Light-induced structural changes in sodiumnitroprusside (Na2(Fe(CN)5NO)·2D2O) at 80 K View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1991-02

AUTHORS

M. Rüdlinger, J. Schefer, G. Chevrier, N. Furer, H. U. Güdel, S. Haussühl, G. Heger, P. Schweiss, T. Vogt, T. Woike, H. Zöllner

ABSTRACT

Groundstate and electronic excited state (MSI) of deuterated sodiumnitroprusside (Na2(Fe(CN)5NO)·2D2O) have been investigated by neutron diffraction as well as by optical and Mössbauer techniques. Significant structural changes occur predominantly in the O−N−Fe−C-bond. It has been shown, that the N−O bond-length is not the order parameter, as expected from other studies. We found an increase in the bond lengths Fe−N4 of 0.019(2) Å and N−O of 0.004(4) Å respectively, which is in qualitative agreement with changes determined by Raman spectroscopy and predictions based on diatomic correlations (Badger/Herschbach/Laurie). Additionally we observed a change in the Fe−C1 bond length of 0.012(3) Å in agreement with Raman meaurements. More... »

PAGES

125-130

References to SciGraph publications

  • 1977-03. On optical dispersion in transparent molecular systems in ZEITSCHRIFT FÜR PHYSIK A HADRONS AND NUCLEI
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    http://scigraph.springernature.com/pub.10.1007/bf01314406

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    http://dx.doi.org/10.1007/bf01314406

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