Ontology type: schema:ScholarlyArticle
1984-12
AUTHORS ABSTRACTThe partitioning of Fe and Mg between garnet and aluminous orthopyroxene has been experimentally investigated in the pressure-temperature range 5–30 kbar and 800–1,200° C in the FeO-MgO-Al2O3-SiO2 (FMAS) and CaO-FeO-MgO-Al2O3-SiO2 (CFMAS) systems. Within the errors of the experimental data, orthopyroxene can be regarded as macroscopically ideal. The effects of Calcium on Fe-Mg partitioning between garnet and orthopyroxene can be attributed to non-ideal Ca-Mg interactions in the garnet, described by the interaction term:WCaMgga-WCaFega=1,400±500 cal/mol site.Reduction of the experimental data, combined with molar volume data for the end-member phases, permits the calibration of a geothermometer which is applicable to garnet peridotites and granulites:\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$T(^\circ C) = \left\{ {\frac{{3,740 + 1,400X_{gr}^{ga} + 22.86P(kb)}}{{R\ln K_D + 1.96}}} \right\} - 273$$ \end{document} with\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$K_D = {{\left\{ {\frac{{Fe}}{{Mg}}} \right\}^{ga} } \mathord{\left/ {\vphantom {{\left\{ {\frac{{Fe}}{{Mg}}} \right\}^{ga} } {\left\{ {\frac{{Fe}}{{Mg}}} \right\}}}} \right. \kern-\nulldelimiterspace} {\left\{ {\frac{{Fe}}{{Mg}}} \right\}}}$$ \end{document} and\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$X_{gr}^{ga} = (Ca/Ca + Mg + Fe)^{ga} .$$ \end{document}The accuracy and precision of this geothermometer are limited by largerelative errors in the experimental and natural-rock data and by the modest absolute variation inKD with temperature. Nevertheless, the geothermometer is shown to yield reasonable temperature estimates for a variety of natural samples. More... »
PAGES359-373
http://scigraph.springernature.com/pub.10.1007/bf01187140
DOIhttp://dx.doi.org/10.1007/bf01187140
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1013412604
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/04",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Earth Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0403",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Geology",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Department of Geology, University of Tasmania, GPO Box 252C, Hobart, Tasmania, Australia",
"id": "http://www.grid.ac/institutes/grid.1009.8",
"name": [
"Department of Geology, University of Tasmania, GPO Box 252C, Hobart, Tasmania, Australia"
],
"type": "Organization"
},
"familyName": "Harley",
"givenName": "Simon L.",
"id": "sg:person.01275544350.30",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01275544350.30"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/bf00371878",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025730498",
"https://doi.org/10.1007/bf00371878"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00518120",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1010042657",
"https://doi.org/10.1007/bf00518120"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00370968",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1051503504",
"https://doi.org/10.1007/bf00370968"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf01132001",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1018102980",
"https://doi.org/10.1007/bf01132001"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00371667",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1004963450",
"https://doi.org/10.1007/bf00371667"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/978-3-642-65558-6",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1019113354",
"https://doi.org/10.1007/978-3-642-65558-6"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00375284",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1010434460",
"https://doi.org/10.1007/bf00375284"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00372076",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1035108904",
"https://doi.org/10.1007/bf00372076"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00377416",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1014263801",
"https://doi.org/10.1007/bf00377416"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00418613",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1044507419",
"https://doi.org/10.1007/bf00418613"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00372836",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1024544652",
"https://doi.org/10.1007/bf00372836"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00372150",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039488171",
"https://doi.org/10.1007/bf00372150"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00372872",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1033443201",
"https://doi.org/10.1007/bf00372872"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00375446",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039868278",
"https://doi.org/10.1007/bf00375446"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/300697a0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021390214",
"https://doi.org/10.1038/300697a0"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00373879",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039605524",
"https://doi.org/10.1007/bf00373879"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1038/273220a0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1011411848",
"https://doi.org/10.1038/273220a0"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00418615",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1026053664",
"https://doi.org/10.1007/bf00418615"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00399481",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021826900",
"https://doi.org/10.1007/bf00399481"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00383299",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1039268374",
"https://doi.org/10.1007/bf00383299"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf00371872",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025043342",
"https://doi.org/10.1007/bf00371872"
],
"type": "CreativeWork"
}
],
"datePublished": "1984-12",
"datePublishedReg": "1984-12-01",
"description": "The partitioning of Fe and Mg between garnet and aluminous orthopyroxene has been experimentally investigated in the pressure-temperature range 5\u201330 kbar and 800\u20131,200\u00b0 C in the FeO-MgO-Al2O3-SiO2 (FMAS) and CaO-FeO-MgO-Al2O3-SiO2 (CFMAS) systems. Within the errors of the experimental data, orthopyroxene can be regarded as macroscopically ideal. The effects of Calcium on Fe-Mg partitioning between garnet and orthopyroxene can be attributed to non-ideal Ca-Mg interactions in the garnet, described by the interaction term:WCaMgga-WCaFega=1,400\u00b1500 cal/mol site.Reduction of the experimental data, combined with molar volume data for the end-member phases, permits the calibration of a geothermometer which is applicable to garnet peridotites and granulites:\\documentclass[12pt]{minimal}\n\t\t\t\t\\usepackage{amsmath}\n\t\t\t\t\\usepackage{wasysym}\n\t\t\t\t\\usepackage{amsfonts}\n\t\t\t\t\\usepackage{amssymb}\n\t\t\t\t\\usepackage{amsbsy}\n\t\t\t\t\\usepackage{mathrsfs}\n\t\t\t\t\\usepackage{upgreek}\n\t\t\t\t\\setlength{\\oddsidemargin}{-69pt}\n\t\t\t\t\\begin{document}\n$$T(^\\circ C) = \\left\\{ {\\frac{{3,740 + 1,400X_{gr}^{ga} + 22.86P(kb)}}{{R\\ln K_D + 1.96}}} \\right\\} - 273$$\n\\end{document} with\\documentclass[12pt]{minimal}\n\t\t\t\t\\usepackage{amsmath}\n\t\t\t\t\\usepackage{wasysym}\n\t\t\t\t\\usepackage{amsfonts}\n\t\t\t\t\\usepackage{amssymb}\n\t\t\t\t\\usepackage{amsbsy}\n\t\t\t\t\\usepackage{mathrsfs}\n\t\t\t\t\\usepackage{upgreek}\n\t\t\t\t\\setlength{\\oddsidemargin}{-69pt}\n\t\t\t\t\\begin{document}\n$$K_D = {{\\left\\{ {\\frac{{Fe}}{{Mg}}} \\right\\}^{ga} } \\mathord{\\left/ {\\vphantom {{\\left\\{ {\\frac{{Fe}}{{Mg}}} \\right\\}^{ga} } {\\left\\{ {\\frac{{Fe}}{{Mg}}} \\right\\}}}} \\right. \\kern-\\nulldelimiterspace} {\\left\\{ {\\frac{{Fe}}{{Mg}}} \\right\\}}}$$\n\\end{document} and\\documentclass[12pt]{minimal}\n\t\t\t\t\\usepackage{amsmath}\n\t\t\t\t\\usepackage{wasysym}\n\t\t\t\t\\usepackage{amsfonts}\n\t\t\t\t\\usepackage{amssymb}\n\t\t\t\t\\usepackage{amsbsy}\n\t\t\t\t\\usepackage{mathrsfs}\n\t\t\t\t\\usepackage{upgreek}\n\t\t\t\t\\setlength{\\oddsidemargin}{-69pt}\n\t\t\t\t\\begin{document}\n$$X_{gr}^{ga} = (Ca/Ca + Mg + Fe)^{ga} .$$\n\\end{document}The accuracy and precision of this geothermometer are limited by largerelative errors in the experimental and natural-rock data and by the modest absolute variation inKD with temperature. Nevertheless, the geothermometer is shown to yield reasonable temperature estimates for a variety of natural samples.",
"genre": "article",
"id": "sg:pub.10.1007/bf01187140",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1026106",
"issn": [
"0010-7999",
"1432-0967"
],
"name": "Contributions to Mineralogy and Petrology",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "4",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "86"
}
],
"keywords": [
"partitioning of Fe",
"experimental data",
"garnet",
"aluminous orthopyroxene",
"orthopyroxene",
"Al2O3-SiO2",
"Al2O3\u2013SiO2 system",
"Fe-Mg",
"end-member phases",
"geothermometer",
"garnet peridotite",
"natural rock data",
"reasonable temperature estimates",
"temperature estimates",
"natural samples",
"experimental study",
"partitioning",
"Fe",
"Mg",
"range 5",
"kbar",
"CaO",
"system",
"error",
"data",
"cal/",
"reduction",
"volume data",
"phase",
"calibration",
"peridotites",
"accuracy",
"precision",
"temperature",
"effect of calcium",
"effect",
"interaction",
"interaction terms",
"terms",
"sites",
"molar volume data",
"estimates",
"variety",
"samples",
"study",
"calcium"
],
"name": "An experimental study of the partitioning of Fe and Mg between garnet and orthopyroxene",
"pagination": "359-373",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1013412604"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf01187140"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf01187140",
"https://app.dimensions.ai/details/publication/pub.1013412604"
],
"sdDataset": "articles",
"sdDatePublished": "2022-08-04T16:50",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_171.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/bf01187140"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01187140'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01187140'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01187140'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01187140'
This table displays all metadata directly associated to this object as RDF triples.
187 TRIPLES
21 PREDICATES
92 URIs
63 LITERALS
6 BLANK NODES