Swelling equilibrium and preferential sorption of crosslinked poly(methyl methacrylate) in the mixture acetonitrile + n-butanol View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1984-11

AUTHORS

R. M. Masegosa, M. A. Llorente, M. G. Prolongo, I. Hernández-Fuentes, A. Horta

ABSTRACT

Measurements of preferential sorption,λ(Ν3), determined by refractometry, and swelling equilibrium,Ν3−1, of PMMA networks have been carried out in the cosolvent mixture MeCN+BuOH at 25‡ and 49 ‡C. With an intermediate mixture composition,Ν3−1 passes through a maximum at both temperatures. At 25 ‡C MeCN is preferentially adsorbed by the network over most of the composition range, but a small inversion is detected. At 49 ‡C MeCN is preferentially adsorbed over all the composition range. The behavior of the system crosslinked PMMA/MeCN + BuOH is compared with the results obtained for solutions of linear PMMA in mixtures formed by the same two solvents, MeCN and BuOH. More... »

PAGES

862-866

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01452216

DOI

http://dx.doi.org/10.1007/bf01452216

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022520121


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