Reactions of 1,4-difeffocenylbuta-1,3-diyne and 1,4-diphenylbut-l-en-3-yne with Ru3(CO)12. Crystal structure of Ru3(CO)8(μ3-η-1-η1-η4-η2-C4Ph2(CH=CHPh)2) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1996-05

AUTHORS

A. A. Koridze, Y. I. Zdanovich, N. V. Andrievskaya, Yu. Siromakhova, P. V. Petrovskii, M. G. Ezernitskaya, F. M. Dolgushin, A. I. Yanovsky, Yu. T. Struchkov

ABSTRACT

Diyne FcCmCC.CFc (Fc is ferrocenyl) reacts with Ru3(CO)12 in boiling hexane to yield binuclear complexes Ru2 and Ru2(CO)6(C4Fc2(C=CFc)2C=O) containing ruthenacyclopentadiene and diruthenacycloheptadienone rings, respectively. The isomerism of the complexes is due to the different ways of coupling of the alkyne fragments of the diyne, namely, “head-to-head”, “head-to-tail” or “tail-to-tail”. The reaction of enyne PhC=CCH=CHPh with Ru3(CO)12 under similar conditions gives isomeric binuclear complexes Ru2(CO)6(C4Ph2(CH=CHPh)2) and trinuclear clusters Ru3(CO)6(w-CO)2(C4Ph2(CH=CHPh)2) and Ru3(CO)8(μ3-,η1-η1-η4-η2 C4Ph2(CH=CHPh)2). The structure of the latter was determined by X-ray diffraction analysis. The Ru3 triangle coordinates eight terminal CO groups and the organic ligand resulting from the “head-to-head” dimerization of enyne molecules; the ruthenacyclopentadiene moiety is η4-coordinated to the Ru(CO)2 group, and the third ruthenium atom is η2-bound to one of the PhCH=CH groups. More... »

PAGES

1200-1206

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01431620

DOI

http://dx.doi.org/10.1007/bf01431620

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039277600


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