A study of the reaction of iron carbonyls with an activated silica matrix and the effect of hydrogen and synthesis ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1986-12

AUTHORS

M. V. Tsodikov, Ya. R. Katsobashvili, E. V. Slivinskii, Yu. V. Maksimov, V. V. Matveev, I. P. Suzdalev, O. G. Éllert, G. F. Ivanova

ABSTRACT

It has been established that the reaction of iron carbonyls with an activated silica matrix leads to the decomposition of the complexes and the predominant formation of iron(III) ions distributed in the interlayer space of silica (polyhedron I).The initial iron-containing complex having the polyhedron I structure is not active in synthesis from CO and H2; the increase in activity in the synthesis is associated with the formation of a reduced, labile complex of iron(II) incorporated in the matrix and of microcrystallites of nonstoichiometric magnetite on the silica surface. It has been established that the reaction of iron carbonyls with an activated silica matrix leads to the decomposition of the complexes and the predominant formation of iron(III) ions distributed in the interlayer space of silica (polyhedron I). The initial iron-containing complex having the polyhedron I structure is not active in synthesis from CO and H2; the increase in activity in the synthesis is associated with the formation of a reduced, labile complex of iron(II) incorporated in the matrix and of microcrystallites of nonstoichiometric magnetite on the silica surface. More... »

PAGES

2443-2447

Journal

TITLE

Russian Chemical Bulletin

ISSUE

12

VOLUME

35

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01474194

DOI

http://dx.doi.org/10.1007/bf01474194

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1038829638


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