Viscoelastic behaviour of model polyurethane networks in the main transition zone View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1987-01

AUTHORS

A. Havránek, M. Ilavský, J. Nedbal, M. Böhm, W. v. Soden, B. Stoll

ABSTRACT

Starlike poly (oxypropylene) molecules (M=2630 resp. 710 g/mol), each with three OH-end-groups, are crosslinked with 4,4′-diphenylmethane diisocyanate in one stoichiometric and several nonstoichiometric reactions. Dynamic mechanical (frequency 10−4 to 102 Hz) and also some dielectric (10−2 to 106 Hz) measurements were made on these networks in a wide temperature range. The time-temperature-superposition principle was used to obtain master curves. Two large relaxation processes were detected (separated by many decades of frequency in some samples). The high frequency process seems to correspond to the glass-rubber transition in linear polymers, the low frequency process is probably due to the relaxation of “dangling chains”. More... »

PAGES

8-18

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01422657

DOI

http://dx.doi.org/10.1007/bf01422657

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042226759


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