Solid-phase bromination of hindered phenols View Full Text


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Article Info

DATE

1996-05

AUTHORS

Y. B. Vol'eva, I. S. Belostotskaya, N. L. Komissarova, V. V. Ershov

ABSTRACT

The solid-Phase bromination of a series oftert-butyl-substituted phenols withN-bromosuccinimide and dioxane dibromide afforded halogenated cyclohexadienones, quinobromides. Under the extrusion conditions, the latter underwent further transformations, mainly, debromination. A new reaction, dioxane dibromide catalyzed anhydroheterocyclization of 2,2′-dihydroxy-3,3′,5,5′-tetra-tert-butyldiphenyl to 2,4,6,8-tetra-tert-butyldibenzofuran, was discovered and the mechanism of this reaction was proposed.

PAGES

1249-1251

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01431636

DOI

http://dx.doi.org/10.1007/bf01431636

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017713415


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