Gas-phase interaction of Me3Si+ ions withcis- andtrans-cyclohexanediols, their methyl ethers, and acetates View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1996-08

AUTHORS

V. L. Kadentsev, N. G. Kolotyrkina, A. A. Stomakhin, O. S. Chizhov

ABSTRACT

The effect of stereochemistry on the mechanism of gas-phase fragmentation of [M+SiMe3]+ ions was studied usingcis- andtrans-1,2- and -1,4-cyclohexanediols, their methyl ethers, and acetates as model compounds. The higher stability of the [M+SiMe3]+ions is characteristic of cis-isomers of all the compounds examined, which is associated with chelation in the case ofcis-cyclohexanediols andcis-methoxycyclohexanols and with the higher reactivity oftrans-isomers due to anchimeric assistance of the methoxy and acetoxy groups. Dehydration is characteristic of the [M+SiMe3]+ ions formed from cyclohexanediols; both hydrogen atoms of the hydroxyl groups take part in the process, thus providing direct evidence of the chelation. More... »

PAGES

1921-1924

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01457777

DOI

http://dx.doi.org/10.1007/bf01457777

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1001651048


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kadentsev", 
        "givenName": "V. L.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kolotyrkina", 
        "givenName": "N. G.", 
        "id": "sg:person.016374705303.78", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016374705303.78"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Stomakhin", 
        "givenName": "A. A.", 
        "id": "sg:person.01210047302.80", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01210047302.80"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chizhov", 
        "givenName": "O. S.", 
        "id": "sg:person.014663256724.68", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014663256724.68"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1996-08", 
    "datePublishedReg": "1996-08-01", 
    "description": "The effect of stereochemistry on the mechanism of gas-phase fragmentation of [M+SiMe3]+ ions was studied usingcis- andtrans-1,2- and -1,4-cyclohexanediols, their methyl ethers, and acetates as model compounds. The higher stability of the [M+SiMe3]+ions is characteristic of cis-isomers of all the compounds examined, which is associated with chelation in the case ofcis-cyclohexanediols andcis-methoxycyclohexanols and with the higher reactivity oftrans-isomers due to anchimeric assistance of the methoxy and acetoxy groups. Dehydration is characteristic of the [M+SiMe3]+ ions formed from cyclohexanediols; both hydrogen atoms of the hydroxyl groups take part in the process, thus providing direct evidence of the chelation.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf01457777", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1063-5211", 
          "1026-3500"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "8", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "45"
      }
    ], 
    "keywords": [
      "gas-phase fragmentation", 
      "gas-phase interactions", 
      "methyl ether", 
      "effect of stereochemistry", 
      "model compounds", 
      "hydroxyl groups", 
      "high reactivity", 
      "hydrogen atoms", 
      "high stability", 
      "anchimeric assistance", 
      "acetoxy group", 
      "cyclohexanediols", 
      "ions", 
      "ether", 
      "compounds", 
      "chelation", 
      "acetate", 
      "methoxy", 
      "stereochemistry", 
      "atoms", 
      "reactivity", 
      "stability", 
      "dehydration", 
      "direct evidence", 
      "interaction", 
      "fragmentation", 
      "group", 
      "process", 
      "mechanism", 
      "effect", 
      "assistance", 
      "part", 
      "cases", 
      "evidence", 
      "ions withcis- andtrans", 
      "withcis- andtrans"
    ], 
    "name": "Gas-phase interaction of Me3Si+ ions withcis- andtrans-cyclohexanediols, their methyl ethers, and acetates", 
    "pagination": "1921-1924", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1001651048"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01457777"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01457777", 
      "https://app.dimensions.ai/details/publication/pub.1001651048"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:01", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_272.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf01457777"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01457777'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01457777'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01457777'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01457777'


 

This table displays all metadata directly associated to this object as RDF triples.

114 TRIPLES      21 PREDICATES      62 URIs      54 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01457777 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N43433236aea54f138483dc6b62ef9ab6
4 schema:datePublished 1996-08
5 schema:datePublishedReg 1996-08-01
6 schema:description The effect of stereochemistry on the mechanism of gas-phase fragmentation of [M+SiMe3]+ ions was studied usingcis- andtrans-1,2- and -1,4-cyclohexanediols, their methyl ethers, and acetates as model compounds. The higher stability of the [M+SiMe3]+ions is characteristic of cis-isomers of all the compounds examined, which is associated with chelation in the case ofcis-cyclohexanediols andcis-methoxycyclohexanols and with the higher reactivity oftrans-isomers due to anchimeric assistance of the methoxy and acetoxy groups. Dehydration is characteristic of the [M+SiMe3]+ ions formed from cyclohexanediols; both hydrogen atoms of the hydroxyl groups take part in the process, thus providing direct evidence of the chelation.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N07c635fe50ce42c5b3850391d8d067c8
11 N81bc52b4ca6e45f78de6ab400a75988b
12 sg:journal.1022309
13 schema:keywords acetate
14 acetoxy group
15 anchimeric assistance
16 assistance
17 atoms
18 cases
19 chelation
20 compounds
21 cyclohexanediols
22 dehydration
23 direct evidence
24 effect
25 effect of stereochemistry
26 ether
27 evidence
28 fragmentation
29 gas-phase fragmentation
30 gas-phase interactions
31 group
32 high reactivity
33 high stability
34 hydrogen atoms
35 hydroxyl groups
36 interaction
37 ions
38 ions withcis- andtrans
39 mechanism
40 methoxy
41 methyl ether
42 model compounds
43 part
44 process
45 reactivity
46 stability
47 stereochemistry
48 withcis- andtrans
49 schema:name Gas-phase interaction of Me3Si+ ions withcis- andtrans-cyclohexanediols, their methyl ethers, and acetates
50 schema:pagination 1921-1924
51 schema:productId N48aa23ea2ed24a0488b2ea60d575a11c
52 Nbb9bb001937a4cafbc2e443e87800188
53 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001651048
54 https://doi.org/10.1007/bf01457777
55 schema:sdDatePublished 2021-11-01T18:01
56 schema:sdLicense https://scigraph.springernature.com/explorer/license/
57 schema:sdPublisher N234664250db847e48717ce17031be117
58 schema:url https://doi.org/10.1007/bf01457777
59 sgo:license sg:explorer/license/
60 sgo:sdDataset articles
61 rdf:type schema:ScholarlyArticle
62 N07c635fe50ce42c5b3850391d8d067c8 schema:volumeNumber 45
63 rdf:type schema:PublicationVolume
64 N1024eb25ab2940dbb0e717efcdca265a rdf:first sg:person.014663256724.68
65 rdf:rest rdf:nil
66 N234664250db847e48717ce17031be117 schema:name Springer Nature - SN SciGraph project
67 rdf:type schema:Organization
68 N43433236aea54f138483dc6b62ef9ab6 rdf:first N96c72e355f284224866ac244cb7aafe7
69 rdf:rest Ndde6f86dc0fe4f61a82f9ea809772913
70 N48aa23ea2ed24a0488b2ea60d575a11c schema:name dimensions_id
71 schema:value pub.1001651048
72 rdf:type schema:PropertyValue
73 N81bc52b4ca6e45f78de6ab400a75988b schema:issueNumber 8
74 rdf:type schema:PublicationIssue
75 N96c72e355f284224866ac244cb7aafe7 schema:affiliation grid-institutes:grid.439283.7
76 schema:familyName Kadentsev
77 schema:givenName V. L.
78 rdf:type schema:Person
79 N9f955b5e1d324d30ad45fb2d222c1a9e rdf:first sg:person.01210047302.80
80 rdf:rest N1024eb25ab2940dbb0e717efcdca265a
81 Nbb9bb001937a4cafbc2e443e87800188 schema:name doi
82 schema:value 10.1007/bf01457777
83 rdf:type schema:PropertyValue
84 Ndde6f86dc0fe4f61a82f9ea809772913 rdf:first sg:person.016374705303.78
85 rdf:rest N9f955b5e1d324d30ad45fb2d222c1a9e
86 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
87 schema:name Chemical Sciences
88 rdf:type schema:DefinedTerm
89 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
90 schema:name Inorganic Chemistry
91 rdf:type schema:DefinedTerm
92 sg:journal.1022309 schema:issn 1026-3500
93 1063-5211
94 schema:name Russian Chemical Bulletin
95 schema:publisher Springer Nature
96 rdf:type schema:Periodical
97 sg:person.01210047302.80 schema:affiliation grid-institutes:grid.439283.7
98 schema:familyName Stomakhin
99 schema:givenName A. A.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01210047302.80
101 rdf:type schema:Person
102 sg:person.014663256724.68 schema:affiliation grid-institutes:grid.439283.7
103 schema:familyName Chizhov
104 schema:givenName O. S.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014663256724.68
106 rdf:type schema:Person
107 sg:person.016374705303.78 schema:affiliation grid-institutes:grid.439283.7
108 schema:familyName Kolotyrkina
109 schema:givenName N. G.
110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016374705303.78
111 rdf:type schema:Person
112 grid-institutes:grid.439283.7 schema:alternateName N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation
113 schema:name N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation
114 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...