Characteristics of transition state and reactivity of hydrocarbon molecules in reaction of hydrogen atom abstraction by peroxide radicals View Full Text


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Article Info

DATE

1991-07

AUTHORS

I. A. Opeida, A. F. Dmitruk, O. M. Zarechnaya

ABSTRACT

In the MINDO/3 approximation, transition states (TSs) have been found for the reaction of hydrogen atom abstraction by hydroperoxide radicals from molecules containing a C-H bond in the α-position relative to the double bond. It has been shown that the TSs have a structure with partial charge transfer, and the reactivity of the molecules depends on their electron-donor properties and the TS structure. More... »

PAGES

418-420

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01372520

DOI

http://dx.doi.org/10.1007/bf01372520

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004879413


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