Ontology type: schema:ScholarlyArticle
1988-04
AUTHORSL. I. Gvinter, N. V. Borunova, R. G. Akhmadieva, N. V. Antseva, N. A. Yusupova, I. U. Numanov, V. Z. Sharf
ABSTRACTConclusionsComplexes of rhenium with cyclic sulfur-containing ligands (thiophane, 2-propylthio-phane) catalyze hydrogenation and isomerization of olefin and diene hydrocarbons.The catalytic activity of the complexes is a function of the ligand environment, the nature of the substrate, and the solvent.The catalysts tested accelerate isomerization of α-olefins both in hydrogen and in an inert atmosphere with the predominant formation of cis-β-olefins. More... »
PAGES641-644
http://scigraph.springernature.com/pub.10.1007/bf01455466
DOIhttp://dx.doi.org/10.1007/bf01455466
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1050235240
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Inorganic Chemistry",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe",
"id": "http://www.grid.ac/institutes/grid.501752.4",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow",
"V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe"
],
"type": "Organization"
},
"familyName": "Gvinter",
"givenName": "L. I.",
"id": "sg:person.013423307113.48",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013423307113.48"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe",
"id": "http://www.grid.ac/institutes/grid.501752.4",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow",
"V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe"
],
"type": "Organization"
},
"familyName": "Borunova",
"givenName": "N. V.",
"id": "sg:person.07370266201.21",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07370266201.21"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe",
"id": "http://www.grid.ac/institutes/grid.501752.4",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow",
"V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe"
],
"type": "Organization"
},
"familyName": "Akhmadieva",
"givenName": "R. G.",
"id": "sg:person.014217026345.57",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014217026345.57"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe",
"id": "http://www.grid.ac/institutes/grid.501752.4",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow",
"V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe"
],
"type": "Organization"
},
"familyName": "Antseva",
"givenName": "N. V.",
"id": "sg:person.015073513442.90",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015073513442.90"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe",
"id": "http://www.grid.ac/institutes/grid.501752.4",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow",
"V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe"
],
"type": "Organization"
},
"familyName": "Yusupova",
"givenName": "N. A.",
"id": "sg:person.013205141306.44",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013205141306.44"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe",
"id": "http://www.grid.ac/institutes/grid.501752.4",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow",
"V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe"
],
"type": "Organization"
},
"familyName": "Numanov",
"givenName": "I. U.",
"id": "sg:person.016407347745.05",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016407347745.05"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe",
"id": "http://www.grid.ac/institutes/grid.501752.4",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow",
"V. I. Nikitin Institute of Chemistry, Academy of Sciences of the Tadzhik SSR, Dushanbe"
],
"type": "Organization"
},
"familyName": "Sharf",
"givenName": "V. Z.",
"id": "sg:person.012355773047.12",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012355773047.12"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/bf02116756",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1017216648",
"https://doi.org/10.1007/bf02116756"
],
"type": "CreativeWork"
}
],
"datePublished": "1988-04",
"datePublishedReg": "1988-04-01",
"description": "ConclusionsComplexes of rhenium with cyclic sulfur-containing ligands (thiophane, 2-propylthio-phane) catalyze hydrogenation and isomerization of olefin and diene hydrocarbons.The catalytic activity of the complexes is a function of the ligand environment, the nature of the substrate, and the solvent.The catalysts tested accelerate isomerization of \u03b1-olefins both in hydrogen and in an inert atmosphere with the predominant formation of cis-\u03b2-olefins.",
"genre": "article",
"id": "sg:pub.10.1007/bf01455466",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1022309",
"issn": [
"1026-3500",
"1066-5285"
],
"name": "Russian Chemical Bulletin",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "4",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "37"
}
],
"keywords": [
"isomerization of olefins",
"catalysts of hydrogenation",
"sulfur-containing ligands",
"ligand environment",
"catalytic activity",
"diene hydrocarbons",
"cyclic sulfides",
"olefins",
"inert atmosphere",
"predominant formation",
"isomerization",
"catalyst",
"hydrogenation",
"complexes",
"solvent",
"ConclusionsComplexes",
"rhenium",
"ligands",
"hydrogen",
"sulfide",
"hydrocarbons",
"cis",
"substrate",
"atmosphere",
"formation",
"nature",
"activity",
"environment",
"function"
],
"name": "Complexes of rhenium(V) with cyclic sulfides: Catalysts of hydrogenation and isomerization of olefins",
"pagination": "641-644",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1050235240"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf01455466"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf01455466",
"https://app.dimensions.ai/details/publication/pub.1050235240"
],
"sdDataset": "articles",
"sdDatePublished": "2022-05-20T07:18",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_214.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/bf01455466"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01455466'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01455466'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01455466'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01455466'
This table displays all metadata directly associated to this object as RDF triples.
138 TRIPLES
22 PREDICATES
57 URIs
47 LITERALS
6 BLANK NODES