Rearrangement of the crystal structure during solid-phase elimination of solvate acetic acid fromN′-(5-nitrofurfurylidene)isonicotinic hydrazide monohydrate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1996-10

AUTHORS

S. M. Aldoshin, E. G. Atovmyan, L. A. Nikonova, A. N. Utenyshev, I. I. Chuev

ABSTRACT

A new crystal modification ofN′-(5-nitrofurfurylidene)isonicotinic hydrazide (1) was studied by IR spectroscopy and X-ray structural analysis. The compound studied is the product of solid-phase desolvation of solvate hydrate1 of the composition [MeCOOH · 1 · H2O]. Spontaneous elimination of solvate acetic acid results in complex overall rearrangement of the crystal structure and formation of a new system of intermolecular hydrogen bonds. The crystal hydrate of 1 : 1 composition (1c) was formed from compound1. In the crystal structure of1c molecules1 are linked in infinite chains through intermolecular C=O...W...H-N hydrogen bonds. The second hydrogen atom of the molecule of the crystallization water is involved in formation of an intermolecular O-H...N(Py) hydrogen bond with the nitrogen atom of the pyridine ring of the molecule of the adjacent chain. More... »

PAGES

2373-2377

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01435385

DOI

http://dx.doi.org/10.1007/bf01435385

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034913766


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