Molecular structures of [CpRu(PPh3)(dtoxa-H2O)]BF4 and {[CpRu(PPh3)2]2(μ-dtoxa)}(BF4)2, dtoxa=dithiooxamide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-04

AUTHORS

M. Draganjac, David Minick, A. W. Cordes

ABSTRACT

The reaction of [CpRu(PPh3)2(n-C3H7SH)]BF4 with dithiooxamide (dtoxa) gave two products: {[CpRu(PPh3)2]2(μ-dtoxa)} (BF4)2,1, and [CpRu(PPh3)(dtoxa-H2O)]BF4,2. The structures of both complexes were determined by X-ray diffraction techniques. Compound1 crystallized in the triclinic space groupP¯1,a=12.822(4),b=14.16(1),c=23.631(8) Å,α=84.57(4),β=83.64(3), γ=83.57(4)°,Z=2,R=0.069,Rw=0.084. The structure of1 shows two CpRu(PPh3)2+ units bridged through the S atoms of the dtoxa ligand. Ru-S distances are 2.377(6)Å for Ru1-S1 and 2.368(6) Å for Ru2-S2. Compound2 crystallized in the monoclinic space groupP21/c,a=13.446(3),b=13.461(7),c=31.214(7) Å,β=100.78(3)°,Z=8,R=0.054,Rw=0.055. The structure of2 has two molecules in the asymmetric unit. The Ru is chelated to the dtoxa through the S atoms: Ru1-S1, 2.307(4); Ru1-S2, 2.300(4); Ru2-S3, 2.295(4); Ru2-S4, 2.287(4) Å. The coordination sphere of the Ru in2 is completed by a cyclopentadienyl ligand and a triphenylphosphine. More... »

PAGES

265-271

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01263585

DOI

http://dx.doi.org/10.1007/bf01263585

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004787321


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "name": [
            "Department of Chemistry and Biochemistry, Arkansas State University, 72467, State University, Arkansas"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Draganjac", 
        "givenName": "M.", 
        "id": "sg:person.013230634754.21", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013230634754.21"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Department of Chemistry and Biochemistry, Arkansas State University, 72467, State University, Arkansas"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Minick", 
        "givenName": "David", 
        "id": "sg:person.012563157067.50", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012563157067.50"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Arkansas at Fayetteville", 
          "id": "https://www.grid.ac/institutes/grid.411017.2", 
          "name": [
            "Department of Chemistry and Biochemistry, University of Arkansas, 72701, Fayetteville, Arkansas"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Cordes", 
        "givenName": "A. W.", 
        "id": "sg:person.012661461307.69", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012661461307.69"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1039/c39850000188", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017287960"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9517(81)90303-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019405968"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01227122", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031596398", 
          "https://doi.org/10.1007/bf01227122"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0365110x64002067", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039037964"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9517(84)90366-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045259115"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00031a005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055538870"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00260a001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055549508"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00267a023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055549808"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00319a024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055551963"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00335a013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055552555"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50189a014", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055578168"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1993-04", 
    "datePublishedReg": "1993-04-01", 
    "description": "The reaction of [CpRu(PPh3)2(n-C3H7SH)]BF4 with dithiooxamide (dtoxa) gave two products: {[CpRu(PPh3)2]2(\u03bc-dtoxa)} (BF4)2,1, and [CpRu(PPh3)(dtoxa-H2O)]BF4,2. The structures of both complexes were determined by X-ray diffraction techniques. Compound1 crystallized in the triclinic space groupP\u00af1,a=12.822(4),b=14.16(1),c=23.631(8) \u00c5,\u03b1=84.57(4),\u03b2=83.64(3), \u03b3=83.57(4)\u00b0,Z=2,R=0.069,Rw=0.084. The structure of1 shows two CpRu(PPh3)2+ units bridged through the S atoms of the dtoxa ligand. Ru-S distances are 2.377(6)\u00c5 for Ru1-S1 and 2.368(6) \u00c5 for Ru2-S2. Compound2 crystallized in the monoclinic space groupP21/c,a=13.446(3),b=13.461(7),c=31.214(7) \u00c5,\u03b2=100.78(3)\u00b0,Z=8,R=0.054,Rw=0.055. The structure of2 has two molecules in the asymmetric unit. The Ru is chelated to the dtoxa through the S atoms: Ru1-S1, 2.307(4); Ru1-S2, 2.300(4); Ru2-S3, 2.295(4); Ru2-S4, 2.287(4) \u00c5. The coordination sphere of the Ru in2 is completed by a cyclopentadienyl ligand and a triphenylphosphine.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf01263585", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1093566", 
        "issn": [
          "1074-1542", 
          "1572-8854"
        ], 
        "name": "Journal of Chemical Crystallography", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "23"
      }
    ], 
    "name": "Molecular structures of [CpRu(PPh3)(dtoxa-H2O)]BF4 and {[CpRu(PPh3)2]2(\u03bc-dtoxa)}(BF4)2, dtoxa=dithiooxamide", 
    "pagination": "265-271", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "16cfb594c720565b6ebf5752aee18a7c604affdd75c6a583618416d56c506470"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01263585"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1004787321"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01263585", 
      "https://app.dimensions.ai/details/publication/pub.1004787321"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:33", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000370_0000000370/records_46769_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/BF01263585"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01263585'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01263585'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01263585'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01263585'


 

This table displays all metadata directly associated to this object as RDF triples.

113 TRIPLES      21 PREDICATES      38 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01263585 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N0c5f4e132bc34343ad2784cbd0c4f533
4 schema:citation sg:pub.10.1007/bf01227122
5 https://doi.org/10.1016/0021-9517(81)90303-1
6 https://doi.org/10.1016/0021-9517(84)90366-x
7 https://doi.org/10.1021/ic00031a005
8 https://doi.org/10.1021/ic00260a001
9 https://doi.org/10.1021/ic00267a023
10 https://doi.org/10.1021/ic00319a024
11 https://doi.org/10.1021/ic00335a013
12 https://doi.org/10.1021/ic50189a014
13 https://doi.org/10.1039/c39850000188
14 https://doi.org/10.1107/s0365110x64002067
15 schema:datePublished 1993-04
16 schema:datePublishedReg 1993-04-01
17 schema:description The reaction of [CpRu(PPh3)2(n-C3H7SH)]BF4 with dithiooxamide (dtoxa) gave two products: {[CpRu(PPh3)2]2(μ-dtoxa)} (BF4)2,1, and [CpRu(PPh3)(dtoxa-H2O)]BF4,2. The structures of both complexes were determined by X-ray diffraction techniques. Compound1 crystallized in the triclinic space groupP¯1,a=12.822(4),b=14.16(1),c=23.631(8) Å,α=84.57(4),β=83.64(3), γ=83.57(4)°,Z=2,R=0.069,Rw=0.084. The structure of1 shows two CpRu(PPh3)2+ units bridged through the S atoms of the dtoxa ligand. Ru-S distances are 2.377(6)Å for Ru1-S1 and 2.368(6) Å for Ru2-S2. Compound2 crystallized in the monoclinic space groupP21/c,a=13.446(3),b=13.461(7),c=31.214(7) Å,β=100.78(3)°,Z=8,R=0.054,Rw=0.055. The structure of2 has two molecules in the asymmetric unit. The Ru is chelated to the dtoxa through the S atoms: Ru1-S1, 2.307(4); Ru1-S2, 2.300(4); Ru2-S3, 2.295(4); Ru2-S4, 2.287(4) Å. The coordination sphere of the Ru in2 is completed by a cyclopentadienyl ligand and a triphenylphosphine.
18 schema:genre research_article
19 schema:inLanguage en
20 schema:isAccessibleForFree false
21 schema:isPartOf N03dc116895ba481d89ed1745bd477465
22 Naf19495b5da64bf39dbff8e87fb58cb4
23 sg:journal.1093566
24 schema:name Molecular structures of [CpRu(PPh3)(dtoxa-H2O)]BF4 and {[CpRu(PPh3)2]2(μ-dtoxa)}(BF4)2, dtoxa=dithiooxamide
25 schema:pagination 265-271
26 schema:productId N65260dca608546638eb7c4adedef2e1a
27 Na1a27e83a9ce4c1c8025fdaa18ca9064
28 Nb351268e08e54b73903a7bb3c6698e80
29 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004787321
30 https://doi.org/10.1007/bf01263585
31 schema:sdDatePublished 2019-04-11T13:33
32 schema:sdLicense https://scigraph.springernature.com/explorer/license/
33 schema:sdPublisher Nc0f08e152ad249c9a938d34d726e4ed2
34 schema:url http://link.springer.com/10.1007/BF01263585
35 sgo:license sg:explorer/license/
36 sgo:sdDataset articles
37 rdf:type schema:ScholarlyArticle
38 N03dc116895ba481d89ed1745bd477465 schema:issueNumber 4
39 rdf:type schema:PublicationIssue
40 N0c5f4e132bc34343ad2784cbd0c4f533 rdf:first sg:person.013230634754.21
41 rdf:rest N9a116fb32d304b1a81760f8eba7d730b
42 N65260dca608546638eb7c4adedef2e1a schema:name readcube_id
43 schema:value 16cfb594c720565b6ebf5752aee18a7c604affdd75c6a583618416d56c506470
44 rdf:type schema:PropertyValue
45 N917d1ca866a64ad5b4bce42d3e134283 rdf:first sg:person.012661461307.69
46 rdf:rest rdf:nil
47 N9682daffc11f474eae859cf24405832b schema:name Department of Chemistry and Biochemistry, Arkansas State University, 72467, State University, Arkansas
48 rdf:type schema:Organization
49 N9a116fb32d304b1a81760f8eba7d730b rdf:first sg:person.012563157067.50
50 rdf:rest N917d1ca866a64ad5b4bce42d3e134283
51 Na1a27e83a9ce4c1c8025fdaa18ca9064 schema:name doi
52 schema:value 10.1007/bf01263585
53 rdf:type schema:PropertyValue
54 Nac151dc772504e50844344e1579370e2 schema:name Department of Chemistry and Biochemistry, Arkansas State University, 72467, State University, Arkansas
55 rdf:type schema:Organization
56 Naf19495b5da64bf39dbff8e87fb58cb4 schema:volumeNumber 23
57 rdf:type schema:PublicationVolume
58 Nb351268e08e54b73903a7bb3c6698e80 schema:name dimensions_id
59 schema:value pub.1004787321
60 rdf:type schema:PropertyValue
61 Nc0f08e152ad249c9a938d34d726e4ed2 schema:name Springer Nature - SN SciGraph project
62 rdf:type schema:Organization
63 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
64 schema:name Chemical Sciences
65 rdf:type schema:DefinedTerm
66 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
67 schema:name Inorganic Chemistry
68 rdf:type schema:DefinedTerm
69 sg:journal.1093566 schema:issn 1074-1542
70 1572-8854
71 schema:name Journal of Chemical Crystallography
72 rdf:type schema:Periodical
73 sg:person.012563157067.50 schema:affiliation Nac151dc772504e50844344e1579370e2
74 schema:familyName Minick
75 schema:givenName David
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012563157067.50
77 rdf:type schema:Person
78 sg:person.012661461307.69 schema:affiliation https://www.grid.ac/institutes/grid.411017.2
79 schema:familyName Cordes
80 schema:givenName A. W.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012661461307.69
82 rdf:type schema:Person
83 sg:person.013230634754.21 schema:affiliation N9682daffc11f474eae859cf24405832b
84 schema:familyName Draganjac
85 schema:givenName M.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013230634754.21
87 rdf:type schema:Person
88 sg:pub.10.1007/bf01227122 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031596398
89 https://doi.org/10.1007/bf01227122
90 rdf:type schema:CreativeWork
91 https://doi.org/10.1016/0021-9517(81)90303-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019405968
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1016/0021-9517(84)90366-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1045259115
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1021/ic00031a005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055538870
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1021/ic00260a001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055549508
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1021/ic00267a023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055549808
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1021/ic00319a024 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055551963
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1021/ic00335a013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055552555
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1021/ic50189a014 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055578168
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1039/c39850000188 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017287960
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1107/s0365110x64002067 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039037964
110 rdf:type schema:CreativeWork
111 https://www.grid.ac/institutes/grid.411017.2 schema:alternateName University of Arkansas at Fayetteville
112 schema:name Department of Chemistry and Biochemistry, University of Arkansas, 72701, Fayetteville, Arkansas
113 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...