Synthesis and protonation of an OS3(μ-H)(CO)10(μ-σ,η2-C≡CCMe2OMe) cluster View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1996-12

AUTHORS

V. V. Krivykh, O. A. Kizas, E. V. Vorontsov, A. A. Koridze

ABSTRACT

Triosmium cluster Os3(μ-H)(CO)10(μ-σ-η2-C≡CC Me2OMe) (1) was obtained by treating OS3(μ-H)(μ-Cl)(CO)10 with LiC≡CCMe2OMe. The reaction of cluster1 with HBF4 · Et2O at −60 °C leads to the cationic complex [Os3(μ-H)(CO)10(μ-σ,σ,η2-C=C=C Me2)]+BF4− (2) with an allenylidene ligand. Thes1H and13C NMR spectra of complex2 reveal the temperature dependence caused by migration of hydrocarbon and carbonyl ligands. Thermodynamic parameters were obtained for be exchange process of the allenylidene ligand. More... »

PAGES

2840-2842

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01430656

DOI

http://dx.doi.org/10.1007/bf01430656

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030202427


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, USSR", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Krivykh", 
        "givenName": "V. V.", 
        "id": "sg:person.07470027203.04", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07470027203.04"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, USSR", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kizas", 
        "givenName": "O. A.", 
        "id": "sg:person.013520616042.88", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013520616042.88"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, USSR", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vorontsov", 
        "givenName": "E. V.", 
        "id": "sg:person.07430741313.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07430741313.09"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, USSR", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Koridze", 
        "givenName": "A. A.", 
        "id": "sg:person.0613225461.83", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0613225461.83"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf01028385", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012243362", 
          "https://doi.org/10.1007/bf01028385"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1996-12", 
    "datePublishedReg": "1996-12-01", 
    "description": "Triosmium cluster Os3(\u03bc-H)(CO)10(\u03bc-\u03c3-\u03b72-C\u2261CC Me2OMe) (1) was obtained by treating OS3(\u03bc-H)(\u03bc-Cl)(CO)10 with LiC\u2261CCMe2OMe. The reaction of cluster1 with HBF4 \u00b7 Et2O at \u221260 \u00b0C leads to the cationic complex [Os3(\u03bc-H)(CO)10(\u03bc-\u03c3,\u03c3,\u03b72-C=C=C Me2)]+BF4\u2212 (2) with an allenylidene ligand. Thes1H and13C NMR spectra of complex2 reveal the temperature dependence caused by migration of hydrocarbon and carbonyl ligands. Thermodynamic parameters were obtained for be exchange process of the allenylidene ligand.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf01430656", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "45"
      }
    ], 
    "keywords": [
      "allenylidene ligand", 
      "and13C NMR spectra", 
      "cationic complexes", 
      "carbonyl ligands", 
      "triosmium clusters", 
      "NMR spectra", 
      "thermodynamic parameters", 
      "ligands", 
      "exchange process", 
      "HBF4", 
      "Et2O", 
      "protonation", 
      "synthesis", 
      "reaction", 
      "complexes", 
      "temperature dependence", 
      "hydrocarbons", 
      "complex2", 
      "spectra", 
      "clusters", 
      "dependence", 
      "process", 
      "migration of hydrocarbons", 
      "parameters", 
      "cluster1", 
      "migration"
    ], 
    "name": "Synthesis and protonation of an OS3(\u03bc-H)(CO)10(\u03bc-\u03c3,\u03b72-C\u2261CCMe2OMe) cluster", 
    "pagination": "2840-2842", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1030202427"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01430656"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01430656", 
      "https://app.dimensions.ai/details/publication/pub.1030202427"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-12-01T06:21", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_273.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf01430656"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01430656'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01430656'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01430656'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01430656'


 

This table displays all metadata directly associated to this object as RDF triples.

108 TRIPLES      21 PREDICATES      52 URIs      43 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01430656 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author Nda7c246e5d304be89fe01e41c12feb1e
4 schema:citation sg:pub.10.1007/bf01028385
5 schema:datePublished 1996-12
6 schema:datePublishedReg 1996-12-01
7 schema:description Triosmium cluster Os3(μ-H)(CO)10(μ-σ-η2-C≡CC Me2OMe) (1) was obtained by treating OS3(μ-H)(μ-Cl)(CO)10 with LiC≡CCMe2OMe. The reaction of cluster1 with HBF4 · Et2O at −60 °C leads to the cationic complex [Os3(μ-H)(CO)10(μ-σ,σ,η2-C=C=C Me2)]+BF4− (2) with an allenylidene ligand. Thes1H and13C NMR spectra of complex2 reveal the temperature dependence caused by migration of hydrocarbon and carbonyl ligands. Thermodynamic parameters were obtained for be exchange process of the allenylidene ligand.
8 schema:genre article
9 schema:isAccessibleForFree false
10 schema:isPartOf N049f0e07c39f4165b1ce2a8b8b0091b4
11 N6419c71c40dc4d6396b9a87a32dd8662
12 sg:journal.1022309
13 schema:keywords Et2O
14 HBF4
15 NMR spectra
16 allenylidene ligand
17 and13C NMR spectra
18 carbonyl ligands
19 cationic complexes
20 cluster1
21 clusters
22 complex2
23 complexes
24 dependence
25 exchange process
26 hydrocarbons
27 ligands
28 migration
29 migration of hydrocarbons
30 parameters
31 process
32 protonation
33 reaction
34 spectra
35 synthesis
36 temperature dependence
37 thermodynamic parameters
38 triosmium clusters
39 schema:name Synthesis and protonation of an OS3(μ-H)(CO)10(μ-σ,η2-C≡CCMe2OMe) cluster
40 schema:pagination 2840-2842
41 schema:productId N2e49d1b402104b3c92193dc1e323e9f3
42 N7e6ef65321cd4012951e12a797ff0e72
43 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030202427
44 https://doi.org/10.1007/bf01430656
45 schema:sdDatePublished 2022-12-01T06:21
46 schema:sdLicense https://scigraph.springernature.com/explorer/license/
47 schema:sdPublisher N8d563dbfe35a49d8934f454697fa8eda
48 schema:url https://doi.org/10.1007/bf01430656
49 sgo:license sg:explorer/license/
50 sgo:sdDataset articles
51 rdf:type schema:ScholarlyArticle
52 N049f0e07c39f4165b1ce2a8b8b0091b4 schema:volumeNumber 45
53 rdf:type schema:PublicationVolume
54 N2e49d1b402104b3c92193dc1e323e9f3 schema:name doi
55 schema:value 10.1007/bf01430656
56 rdf:type schema:PropertyValue
57 N31936d2b6ed7494398be98f3127da6bd rdf:first sg:person.0613225461.83
58 rdf:rest rdf:nil
59 N5c83009a866a4a198e02bea23b4ef594 rdf:first sg:person.013520616042.88
60 rdf:rest Ne95c6e3dbdf14048a6a76c9838616fb9
61 N6419c71c40dc4d6396b9a87a32dd8662 schema:issueNumber 12
62 rdf:type schema:PublicationIssue
63 N7e6ef65321cd4012951e12a797ff0e72 schema:name dimensions_id
64 schema:value pub.1030202427
65 rdf:type schema:PropertyValue
66 N8d563dbfe35a49d8934f454697fa8eda schema:name Springer Nature - SN SciGraph project
67 rdf:type schema:Organization
68 Nda7c246e5d304be89fe01e41c12feb1e rdf:first sg:person.07470027203.04
69 rdf:rest N5c83009a866a4a198e02bea23b4ef594
70 Ne95c6e3dbdf14048a6a76c9838616fb9 rdf:first sg:person.07430741313.09
71 rdf:rest N31936d2b6ed7494398be98f3127da6bd
72 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
73 schema:name Chemical Sciences
74 rdf:type schema:DefinedTerm
75 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
76 schema:name Organic Chemistry
77 rdf:type schema:DefinedTerm
78 sg:journal.1022309 schema:issn 1066-5285
79 1573-9171
80 schema:name Russian Chemical Bulletin
81 schema:publisher Springer Nature
82 rdf:type schema:Periodical
83 sg:person.013520616042.88 schema:affiliation grid-institutes:grid.431939.5
84 schema:familyName Kizas
85 schema:givenName O. A.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013520616042.88
87 rdf:type schema:Person
88 sg:person.0613225461.83 schema:affiliation grid-institutes:grid.431939.5
89 schema:familyName Koridze
90 schema:givenName A. A.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0613225461.83
92 rdf:type schema:Person
93 sg:person.07430741313.09 schema:affiliation grid-institutes:grid.431939.5
94 schema:familyName Vorontsov
95 schema:givenName E. V.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07430741313.09
97 rdf:type schema:Person
98 sg:person.07470027203.04 schema:affiliation grid-institutes:grid.431939.5
99 schema:familyName Krivykh
100 schema:givenName V. V.
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07470027203.04
102 rdf:type schema:Person
103 sg:pub.10.1007/bf01028385 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012243362
104 https://doi.org/10.1007/bf01028385
105 rdf:type schema:CreativeWork
106 grid-institutes:grid.431939.5 schema:alternateName A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, USSR
107 schema:name A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, USSR
108 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...