Synthesis ofN-chioroacetyl-β-glycopyranosylamines, derivatives of monosaccharides and lactose View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1996-07

AUTHORS

L. M. Likhosherstov, O. S. Novikova, V. N. Shibaev, N. K. Kochetkov

ABSTRACT

N-Chloroacetyl-β-glycopyranosylimines were synthesized from various monosaccharide (hexoses, pentoses, deoxysugars, uronic acids, and sugar phosphates) and a disaccharide (lactose) byN-acylation of the corresponding β-glycosylamines with chloroacetic anhydride in DMF In some cases, treatment of rnonosacc harides with NH3 in the presence of (NH4)2CO3 in MeOH or aqueous MeOH was more efficient than the methods previously described, as it gave β-glycosylarnines in higher yields. More... »

PAGES

1760-1763

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01431821

DOI

http://dx.doi.org/10.1007/bf01431821

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037687923


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Likhosherstov", 
        "givenName": "L. M.", 
        "id": "sg:person.01222113333.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01222113333.75"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Novikova", 
        "givenName": "O. S.", 
        "id": "sg:person.0641301571.82", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0641301571.82"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shibaev", 
        "givenName": "V. N.", 
        "id": "sg:person.015075554137.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015075554137.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kochetkov", 
        "givenName": "N. K.", 
        "id": "sg:person.014702544422.40", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014702544422.40"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1996-07", 
    "datePublishedReg": "1996-07-01", 
    "description": "N-Chloroacetyl-\u03b2-glycopyranosylimines were synthesized from various monosaccharide (hexoses, pentoses, deoxysugars, uronic acids, and sugar phosphates) and a disaccharide (lactose) byN-acylation of the corresponding \u03b2-glycosylamines with chloroacetic anhydride in DMF In some cases, treatment of rnonosacc harides with NH3 in the presence of (NH4)2CO3 in MeOH or aqueous MeOH was more efficient than the methods previously described, as it gave \u03b2-glycosylarnines in higher yields.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf01431821", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1026-3500", 
          "1066-5285"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "45"
      }
    ], 
    "keywords": [
      "treatment", 
      "derivatives of monosaccharides", 
      "cases", 
      "presence", 
      "monosaccharides", 
      "lactose", 
      "disaccharides", 
      "aqueous MeOH", 
      "chloroacetyl", 
      "chloroacetic anhydride", 
      "method", 
      "derivatives", 
      "MeOH", 
      "high yield", 
      "synthesis", 
      "glycopyranosylamines", 
      "glycosylamines", 
      "anhydride", 
      "DMF", 
      "NH3", 
      "yield"
    ], 
    "name": "Synthesis ofN-chioroacetyl-\u03b2-glycopyranosylamines, derivatives of monosaccharides and lactose", 
    "pagination": "1760-1763", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1037687923"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01431821"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01431821", 
      "https://app.dimensions.ai/details/publication/pub.1037687923"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-20T07:20", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_275.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf01431821"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01431821'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01431821'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01431821'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01431821'


 

This table displays all metadata directly associated to this object as RDF triples.

100 TRIPLES      21 PREDICATES      47 URIs      39 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01431821 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N38b4211bd85c42f682fa4186140340cc
4 schema:datePublished 1996-07
5 schema:datePublishedReg 1996-07-01
6 schema:description N-Chloroacetyl-β-glycopyranosylimines were synthesized from various monosaccharide (hexoses, pentoses, deoxysugars, uronic acids, and sugar phosphates) and a disaccharide (lactose) byN-acylation of the corresponding β-glycosylamines with chloroacetic anhydride in DMF In some cases, treatment of rnonosacc harides with NH3 in the presence of (NH4)2CO3 in MeOH or aqueous MeOH was more efficient than the methods previously described, as it gave β-glycosylarnines in higher yields.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N9a684abfd1cb4951a9ed6331a43ea165
11 Nca15636ad6614e928ba6fef0644d375c
12 sg:journal.1022309
13 schema:keywords DMF
14 MeOH
15 NH3
16 anhydride
17 aqueous MeOH
18 cases
19 chloroacetic anhydride
20 chloroacetyl
21 derivatives
22 derivatives of monosaccharides
23 disaccharides
24 glycopyranosylamines
25 glycosylamines
26 high yield
27 lactose
28 method
29 monosaccharides
30 presence
31 synthesis
32 treatment
33 yield
34 schema:name Synthesis ofN-chioroacetyl-β-glycopyranosylamines, derivatives of monosaccharides and lactose
35 schema:pagination 1760-1763
36 schema:productId N5b448a9c26474b2b8cbee6b210559c59
37 N6a9a1a2b5fc3473991f519dd8ec8b4cb
38 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037687923
39 https://doi.org/10.1007/bf01431821
40 schema:sdDatePublished 2022-05-20T07:20
41 schema:sdLicense https://scigraph.springernature.com/explorer/license/
42 schema:sdPublisher Nec662ffacae2443aa98bd1691a2f120d
43 schema:url https://doi.org/10.1007/bf01431821
44 sgo:license sg:explorer/license/
45 sgo:sdDataset articles
46 rdf:type schema:ScholarlyArticle
47 N38b4211bd85c42f682fa4186140340cc rdf:first sg:person.01222113333.75
48 rdf:rest Nb21bb34bdc0a426486b2310c96ee5270
49 N5b448a9c26474b2b8cbee6b210559c59 schema:name dimensions_id
50 schema:value pub.1037687923
51 rdf:type schema:PropertyValue
52 N6a9a1a2b5fc3473991f519dd8ec8b4cb schema:name doi
53 schema:value 10.1007/bf01431821
54 rdf:type schema:PropertyValue
55 N7a56e9622fb24061a51356af96781361 rdf:first sg:person.014702544422.40
56 rdf:rest rdf:nil
57 N9a684abfd1cb4951a9ed6331a43ea165 schema:volumeNumber 45
58 rdf:type schema:PublicationVolume
59 Nb21bb34bdc0a426486b2310c96ee5270 rdf:first sg:person.0641301571.82
60 rdf:rest Ncf4e5b0a1b89459c9c043776fec4cc65
61 Nca15636ad6614e928ba6fef0644d375c schema:issueNumber 7
62 rdf:type schema:PublicationIssue
63 Ncf4e5b0a1b89459c9c043776fec4cc65 rdf:first sg:person.015075554137.34
64 rdf:rest N7a56e9622fb24061a51356af96781361
65 Nec662ffacae2443aa98bd1691a2f120d schema:name Springer Nature - SN SciGraph project
66 rdf:type schema:Organization
67 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
68 schema:name Chemical Sciences
69 rdf:type schema:DefinedTerm
70 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
71 schema:name Organic Chemistry
72 rdf:type schema:DefinedTerm
73 sg:journal.1022309 schema:issn 1026-3500
74 1066-5285
75 schema:name Russian Chemical Bulletin
76 schema:publisher Springer Nature
77 rdf:type schema:Periodical
78 sg:person.01222113333.75 schema:affiliation grid-institutes:grid.439283.7
79 schema:familyName Likhosherstov
80 schema:givenName L. M.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01222113333.75
82 rdf:type schema:Person
83 sg:person.014702544422.40 schema:affiliation grid-institutes:grid.439283.7
84 schema:familyName Kochetkov
85 schema:givenName N. K.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014702544422.40
87 rdf:type schema:Person
88 sg:person.015075554137.34 schema:affiliation grid-institutes:grid.439283.7
89 schema:familyName Shibaev
90 schema:givenName V. N.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015075554137.34
92 rdf:type schema:Person
93 sg:person.0641301571.82 schema:affiliation grid-institutes:grid.439283.7
94 schema:familyName Novikova
95 schema:givenName O. S.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0641301571.82
97 rdf:type schema:Person
98 grid-institutes:grid.439283.7 schema:alternateName N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation
99 schema:name N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation
100 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...