Thermal decomposition of transition metal carboxylates View Full Text


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Article Info

DATE

1996-06

AUTHORS

A. S. Rozenberg, V. R. Stepanov

ABSTRACT

Thermal decomposition of anhydrous Cu(HCOO)2 (1) affords H2, CO, CO2, H2O, HCuOOH, CuHCOO, Cu, and the polymeric product, which contains -CH2O,-C(O)OH-, and -RCH-0- groups. Dccomposition of1 proceeds in stages with formation of copper(I) formate as an intermediate. Possible pathways of decomposition ofI, including isomeric forms of the HCO2 radical as intermediates, were analyzed. More... »

PAGES

1336-1343

References to SciGraph publications

  • 1987-07. Origin of organic gaseous products formed in the thermal decomposition of formates in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • 1974-09. The thermal decomposition of calcium, sodium, silver and copper(II) acetates in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf01434208

    DOI

    http://dx.doi.org/10.1007/bf01434208

    DIMENSIONS

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