Synthesis and spectroscopic features of bis(tetramethylammonium) and bis(benzyltriethylammonium) salts possessing a μ-oxo-bis(trichloroferrate) anion structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1984-06

AUTHORS

Eberhard W. Neuse, Maria G. Meirim

ABSTRACT

The two μ-oxo-bis(trichloroferrate) salts (1) and (3) with diamagnetic ammonium cations are prepared as prototype compounds possessing an oxo-bridged dimer anion structure in which each iron(III) centre coordinates tetrahedrally to the three Cl ligands in addition to the bridging ligand. Antiferromagnetic coupling between the two iron centres in the anion complex is indicated by the low room-temperature effective magnetic moments (1.71–1.74 μB). The i.r. and electronic absorption spectra are in accord with the proposed anionic oxygen bridge structure. More... »

PAGES

205-208

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01227119

DOI

http://dx.doi.org/10.1007/bf01227119

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043040852


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, University of the Witwatersrand, Johannesburg, RSA", 
          "id": "http://www.grid.ac/institutes/grid.11951.3d", 
          "name": [
            "Department of Chemistry, University of the Witwatersrand, Johannesburg, RSA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Neuse", 
        "givenName": "Eberhard W.", 
        "id": "sg:person.013222105727.64", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013222105727.64"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, University of the Witwatersrand, Johannesburg, RSA", 
          "id": "http://www.grid.ac/institutes/grid.11951.3d", 
          "name": [
            "Department of Chemistry, University of the Witwatersrand, Johannesburg, RSA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Meirim", 
        "givenName": "Maria G.", 
        "id": "sg:person.012246571065.19", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012246571065.19"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1984-06", 
    "datePublishedReg": "1984-06-01", 
    "description": "The two \u03bc-oxo-bis(trichloroferrate) salts (1) and (3) with diamagnetic ammonium cations are prepared as prototype compounds possessing an oxo-bridged dimer anion structure in which each iron(III) centre coordinates tetrahedrally to the three Cl ligands in addition to the bridging ligand. Antiferromagnetic coupling between the two iron centres in the anion complex is indicated by the low room-temperature effective magnetic moments (1.71\u20131.74 \u03bcB). The i.r. and electronic absorption spectra are in accord with the proposed anionic oxygen bridge structure.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf01227119", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136539", 
        "issn": [
          "0340-4285", 
          "1572-901X"
        ], 
        "name": "Transition Metal Chemistry", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "9"
      }
    ], 
    "keywords": [
      "anion structure", 
      "\u03bc-oxo", 
      "room temperature effective magnetic moment", 
      "electronic absorption spectra", 
      "oxygen-bridged structure", 
      "anion complexes", 
      "iron center", 
      "Cl ligands", 
      "ammonium cations", 
      "effective magnetic moment", 
      "spectroscopic features", 
      "antiferromagnetic coupling", 
      "absorption spectra", 
      "prototype compounds", 
      "ligands", 
      "salt", 
      "magnetic moment", 
      "cations", 
      "structure", 
      "compounds", 
      "synthesis", 
      "complexes", 
      "spectra", 
      "coupling", 
      "accord", 
      "addition", 
      "center", 
      "bridge structure", 
      "moment", 
      "features"
    ], 
    "name": "Synthesis and spectroscopic features of bis(tetramethylammonium) and bis(benzyltriethylammonium) salts possessing a \u03bc-oxo-bis(trichloroferrate) anion structure", 
    "pagination": "205-208", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1043040852"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01227119"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01227119", 
      "https://app.dimensions.ai/details/publication/pub.1043040852"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-12-01T06:18", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_168.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf01227119"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01227119'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01227119'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01227119'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01227119'


 

This table displays all metadata directly associated to this object as RDF triples.

94 TRIPLES      20 PREDICATES      55 URIs      47 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01227119 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N2a06321f71774f55b90c9fa92ca8835b
4 schema:datePublished 1984-06
5 schema:datePublishedReg 1984-06-01
6 schema:description The two μ-oxo-bis(trichloroferrate) salts (1) and (3) with diamagnetic ammonium cations are prepared as prototype compounds possessing an oxo-bridged dimer anion structure in which each iron(III) centre coordinates tetrahedrally to the three Cl ligands in addition to the bridging ligand. Antiferromagnetic coupling between the two iron centres in the anion complex is indicated by the low room-temperature effective magnetic moments (1.71–1.74 μB). The i.r. and electronic absorption spectra are in accord with the proposed anionic oxygen bridge structure.
7 schema:genre article
8 schema:isAccessibleForFree false
9 schema:isPartOf N0b09830e5adc4010a16fe2ed7f38be27
10 N76228391d75440ffa29972b1ddda2aed
11 sg:journal.1136539
12 schema:keywords Cl ligands
13 absorption spectra
14 accord
15 addition
16 ammonium cations
17 anion complexes
18 anion structure
19 antiferromagnetic coupling
20 bridge structure
21 cations
22 center
23 complexes
24 compounds
25 coupling
26 effective magnetic moment
27 electronic absorption spectra
28 features
29 iron center
30 ligands
31 magnetic moment
32 moment
33 oxygen-bridged structure
34 prototype compounds
35 room temperature effective magnetic moment
36 salt
37 spectra
38 spectroscopic features
39 structure
40 synthesis
41 μ-oxo
42 schema:name Synthesis and spectroscopic features of bis(tetramethylammonium) and bis(benzyltriethylammonium) salts possessing a μ-oxo-bis(trichloroferrate) anion structure
43 schema:pagination 205-208
44 schema:productId N7042d169a2b4481c95ca8754ddd747de
45 N99abaa368f3d466589e040ea49a2d36c
46 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043040852
47 https://doi.org/10.1007/bf01227119
48 schema:sdDatePublished 2022-12-01T06:18
49 schema:sdLicense https://scigraph.springernature.com/explorer/license/
50 schema:sdPublisher N70fa343bb6ac440faf1c77a783d67f67
51 schema:url https://doi.org/10.1007/bf01227119
52 sgo:license sg:explorer/license/
53 sgo:sdDataset articles
54 rdf:type schema:ScholarlyArticle
55 N0b09830e5adc4010a16fe2ed7f38be27 schema:volumeNumber 9
56 rdf:type schema:PublicationVolume
57 N2a06321f71774f55b90c9fa92ca8835b rdf:first sg:person.013222105727.64
58 rdf:rest Nc69142be873c49aaa45afd1ea9373268
59 N7042d169a2b4481c95ca8754ddd747de schema:name doi
60 schema:value 10.1007/bf01227119
61 rdf:type schema:PropertyValue
62 N70fa343bb6ac440faf1c77a783d67f67 schema:name Springer Nature - SN SciGraph project
63 rdf:type schema:Organization
64 N76228391d75440ffa29972b1ddda2aed schema:issueNumber 6
65 rdf:type schema:PublicationIssue
66 N99abaa368f3d466589e040ea49a2d36c schema:name dimensions_id
67 schema:value pub.1043040852
68 rdf:type schema:PropertyValue
69 Nc69142be873c49aaa45afd1ea9373268 rdf:first sg:person.012246571065.19
70 rdf:rest rdf:nil
71 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
72 schema:name Chemical Sciences
73 rdf:type schema:DefinedTerm
74 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
75 schema:name Inorganic Chemistry
76 rdf:type schema:DefinedTerm
77 sg:journal.1136539 schema:issn 0340-4285
78 1572-901X
79 schema:name Transition Metal Chemistry
80 schema:publisher Springer Nature
81 rdf:type schema:Periodical
82 sg:person.012246571065.19 schema:affiliation grid-institutes:grid.11951.3d
83 schema:familyName Meirim
84 schema:givenName Maria G.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012246571065.19
86 rdf:type schema:Person
87 sg:person.013222105727.64 schema:affiliation grid-institutes:grid.11951.3d
88 schema:familyName Neuse
89 schema:givenName Eberhard W.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013222105727.64
91 rdf:type schema:Person
92 grid-institutes:grid.11951.3d schema:alternateName Department of Chemistry, University of the Witwatersrand, Johannesburg, RSA
93 schema:name Department of Chemistry, University of the Witwatersrand, Johannesburg, RSA
94 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...