Steroids and related studies, Part LIII. Structure and function of synthetic bisquaternary aza steroidal neuromuscular blocking agents View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1980-04

AUTHORS

Rex A. Palmer, Mohammed A. Kalam, Harkishan Singh, Dharam Paul

ABSTRACT

The molecular structures of three dimethiodide bisquaternary aza steroids, determined crystallographically, are reported. The compounds are (i) 17a-methyl-3β-pyrrolidino-17a-aza-d-homo-5-androstene dimethiodide (HS310, or chandonium iodide), (ii) 4,17a-dimethyl-4, 17a-diaza-d-homo-5α-androstane dimethiodide (HS342), and (iii) 4-methyl-17β-dimethylamino-4-aza-5α-androstane dimethiodide (HS467). RingB in HS310 is a half-chair and ringD in HS467 is a distorted envelope. All other rings in the steroid skeletons of the three molecules are in the chair conformation, and all rings aretrans-connected. All three molecules are known to exhibit competitive neuromuscular blocking activity, each with different potency. This is discussed in relation to the observed inter-onium N+ ⋯ N+ distances and other features of molecular geometry of importance in drug design. More... »

PAGES

31-53

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01209551

DOI

http://dx.doi.org/10.1007/bf01209551

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050799426


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