Synthesis and structure of 1-(2-amino)phenyl-2-phenyl-12H-indolo[3,2-c]carbazole ethylacetate solvate, a new indolocarbazole compound View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1989-04

AUTHORS

Paolo Domiano, Vittorio Bocchi, Gerardo Palla

ABSTRACT

The structure of a new indolo-carbazole compound, unique in having two indole rings with NH groupstrans-fused to a phenyl ring, has been determined by X-ray crystallography. The crystals are monoclinic, space groupP21/n,a=25.548(7),b=8.532(3),c=12.594(4) Å,β=93.50(2)°,Vc=2740.1(2) Å3,Z=4,Dk=1.240 g cm−3, λ (CuKα)=1.54178 Å,μ=5.79 cm−1,F(000)=1080,R=0.071,Rw=0.080 for 2939 unique significant reflections measured at 298 K. The crystals retain one mole of ethyl acetate per molecule, which shows disorder. Restricted rotation of the phenyl and aminophenyl groups was detected by13C nmr. The title Indolo-carbazoles are easily obtained by reaction of 3-bromoindoles with 2,3′-biindolyls and show an interesting planar structure which could be investigated for anticancer properties. More... »

PAGES

277-287

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01194123

DOI

http://dx.doi.org/10.1007/bf01194123

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009574740


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