Synthesis and spectroscopic features of bis(tetramethylammonium) and bis(benzyltriethylammonium) salts possessing a μ-oxo-bis(trichloroferrate) anion structure View Full Text


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Article Info

DATE

1984-06

AUTHORS

Eberhard W. Neuse, Maria G. Meirim

ABSTRACT

The two μ-oxo-bis(trichloroferrate) salts (1) and (3) with diamagnetic ammonium cations are prepared as prototype compounds possessing an oxo-bridged dimer anion structure in which each iron(III) centre coordinates tetrahedrally to the three Cl ligands in addition to the bridging ligand. Antiferromagnetic coupling between the two iron centres in the anion complex is indicated by the low room-temperature effective magnetic moments (1.71–1.74 μB). The i.r. and electronic absorption spectra are in accord with the proposed anionic oxygen bridge structure. More... »

PAGES

205-208

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01227119

DOI

http://dx.doi.org/10.1007/bf01227119

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043040852


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