Thermally stimulated depolarization currents of tactic polymethyl methacrylates and their mixtures View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1981-03

AUTHORS

K. Ohara, G. Rehage

ABSTRACT

Thermally stimulated depolarization currents (TSDC) of atactic (a), syndiotactic (s) and isotactic (i) PMMA and mixtures ofs- andi-PMMA were measured. In pure tactic PMMA, TSDC peak was obtained at a temperature corresponding to the glass transition temperature of each PMMA. TSDC of mixtures isolated as precipitates from 1/1 and 1/2 (i/sweight ratio) mixed solutions showed a peak which can be attributed to the glass transition temperature of the stereocomplex. TSDC of original l/1 mixture showed two peaks which are ascribed to the glass transition temperature of residual i-PMMA and the stereocomplex. The results suggests that stereocomplex formation occurs ini/s weight ratio of 1/2 independent of the way of preparation. More... »

PAGES

318-325

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01524710

DOI

http://dx.doi.org/10.1007/bf01524710

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017299057


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Materials Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Faculty of Textile Science and Technology, Shinshu University, 3-15-1 Tokida, 386, Ueda, Japan", 
          "id": "http://www.grid.ac/institutes/grid.263518.b", 
          "name": [
            "Faculty of Textile Science and Technology, Shinshu University, 3-15-1 Tokida, 386, Ueda, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ohara", 
        "givenName": "K.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institut f\u00fcr Pysik. Chemie der TU Clausthal, Clausthal-Zellerfeld, Germany", 
          "id": "http://www.grid.ac/institutes/grid.5164.6", 
          "name": [
            "Institut f\u00fcr Pysik. Chemie der TU Clausthal, Clausthal-Zellerfeld, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rehage", 
        "givenName": "G.", 
        "id": "sg:person.016476122135.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016476122135.16"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1295/polymj.1.46", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025044081", 
          "https://doi.org/10.1295/polymj.1.46"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01517014", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044607350", 
          "https://doi.org/10.1007/bf01517014"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1295/polymj.2.173", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038151172", 
          "https://doi.org/10.1295/polymj.2.173"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01384032", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007754090", 
          "https://doi.org/10.1007/bf01384032"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1981-03", 
    "datePublishedReg": "1981-03-01", 
    "description": "Thermally stimulated depolarization currents (TSDC) of atactic (a), syndiotactic (s) and isotactic (i) PMMA and mixtures ofs- andi-PMMA were measured. In pure tactic PMMA, TSDC peak was obtained at a temperature corresponding to the glass transition temperature of each PMMA. TSDC of mixtures isolated as precipitates from 1/1 and 1/2 (i/sweight ratio) mixed solutions showed a peak which can be attributed to the glass transition temperature of the stereocomplex. TSDC of original l/1 mixture showed two peaks which are ascribed to the glass transition temperature of residual i-PMMA and the stereocomplex. The results suggests that stereocomplex formation occurs ini/s weight ratio of 1/2 independent of the way of preparation.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf01524710", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1083512", 
        "issn": [
          "0303-402X", 
          "1435-1536"
        ], 
        "name": "Colloid and Polymer Science", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "259"
      }
    ], 
    "keywords": [
      "depolarization currents", 
      "current", 
      "PMMA", 
      "TSDC peaks", 
      "peak", 
      "temperature", 
      "glass transition temperature", 
      "transition temperature", 
      "TSDC", 
      "mixture", 
      "precipitates", 
      "mixed solution", 
      "solution", 
      "stereocomplex", 
      "stereocomplex formation", 
      "weight ratio", 
      "way of preparation", 
      "polymethyl methacrylate", 
      "methacrylate", 
      "atactic", 
      "isotactic PMMA", 
      "pure tactic PMMA", 
      "tactic PMMA", 
      "TSDC of mixtures", 
      "original l/1 mixture", 
      "l/1 mixture", 
      "residual i", 
      "results", 
      "formation", 
      "ini/s weight ratio", 
      "s weight ratio", 
      "ratio", 
      "independent", 
      "way", 
      "preparation", 
      "tactic polymethyl methacrylates"
    ], 
    "name": "Thermally stimulated depolarization currents of tactic polymethyl methacrylates and their mixtures", 
    "pagination": "318-325", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1017299057"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01524710"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01524710", 
      "https://app.dimensions.ai/details/publication/pub.1017299057"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-12-01T19:04", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211201/entities/gbq_results/article/article_167.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf01524710"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01524710'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01524710'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01524710'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01524710'


 

This table displays all metadata directly associated to this object as RDF triples.

131 TRIPLES      22 PREDICATES      69 URIs      54 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01524710 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 anzsrc-for:0306
4 anzsrc-for:09
5 anzsrc-for:0912
6 schema:author Nebbda6d5653a4fe3942b3481942a1fef
7 schema:citation sg:pub.10.1007/bf01384032
8 sg:pub.10.1007/bf01517014
9 sg:pub.10.1295/polymj.1.46
10 sg:pub.10.1295/polymj.2.173
11 schema:datePublished 1981-03
12 schema:datePublishedReg 1981-03-01
13 schema:description Thermally stimulated depolarization currents (TSDC) of atactic (a), syndiotactic (s) and isotactic (i) PMMA and mixtures ofs- andi-PMMA were measured. In pure tactic PMMA, TSDC peak was obtained at a temperature corresponding to the glass transition temperature of each PMMA. TSDC of mixtures isolated as precipitates from 1/1 and 1/2 (i/sweight ratio) mixed solutions showed a peak which can be attributed to the glass transition temperature of the stereocomplex. TSDC of original l/1 mixture showed two peaks which are ascribed to the glass transition temperature of residual i-PMMA and the stereocomplex. The results suggests that stereocomplex formation occurs ini/s weight ratio of 1/2 independent of the way of preparation.
14 schema:genre article
15 schema:inLanguage en
16 schema:isAccessibleForFree false
17 schema:isPartOf N6419cb939a2744f583d138f39b52057d
18 Na6b2ec24a2fe4d1a89a44d62c0e48d4e
19 sg:journal.1083512
20 schema:keywords PMMA
21 TSDC
22 TSDC of mixtures
23 TSDC peaks
24 atactic
25 current
26 depolarization currents
27 formation
28 glass transition temperature
29 independent
30 ini/s weight ratio
31 isotactic PMMA
32 l/1 mixture
33 methacrylate
34 mixed solution
35 mixture
36 original l/1 mixture
37 peak
38 polymethyl methacrylate
39 precipitates
40 preparation
41 pure tactic PMMA
42 ratio
43 residual i
44 results
45 s weight ratio
46 solution
47 stereocomplex
48 stereocomplex formation
49 tactic PMMA
50 tactic polymethyl methacrylates
51 temperature
52 transition temperature
53 way
54 way of preparation
55 weight ratio
56 schema:name Thermally stimulated depolarization currents of tactic polymethyl methacrylates and their mixtures
57 schema:pagination 318-325
58 schema:productId N7ae50bd36dad412696aa6c0eda4ed514
59 Nda61b1d92338421091ee38e2b1aa0957
60 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017299057
61 https://doi.org/10.1007/bf01524710
62 schema:sdDatePublished 2021-12-01T19:04
63 schema:sdLicense https://scigraph.springernature.com/explorer/license/
64 schema:sdPublisher N9e215daf564c498ea2d43ea9f217ce9a
65 schema:url https://doi.org/10.1007/bf01524710
66 sgo:license sg:explorer/license/
67 sgo:sdDataset articles
68 rdf:type schema:ScholarlyArticle
69 N6419cb939a2744f583d138f39b52057d schema:volumeNumber 259
70 rdf:type schema:PublicationVolume
71 N73f7878b810045d8afd80735b65f240e rdf:first sg:person.016476122135.16
72 rdf:rest rdf:nil
73 N7ae50bd36dad412696aa6c0eda4ed514 schema:name dimensions_id
74 schema:value pub.1017299057
75 rdf:type schema:PropertyValue
76 N9e215daf564c498ea2d43ea9f217ce9a schema:name Springer Nature - SN SciGraph project
77 rdf:type schema:Organization
78 Na6b2ec24a2fe4d1a89a44d62c0e48d4e schema:issueNumber 3
79 rdf:type schema:PublicationIssue
80 Nda61b1d92338421091ee38e2b1aa0957 schema:name doi
81 schema:value 10.1007/bf01524710
82 rdf:type schema:PropertyValue
83 Ne5d7b10fd9b743c4abad6f1555da592c schema:affiliation grid-institutes:grid.263518.b
84 schema:familyName Ohara
85 schema:givenName K.
86 rdf:type schema:Person
87 Nebbda6d5653a4fe3942b3481942a1fef rdf:first Ne5d7b10fd9b743c4abad6f1555da592c
88 rdf:rest N73f7878b810045d8afd80735b65f240e
89 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
90 schema:name Chemical Sciences
91 rdf:type schema:DefinedTerm
92 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
93 schema:name Macromolecular and Materials Chemistry
94 rdf:type schema:DefinedTerm
95 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
96 schema:name Physical Chemistry (incl. Structural)
97 rdf:type schema:DefinedTerm
98 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
99 schema:name Engineering
100 rdf:type schema:DefinedTerm
101 anzsrc-for:0912 schema:inDefinedTermSet anzsrc-for:
102 schema:name Materials Engineering
103 rdf:type schema:DefinedTerm
104 sg:journal.1083512 schema:issn 0303-402X
105 1435-1536
106 schema:name Colloid and Polymer Science
107 schema:publisher Springer Nature
108 rdf:type schema:Periodical
109 sg:person.016476122135.16 schema:affiliation grid-institutes:grid.5164.6
110 schema:familyName Rehage
111 schema:givenName G.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016476122135.16
113 rdf:type schema:Person
114 sg:pub.10.1007/bf01384032 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007754090
115 https://doi.org/10.1007/bf01384032
116 rdf:type schema:CreativeWork
117 sg:pub.10.1007/bf01517014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044607350
118 https://doi.org/10.1007/bf01517014
119 rdf:type schema:CreativeWork
120 sg:pub.10.1295/polymj.1.46 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025044081
121 https://doi.org/10.1295/polymj.1.46
122 rdf:type schema:CreativeWork
123 sg:pub.10.1295/polymj.2.173 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038151172
124 https://doi.org/10.1295/polymj.2.173
125 rdf:type schema:CreativeWork
126 grid-institutes:grid.263518.b schema:alternateName Faculty of Textile Science and Technology, Shinshu University, 3-15-1 Tokida, 386, Ueda, Japan
127 schema:name Faculty of Textile Science and Technology, Shinshu University, 3-15-1 Tokida, 386, Ueda, Japan
128 rdf:type schema:Organization
129 grid-institutes:grid.5164.6 schema:alternateName Institut für Pysik. Chemie der TU Clausthal, Clausthal-Zellerfeld, Germany
130 schema:name Institut für Pysik. Chemie der TU Clausthal, Clausthal-Zellerfeld, Germany
131 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...