenName": "Hiromu", 
        "id": "sg:person.015535641115.24", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015535641115.24"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0045-2068(71)90020-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000759431"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-5193(72)90044-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007621394"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01808147", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011274175", 
          "https://doi.org/10.1007/bf01808147"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01808147", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011274175", 
          "https://doi.org/10.1007/bf01808147"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4020(01)99315-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017783622"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0303-2647(67)90031-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019611351"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0303-2647(67)90031-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019611351"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0003-9861(61)90330-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022013092"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.57.1097", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033744209"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02138294", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034585724", 
          "https://doi.org/10.1007/bf02138294"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00928901", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038603430", 
          "https://doi.org/10.1007/bf00928901"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.58.1903", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047985894"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/224795a0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050775752", 
          "https://doi.org/10.1038/224795a0"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://app.dimensions.ai/details/publication/pub.1080510741", 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1993-06", 
    "datePublishedReg": "1993-06-01", 
    "description": "The reactions of 2- and 3-aminopropionitrile (APN), and 2,2\u2032-iminodipropionitrile (IDPN) were carried out in aqueous ammoniacal media. 2-APN was found to give IDPN, N-(1-cyanoethyl)alanine amide, N-(1-cyanoethyl)alanine, N-(1-carbamoylethyl)alanine, 2,2\u2032-iminodipropionic acid, alanine amide, and alanine. Compounds of biological significance such as peptides and amino acids other than alanine were not formed. The results were well consistent with those obtained for aminoacetonitrile. IDPN which can be formed easily from 2-APN in aqueous media, also yielded the same products as with 2-APN. On the other hand, 3-APN gave 3-alanine via 3-alanine amide under similar conditions. 3-APN was found to be more stable than 2-APN in aqueous media.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf01581835", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1096558", 
        "issn": [
          "0169-6149", 
          "1573-0875"
        ], 
        "name": "Origins of Life and Evolution of Biospheres", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "23"
      }
    ], 
    "name": "On the reaction of 2-aminopropionitrile in aqueous media", 
    "pagination": "153-165", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "988caaabfc70dd4bbb6f0fe175775757d2ebbed3f7647e6ff476223a3cc50601"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01581835"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1032022420"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01581835", 
      "https://app.dimensions.ai/details/publication/pub.1032022420"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:28", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000370_0000000370/records_46741_00000001.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/BF01581835"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01581835'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01581835'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01581835'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01581835'


 

This table displays all metadata directly associated to this object as RDF triples.

120 TRIPLES      21 PREDICATES      39 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01581835 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author Nc88131d381ca4c3eb14ddef6ab3a3811
4 schema:citation sg:pub.10.1007/bf00928901
5 sg:pub.10.1007/bf01808147
6 sg:pub.10.1007/bf02138294
7 sg:pub.10.1038/224795a0
8 https://app.dimensions.ai/details/publication/pub.1080510741
9 https://doi.org/10.1016/0003-9861(61)90330-7
10 https://doi.org/10.1016/0022-5193(72)90044-6
11 https://doi.org/10.1016/0045-2068(71)90020-4
12 https://doi.org/10.1016/0303-2647(67)90031-7
13 https://doi.org/10.1016/s0040-4020(01)99315-9
14 https://doi.org/10.1246/bcsj.57.1097
15 https://doi.org/10.1246/bcsj.58.1903
16 schema:datePublished 1993-06
17 schema:datePublishedReg 1993-06-01
18 schema:description The reactions of 2- and 3-aminopropionitrile (APN), and 2,2′-iminodipropionitrile (IDPN) were carried out in aqueous ammoniacal media. 2-APN was found to give IDPN, N-(1-cyanoethyl)alanine amide, N-(1-cyanoethyl)alanine, N-(1-carbamoylethyl)alanine, 2,2′-iminodipropionic acid, alanine amide, and alanine. Compounds of biological significance such as peptides and amino acids other than alanine were not formed. The results were well consistent with those obtained for aminoacetonitrile. IDPN which can be formed easily from 2-APN in aqueous media, also yielded the same products as with 2-APN. On the other hand, 3-APN gave 3-alanine via 3-alanine amide under similar conditions. 3-APN was found to be more stable than 2-APN in aqueous media.
19 schema:genre research_article
20 schema:inLanguage en
21 schema:isAccessibleForFree false
22 schema:isPartOf N3ffe4c912bfa4f95bdcb10b3d706a683
23 Na6873ced58b3496daa738a13b7f684af
24 sg:journal.1096558
25 schema:name On the reaction of 2-aminopropionitrile in aqueous media
26 schema:pagination 153-165
27 schema:productId N2310704e03f14c8682a565155909ca8b
28 Nd517f671aab14d609fa40b85f066e605
29 Ne02354221f1c48b0bd445b398e1c33e5
30 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032022420
31 https://doi.org/10.1007/bf01581835
32 schema:sdDatePublished 2019-04-11T13:28
33 schema:sdLicense https://scigraph.springernature.com/explorer/license/
34 schema:sdPublisher Nefebbd35a9874bd99d8542f5e250a826
35 schema:url http://link.springer.com/10.1007/BF01581835
36 sgo:license sg:explorer/license/
37 sgo:sdDataset articles
38 rdf:type schema:ScholarlyArticle
39 N08cdbff4b4204d6ca053b5efcec62e42 rdf:first sg:person.015541720521.46
40 rdf:rest N1ae23f9cd51944fdab9d87fc9155aba6
41 N1ae23f9cd51944fdab9d87fc9155aba6 rdf:first sg:person.015535641115.24
42 rdf:rest rdf:nil
43 N1e2550b2290b469eb07d23b5a4b630d9 rdf:first N1f9c4e2149b74a3685de403aea2fa2dc
44 rdf:rest N08cdbff4b4204d6ca053b5efcec62e42
45 N1f9c4e2149b74a3685de403aea2fa2dc schema:affiliation https://www.grid.ac/institutes/grid.267335.6
46 schema:familyName Seno
47 schema:givenName Shigeaki
48 rdf:type schema:Person
49 N2310704e03f14c8682a565155909ca8b schema:name dimensions_id
50 schema:value pub.1032022420
51 rdf:type schema:PropertyValue
52 N3ffe4c912bfa4f95bdcb10b3d706a683 schema:volumeNumber 23
53 rdf:type schema:PublicationVolume
54 Na6873ced58b3496daa738a13b7f684af schema:issueNumber 3
55 rdf:type schema:PublicationIssue
56 Nc88131d381ca4c3eb14ddef6ab3a3811 rdf:first sg:person.07511302563.25
57 rdf:rest N1e2550b2290b469eb07d23b5a4b630d9
58 Nd517f671aab14d609fa40b85f066e605 schema:name doi
59 schema:value 10.1007/bf01581835
60 rdf:type schema:PropertyValue
61 Ne02354221f1c48b0bd445b398e1c33e5 schema:name readcube_id
62 schema:value 988caaabfc70dd4bbb6f0fe175775757d2ebbed3f7647e6ff476223a3cc50601
63 rdf:type schema:PropertyValue
64 Nefebbd35a9874bd99d8542f5e250a826 schema:name Springer Nature - SN SciGraph project
65 rdf:type schema:Organization
66 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
67 schema:name Chemical Sciences
68 rdf:type schema:DefinedTerm
69 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
70 schema:name Organic Chemistry
71 rdf:type schema:DefinedTerm
72 sg:journal.1096558 schema:issn 0169-6149
73 1573-0875
74 schema:name Origins of Life and Evolution of Biospheres
75 rdf:type schema:Periodical
76 sg:person.015535641115.24 schema:affiliation https://www.grid.ac/institutes/grid.267335.6
77 schema:familyName Hayashi
78 schema:givenName Hiromu
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015535641115.24
80 rdf:type schema:Person
81 sg:person.015541720521.46 schema:affiliation https://www.grid.ac/institutes/grid.267335.6
82 schema:familyName Sugiyama
83 schema:givenName Shigeru
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015541720521.46
85 rdf:type schema:Person
86 sg:person.07511302563.25 schema:affiliation https://www.grid.ac/institutes/grid.267335.6
87 schema:familyName Kawashiro
88 schema:givenName Katsuhiro
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07511302563.25
90 rdf:type schema:Person
91 sg:pub.10.1007/bf00928901 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038603430
92 https://doi.org/10.1007/bf00928901
93 rdf:type schema:CreativeWork
94 sg:pub.10.1007/bf01808147 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011274175
95 https://doi.org/10.1007/bf01808147
96 rdf:type schema:CreativeWork
97 sg:pub.10.1007/bf02138294 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034585724
98 https://doi.org/10.1007/bf02138294
99 rdf:type schema:CreativeWork
100 sg:pub.10.1038/224795a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050775752
101 https://doi.org/10.1038/224795a0
102 rdf:type schema:CreativeWork
103 https://app.dimensions.ai/details/publication/pub.1080510741 schema:CreativeWork
104 https://doi.org/10.1016/0003-9861(61)90330-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022013092
105 rdf:type schema:CreativeWork
106 https://doi.org/10.1016/0022-5193(72)90044-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007621394
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1016/0045-2068(71)90020-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000759431
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1016/0303-2647(67)90031-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019611351
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1016/s0040-4020(01)99315-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017783622
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1246/bcsj.57.1097 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033744209
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1246/bcsj.58.1903 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047985894
117 rdf:type schema:CreativeWork
118 https://www.grid.ac/institutes/grid.267335.6 schema:alternateName University of Tokushima
119 schema:name Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima, Minamijosanjima, 770, Tokushima, Japan
120 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...