CN chemiluminescence in N2 + CH4 Flowing afterglow at low temperatures View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1994-09

AUTHORS

J. Janča, A. Tálský, F. Krčma, L. Hochard, A. Ricard

ABSTRACT

The spectra of flowing microwave post-discharge excited in N2 and N2 + CH4(N2 + C2H2) gas mixtures have been studied at low temperature (77 K). The molecular spectra of CN emitted by the collision-induced N + C and N + CH chemiluminescent reactions in the low-temperature afterglow system have been thoroughly investigated. The intensity of different CN (B2Σ+-X2Σ+) vibrational bands is very sensitive to low hydrocarbon concentration in nitrogen used as the working gas. Detection of hydrocarbon species has been demonstrated from concentrations of CH4 and C2H2 in N2 greater than 1010 molecules · cm−3. More... »

PAGES

197-208

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01447078

DOI

http://dx.doi.org/10.1007/bf01447078

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005119303


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0202", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Atomic, Molecular, Nuclear, Particle and Plasma Physics", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Physical Electronics, Faculty of Science, T. G. Masaryk University, Kotl\u00e1\u0159sk\u00e1 2, 61137, Brno, Czech Republic", 
          "id": "http://www.grid.ac/institutes/grid.10267.32", 
          "name": [
            "Department of Physical Electronics, Faculty of Science, T. G. Masaryk University, Kotl\u00e1\u0159sk\u00e1 2, 61137, Brno, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Jan\u010da", 
        "givenName": "J.", 
        "id": "sg:person.013051704733.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013051704733.05"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Physical Electronics, Faculty of Science, T. G. Masaryk University, Kotl\u00e1\u0159sk\u00e1 2, 61137, Brno, Czech Republic", 
          "id": "http://www.grid.ac/institutes/grid.10267.32", 
          "name": [
            "Department of Physical Electronics, Faculty of Science, T. G. Masaryk University, Kotl\u00e1\u0159sk\u00e1 2, 61137, Brno, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "T\u00e1lsk\u00fd", 
        "givenName": "A.", 
        "id": "sg:person.011251775651.63", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011251775651.63"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Physical Electronics, Faculty of Science, T. G. Masaryk University, Kotl\u00e1\u0159sk\u00e1 2, 61137, Brno, Czech Republic", 
          "id": "http://www.grid.ac/institutes/grid.10267.32", 
          "name": [
            "Department of Physical Electronics, Faculty of Science, T. G. Masaryk University, Kotl\u00e1\u0159sk\u00e1 2, 61137, Brno, Czech Republic"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kr\u010dma", 
        "givenName": "F.", 
        "id": "sg:person.012406140373.54", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012406140373.54"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Laboratoire de Physique de Gaz et des Plasmas CNRS, Batiment 212, Universite de Paris-Sud, 91405, Orsay, France", 
          "id": "http://www.grid.ac/institutes/grid.5842.b", 
          "name": [
            "Laboratoire de Physique de Gaz et des Plasmas CNRS, Batiment 212, Universite de Paris-Sud, 91405, Orsay, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hochard", 
        "givenName": "L.", 
        "id": "sg:person.012500732743.04", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012500732743.04"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Laboratoire de Physique de Gaz et des Plasmas CNRS, Batiment 212, Universite de Paris-Sud, 91405, Orsay, France", 
          "id": "http://www.grid.ac/institutes/grid.5842.b", 
          "name": [
            "Laboratoire de Physique de Gaz et des Plasmas CNRS, Batiment 212, Universite de Paris-Sud, 91405, Orsay, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ricard", 
        "givenName": "A.", 
        "id": "sg:person.07620123655.66", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07620123655.66"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/978-1-4615-3400-6_9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013003746", 
          "https://doi.org/10.1007/978-1-4615-3400-6_9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00566212", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007930590", 
          "https://doi.org/10.1007/bf00566212"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1994-09", 
    "datePublishedReg": "1994-09-01", 
    "description": "The spectra of flowing microwave post-discharge excited in N2 and N2 + CH4(N2 + C2H2) gas mixtures have been studied at low temperature (77 K). The molecular spectra of CN emitted by the collision-induced N + C and N + CH chemiluminescent reactions in the low-temperature afterglow system have been thoroughly investigated. The intensity of different CN (B2\u03a3+-X2\u03a3+) vibrational bands is very sensitive to low hydrocarbon concentration in nitrogen used as the working gas. Detection of hydrocarbon species has been demonstrated from concentrations of CH4 and C2H2 in N2 greater than 1010 molecules \u00b7 cm\u22123.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf01447078", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1124016", 
        "issn": [
          "0272-4324", 
          "1572-8986"
        ], 
        "name": "Plasma Chemistry and Plasma Processing", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "14"
      }
    ], 
    "keywords": [
      "low temperatures", 
      "hydrocarbon species", 
      "vibrational bands", 
      "chemiluminescent reaction", 
      "afterglow system", 
      "low hydrocarbon concentrations", 
      "molecular spectra", 
      "N2", 
      "gas mixture", 
      "hydrocarbon concentrations", 
      "concentration of CH4", 
      "CH4", 
      "working gas", 
      "spectra", 
      "C2H2", 
      "temperature", 
      "molecules", 
      "reaction", 
      "mixture", 
      "concentration", 
      "nitrogen", 
      "chemiluminescence", 
      "microwave", 
      "gas", 
      "band", 
      "CN", 
      "detection", 
      "species", 
      "intensity", 
      "system", 
      "CH chemiluminescent reactions", 
      "low-temperature afterglow system", 
      "different CN (B2\u03a3+-X2\u03a3+) vibrational bands", 
      "CN (B2\u03a3+-X2\u03a3+) vibrational bands", 
      "CN chemiluminescence"
    ], 
    "name": "CN chemiluminescence in N2 + CH4 Flowing afterglow at low temperatures", 
    "pagination": "197-208", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1005119303"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01447078"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01447078", 
      "https://app.dimensions.ai/details/publication/pub.1005119303"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T17:59", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_237.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf01447078"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01447078'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01447078'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01447078'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01447078'


 

This table displays all metadata directly associated to this object as RDF triples.

140 TRIPLES      22 PREDICATES      65 URIs      53 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01447078 schema:about anzsrc-for:02
2 anzsrc-for:0202
3 anzsrc-for:09
4 anzsrc-for:0904
5 schema:author Nceaa786557124ec5aa5b05feb76d1c39
6 schema:citation sg:pub.10.1007/978-1-4615-3400-6_9
7 sg:pub.10.1007/bf00566212
8 schema:datePublished 1994-09
9 schema:datePublishedReg 1994-09-01
10 schema:description The spectra of flowing microwave post-discharge excited in N2 and N2 + CH4(N2 + C2H2) gas mixtures have been studied at low temperature (77 K). The molecular spectra of CN emitted by the collision-induced N + C and N + CH chemiluminescent reactions in the low-temperature afterglow system have been thoroughly investigated. The intensity of different CN (B2Σ+-X2Σ+) vibrational bands is very sensitive to low hydrocarbon concentration in nitrogen used as the working gas. Detection of hydrocarbon species has been demonstrated from concentrations of CH4 and C2H2 in N2 greater than 1010 molecules · cm−3.
11 schema:genre article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N1e527aeb251d40d59d3adb4348237042
15 Nd8cdb47d80c043fc9674226cdf64bb1a
16 sg:journal.1124016
17 schema:keywords C2H2
18 CH chemiluminescent reactions
19 CH4
20 CN
21 CN (B2Σ+-X2Σ+) vibrational bands
22 CN chemiluminescence
23 N2
24 afterglow system
25 band
26 chemiluminescence
27 chemiluminescent reaction
28 concentration
29 concentration of CH4
30 detection
31 different CN (B2Σ+-X2Σ+) vibrational bands
32 gas
33 gas mixture
34 hydrocarbon concentrations
35 hydrocarbon species
36 intensity
37 low hydrocarbon concentrations
38 low temperatures
39 low-temperature afterglow system
40 microwave
41 mixture
42 molecular spectra
43 molecules
44 nitrogen
45 reaction
46 species
47 spectra
48 system
49 temperature
50 vibrational bands
51 working gas
52 schema:name CN chemiluminescence in N2 + CH4 Flowing afterglow at low temperatures
53 schema:pagination 197-208
54 schema:productId N4acc0557835144b8a80139d67c2b561b
55 N902efaea24ec4e1291d1c13fc1121e3a
56 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005119303
57 https://doi.org/10.1007/bf01447078
58 schema:sdDatePublished 2021-11-01T17:59
59 schema:sdLicense https://scigraph.springernature.com/explorer/license/
60 schema:sdPublisher Na7c64b87a7fe4f17942c137a978c05a3
61 schema:url https://doi.org/10.1007/bf01447078
62 sgo:license sg:explorer/license/
63 sgo:sdDataset articles
64 rdf:type schema:ScholarlyArticle
65 N001494e86cb24e41909bd748c7062440 rdf:first sg:person.012406140373.54
66 rdf:rest Nb4a39970ae4a428399ae2e1e4b0ff255
67 N0e3e631193fb48c39f95aec0942fd0b1 rdf:first sg:person.07620123655.66
68 rdf:rest rdf:nil
69 N1e527aeb251d40d59d3adb4348237042 schema:volumeNumber 14
70 rdf:type schema:PublicationVolume
71 N4acc0557835144b8a80139d67c2b561b schema:name doi
72 schema:value 10.1007/bf01447078
73 rdf:type schema:PropertyValue
74 N902efaea24ec4e1291d1c13fc1121e3a schema:name dimensions_id
75 schema:value pub.1005119303
76 rdf:type schema:PropertyValue
77 Na7c64b87a7fe4f17942c137a978c05a3 schema:name Springer Nature - SN SciGraph project
78 rdf:type schema:Organization
79 Nb4a39970ae4a428399ae2e1e4b0ff255 rdf:first sg:person.012500732743.04
80 rdf:rest N0e3e631193fb48c39f95aec0942fd0b1
81 Nceaa786557124ec5aa5b05feb76d1c39 rdf:first sg:person.013051704733.05
82 rdf:rest Nfa1e2f872a8149d8ac2536a2984f27e4
83 Nd8cdb47d80c043fc9674226cdf64bb1a schema:issueNumber 3
84 rdf:type schema:PublicationIssue
85 Nfa1e2f872a8149d8ac2536a2984f27e4 rdf:first sg:person.011251775651.63
86 rdf:rest N001494e86cb24e41909bd748c7062440
87 anzsrc-for:02 schema:inDefinedTermSet anzsrc-for:
88 schema:name Physical Sciences
89 rdf:type schema:DefinedTerm
90 anzsrc-for:0202 schema:inDefinedTermSet anzsrc-for:
91 schema:name Atomic, Molecular, Nuclear, Particle and Plasma Physics
92 rdf:type schema:DefinedTerm
93 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
94 schema:name Engineering
95 rdf:type schema:DefinedTerm
96 anzsrc-for:0904 schema:inDefinedTermSet anzsrc-for:
97 schema:name Chemical Engineering
98 rdf:type schema:DefinedTerm
99 sg:journal.1124016 schema:issn 0272-4324
100 1572-8986
101 schema:name Plasma Chemistry and Plasma Processing
102 schema:publisher Springer Nature
103 rdf:type schema:Periodical
104 sg:person.011251775651.63 schema:affiliation grid-institutes:grid.10267.32
105 schema:familyName Tálský
106 schema:givenName A.
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011251775651.63
108 rdf:type schema:Person
109 sg:person.012406140373.54 schema:affiliation grid-institutes:grid.10267.32
110 schema:familyName Krčma
111 schema:givenName F.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012406140373.54
113 rdf:type schema:Person
114 sg:person.012500732743.04 schema:affiliation grid-institutes:grid.5842.b
115 schema:familyName Hochard
116 schema:givenName L.
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012500732743.04
118 rdf:type schema:Person
119 sg:person.013051704733.05 schema:affiliation grid-institutes:grid.10267.32
120 schema:familyName Janča
121 schema:givenName J.
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013051704733.05
123 rdf:type schema:Person
124 sg:person.07620123655.66 schema:affiliation grid-institutes:grid.5842.b
125 schema:familyName Ricard
126 schema:givenName A.
127 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07620123655.66
128 rdf:type schema:Person
129 sg:pub.10.1007/978-1-4615-3400-6_9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013003746
130 https://doi.org/10.1007/978-1-4615-3400-6_9
131 rdf:type schema:CreativeWork
132 sg:pub.10.1007/bf00566212 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007930590
133 https://doi.org/10.1007/bf00566212
134 rdf:type schema:CreativeWork
135 grid-institutes:grid.10267.32 schema:alternateName Department of Physical Electronics, Faculty of Science, T. G. Masaryk University, Kotlářská 2, 61137, Brno, Czech Republic
136 schema:name Department of Physical Electronics, Faculty of Science, T. G. Masaryk University, Kotlářská 2, 61137, Brno, Czech Republic
137 rdf:type schema:Organization
138 grid-institutes:grid.5842.b schema:alternateName Laboratoire de Physique de Gaz et des Plasmas CNRS, Batiment 212, Universite de Paris-Sud, 91405, Orsay, France
139 schema:name Laboratoire de Physique de Gaz et des Plasmas CNRS, Batiment 212, Universite de Paris-Sud, 91405, Orsay, France
140 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...