Complexes of rhenium(V) with cyclic sulfides: Catalysts of hydrogenation and isomerization of olefins View Full Text


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Article Info

DATE

1988-04

AUTHORS

L. I. Gvinter, N. V. Borunova, R. G. Akhmadieva, N. V. Antseva, N. A. Yusupova, I. U. Numanov, V. Z. Sharf

ABSTRACT

ConclusionsComplexes of rhenium with cyclic sulfur-containing ligands (thiophane, 2-propylthio-phane) catalyze hydrogenation and isomerization of olefin and diene hydrocarbons.The catalytic activity of the complexes is a function of the ligand environment, the nature of the substrate, and the solvent.The catalysts tested accelerate isomerization of α-olefins both in hydrogen and in an inert atmosphere with the predominant formation of cis-β-olefins. More... »

PAGES

641-644

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01455466

DOI

http://dx.doi.org/10.1007/bf01455466

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050235240


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