Esr study of the reaction of iron carbonyls with sodium alkylthiolates View Full Text


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Article Info

DATE

1987-07

AUTHORS

Yu. A. Belousov, T. A. Kolosova, E. A. Viktorova, V. A. Sergeev, B. N. Babin

ABSTRACT

ConclusionsThe reaction of iron carbonyls with sodium alkylthiolates proceeds by redox-disproportionation through one-electron transfer to form the Fe2(CO)8∸, Fe3(CO)11 Fe4(CO)13∸, and Fe3(CO)12∸ radical-anions. Fe2(CO)6(SR)2 and Fe3(CO)9(SR)2∸ radical-anions are paramagnetic analogs of the reaction products, Fe2(CO)6(SR)2 and Fe3(CO)9(SR)2, and were detected by ESR spectroscopy.

PAGES

1529-1531

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01557542

DOI

http://dx.doi.org/10.1007/bf01557542

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027530323


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