Crystal and molecular structure of [CpRu(PPh3)2(t-C4H9SH)]BF4 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-08

AUTHORS

David Minick, M. Draganjac, Joey W. Crump, A. W. Cordes

ABSTRACT

The structure of the [CpRu(PPh3)2(t-C4H9SH)]BF4 complex was determined by X-ray diffraction techniques: monoclinic space groupP21/c,a=14.662(9),b=18.515(7),c=15.368(6)Å,β=101.88(5)°,V=4082(6)Å3,Z=4,R=0.049,Rw=0.057. The Ru is attached to two triphenylphosphine ligands, a cyclopentadienyl and thet-butylmercaptan. The Ru-S distance is 2.396(2)Å and the S-H distance is 1.289(2)Å.

PAGES

629-632

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01325185

DOI

http://dx.doi.org/10.1007/bf01325185

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000045191


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