Template synthesiS: Geometrical and electronic structures of the Fe nitrosyl complex formed by bis(S-methylisothiosemicarbazone)-2,4-pentandione View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1991-05

AUTHORS

N. V. Gérbéléu, V. B. Arion, Yu. A. Simonov, V. E. Zavodnik, K. I. Turté, S. S. Stavrov, A. A. Pasynskii, O. G. Ellert, D. I. Grédinaru, M. S. Byrke

ABSTRACT

Sodium acetylacetonate reacts with S-metliylisothiosemicarbazidium nitrate and Fe(NO3)3 · 9H2O in ethanol to make [Fe(HL)NO]NO3, in which H3L is bis(S-methyl-isothiosemicarbazone)-2,4-puntandione. The [Fe(HL)NO]+ cation has a square pyramidal structure with the HL2- arranged around the central ion in the basal plane and the nitrogen atom of the NO group in the apical position, with the iron atom diverging from the plane of the base of the pyramid by 0.477 Å. The FeN0 moiety has a linear structure (∠FeNO = l72.7°). XRD, IR, and Mössbauer spectroscopy have been combined with calculations on the electronic structure to demonstrate that the Fe-NO bond is covalent. More... »

PAGES

327-332

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01372503

DOI

http://dx.doi.org/10.1007/bf01372503

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017986266


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