Observation of87Rb NMR satellite transitions in the commensurate and incommensurate phases of Rb2ZnCl4 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1982-06

AUTHORS

E. Schneider, J. Petersson

ABSTRACT

It is shown that the first order quadrupole split NMR satellite transition frequencies of the87Rb nucleus can be detected in the paraelectric, incommensurate and ferroelectric phases of Rb2ZnCl4. From rotation patterns the electric field gradient tensor at the Rb sites is determined for the paraelectric phase. The data demonstrate a considerable influence of the structural changes in the incommensurate and ferroelectric phases on the observed NMR transition frequencies. For some crystal orientations the satellite transitions are followed through the incommensurate into the ferroelectric phase. Whereas in the former typical quasi continuous spectra are observed in the latter several sharp lines appear. The results are discussed in relation to the structural changes at the phase transitions. More... »

PAGES

169-175

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01312721

DOI

http://dx.doi.org/10.1007/bf01312721

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1038931715


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Fachbereich Physik Fachrichtung 11.3-Technische Physik, Universit\u00e4t des Saarlandes, D-6600, Saarbr\u00fccken, Federal Republic of Germany", 
          "id": "http://www.grid.ac/institutes/grid.11749.3a", 
          "name": [
            "Fachbereich Physik Fachrichtung 11.3-Technische Physik, Universit\u00e4t des Saarlandes, D-6600, Saarbr\u00fccken, Federal Republic of Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Schneider", 
        "givenName": "E.", 
        "id": "sg:person.012706070661.43", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012706070661.43"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Fachbereich Physik Fachrichtung 11.3-Technische Physik, Universit\u00e4t des Saarlandes, D-6600, Saarbr\u00fccken, Federal Republic of Germany", 
          "id": "http://www.grid.ac/institutes/grid.11749.3a", 
          "name": [
            "Fachbereich Physik Fachrichtung 11.3-Technische Physik, Universit\u00e4t des Saarlandes, D-6600, Saarbr\u00fccken, Federal Republic of Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Petersson", 
        "givenName": "J.", 
        "id": "sg:person.010265070607.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010265070607.28"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1982-06", 
    "datePublishedReg": "1982-06-01", 
    "description": "It is shown that the first order quadrupole split NMR satellite transition frequencies of the87Rb nucleus can be detected in the paraelectric, incommensurate and ferroelectric phases of Rb2ZnCl4. From rotation patterns the electric field gradient tensor at the Rb sites is determined for the paraelectric phase. The data demonstrate a considerable influence of the structural changes in the incommensurate and ferroelectric phases on the observed NMR transition frequencies. For some crystal orientations the satellite transitions are followed through the incommensurate into the ferroelectric phase. Whereas in the former typical quasi continuous spectra are observed in the latter several sharp lines appear. The results are discussed in relation to the structural changes at the phase transitions.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf01312721", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1285002", 
        "issn": [
          "0722-3277", 
          "1431-584X"
        ], 
        "name": "Zeitschrift f\u00fcr Physik B Condensed Matter", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "46"
      }
    ], 
    "keywords": [
      "ferroelectric phase", 
      "quasi-continuous spectrum", 
      "gradient tensor", 
      "crystal orientation", 
      "paraelectric phase", 
      "considerable influence", 
      "phase", 
      "phase transition", 
      "electric field gradient tensor", 
      "structural changes", 
      "first-order quadrupole", 
      "field gradient tensor", 
      "frequency", 
      "transition frequencies", 
      "transition", 
      "incommensurate phase", 
      "continuous spectrum", 
      "influence", 
      "orientation", 
      "rotation pattern", 
      "tensor", 
      "Rb2ZnCl4", 
      "results", 
      "satellite transitions", 
      "spectra", 
      "quadrupole", 
      "incommensurate", 
      "changes", 
      "lines", 
      "data", 
      "Rb sites", 
      "sharp lines", 
      "sites", 
      "relation", 
      "patterns", 
      "nucleus"
    ], 
    "name": "Observation of87Rb NMR satellite transitions in the commensurate and incommensurate phases of Rb2ZnCl4", 
    "pagination": "169-175", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1038931715"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01312721"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01312721", 
      "https://app.dimensions.ai/details/publication/pub.1038931715"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-10-01T06:27", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221001/entities/gbq_results/article/article_170.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf01312721"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01312721'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01312721'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01312721'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01312721'


 

This table displays all metadata directly associated to this object as RDF triples.

100 TRIPLES      20 PREDICATES      61 URIs      53 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01312721 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author Na26aa0c34e4045cd8ab0a903ea99a383
4 schema:datePublished 1982-06
5 schema:datePublishedReg 1982-06-01
6 schema:description It is shown that the first order quadrupole split NMR satellite transition frequencies of the87Rb nucleus can be detected in the paraelectric, incommensurate and ferroelectric phases of Rb2ZnCl4. From rotation patterns the electric field gradient tensor at the Rb sites is determined for the paraelectric phase. The data demonstrate a considerable influence of the structural changes in the incommensurate and ferroelectric phases on the observed NMR transition frequencies. For some crystal orientations the satellite transitions are followed through the incommensurate into the ferroelectric phase. Whereas in the former typical quasi continuous spectra are observed in the latter several sharp lines appear. The results are discussed in relation to the structural changes at the phase transitions.
7 schema:genre article
8 schema:isAccessibleForFree false
9 schema:isPartOf N8685f56c3ce34260bf80ef55b3f05488
10 N97dd5f02f9e348aebe17b6b57bb52532
11 sg:journal.1285002
12 schema:keywords Rb sites
13 Rb2ZnCl4
14 changes
15 considerable influence
16 continuous spectrum
17 crystal orientation
18 data
19 electric field gradient tensor
20 ferroelectric phase
21 field gradient tensor
22 first-order quadrupole
23 frequency
24 gradient tensor
25 incommensurate
26 incommensurate phase
27 influence
28 lines
29 nucleus
30 orientation
31 paraelectric phase
32 patterns
33 phase
34 phase transition
35 quadrupole
36 quasi-continuous spectrum
37 relation
38 results
39 rotation pattern
40 satellite transitions
41 sharp lines
42 sites
43 spectra
44 structural changes
45 tensor
46 transition
47 transition frequencies
48 schema:name Observation of87Rb NMR satellite transitions in the commensurate and incommensurate phases of Rb2ZnCl4
49 schema:pagination 169-175
50 schema:productId N178bc9d65d9644fd8c54869dd10dbd0a
51 N522d46e633b1400e9084416bd4576cd2
52 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038931715
53 https://doi.org/10.1007/bf01312721
54 schema:sdDatePublished 2022-10-01T06:27
55 schema:sdLicense https://scigraph.springernature.com/explorer/license/
56 schema:sdPublisher N1e12e55ed5cc4cb6b746a8b6cccc14ff
57 schema:url https://doi.org/10.1007/bf01312721
58 sgo:license sg:explorer/license/
59 sgo:sdDataset articles
60 rdf:type schema:ScholarlyArticle
61 N178bc9d65d9644fd8c54869dd10dbd0a schema:name dimensions_id
62 schema:value pub.1038931715
63 rdf:type schema:PropertyValue
64 N1e12e55ed5cc4cb6b746a8b6cccc14ff schema:name Springer Nature - SN SciGraph project
65 rdf:type schema:Organization
66 N522d46e633b1400e9084416bd4576cd2 schema:name doi
67 schema:value 10.1007/bf01312721
68 rdf:type schema:PropertyValue
69 N8685f56c3ce34260bf80ef55b3f05488 schema:volumeNumber 46
70 rdf:type schema:PublicationVolume
71 N8dc8644f323a4896bc9143eab6414042 rdf:first sg:person.010265070607.28
72 rdf:rest rdf:nil
73 N97dd5f02f9e348aebe17b6b57bb52532 schema:issueNumber 2
74 rdf:type schema:PublicationIssue
75 Na26aa0c34e4045cd8ab0a903ea99a383 rdf:first sg:person.012706070661.43
76 rdf:rest N8dc8644f323a4896bc9143eab6414042
77 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
78 schema:name Chemical Sciences
79 rdf:type schema:DefinedTerm
80 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
81 schema:name Inorganic Chemistry
82 rdf:type schema:DefinedTerm
83 sg:journal.1285002 schema:issn 0722-3277
84 1431-584X
85 schema:name Zeitschrift für Physik B Condensed Matter
86 schema:publisher Springer Nature
87 rdf:type schema:Periodical
88 sg:person.010265070607.28 schema:affiliation grid-institutes:grid.11749.3a
89 schema:familyName Petersson
90 schema:givenName J.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010265070607.28
92 rdf:type schema:Person
93 sg:person.012706070661.43 schema:affiliation grid-institutes:grid.11749.3a
94 schema:familyName Schneider
95 schema:givenName E.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012706070661.43
97 rdf:type schema:Person
98 grid-institutes:grid.11749.3a schema:alternateName Fachbereich Physik Fachrichtung 11.3-Technische Physik, Universität des Saarlandes, D-6600, Saarbrücken, Federal Republic of Germany
99 schema:name Fachbereich Physik Fachrichtung 11.3-Technische Physik, Universität des Saarlandes, D-6600, Saarbrücken, Federal Republic of Germany
100 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...