Amidoalkylation of 2- and 4-hydroxy-pyrimidines with N-(1,2,2,2-tetra-chloroethyl)amides of carboxylic acids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1994-10

AUTHORS

L. P. Prikazchikova, L. I. Rybchenko, S. V. Klyuchko, V. V. Pirozhenko, B. S. Drach

ABSTRACT

The reaction of 2- and 4-hydroxypyrimidines with N-(1,2,2,2-tetrachloroethyl)amides of carboxylic acids in the presence of sodium hydroxide or triethylamine leads to products of amidoalkylation a the N(1) and N(3) atoms respectively. In addition, 2-alkyl-4-hydroxy-pyrimidines give products of O- or C-amidoalkylation with the reagents indicated, evidently caused by steric factors and by kinetic and thermodynamic control. More... »

PAGES

1235-1239

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01184892

DOI

http://dx.doi.org/10.1007/bf01184892

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016560597


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "familyName": "Prikazchikova", 
        "givenName": "L. P.", 
        "id": "sg:person.011154717107.95", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011154717107.95"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Rybchenko", 
        "givenName": "L. I.", 
        "id": "sg:person.012510644357.54", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012510644357.54"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Klyuchko", 
        "givenName": "S. V.", 
        "id": "sg:person.015035075453.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015035075453.55"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Pirozhenko", 
        "givenName": "V. V.", 
        "id": "sg:person.012241771317.04", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012241771317.04"
        ], 
        "type": "Person"
      }, 
      {
        "familyName": "Drach", 
        "givenName": "B. S.", 
        "id": "sg:person.015654206317.39", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015654206317.39"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1994-10", 
    "datePublishedReg": "1994-10-01", 
    "description": "The reaction of 2- and 4-hydroxypyrimidines with N-(1,2,2,2-tetrachloroethyl)amides of carboxylic acids in the presence of sodium hydroxide or triethylamine leads to products of amidoalkylation a the N(1) and N(3) atoms respectively. In addition, 2-alkyl-4-hydroxy-pyrimidines give products of O- or C-amidoalkylation with the reagents indicated, evidently caused by steric factors and by kinetic and thermodynamic control.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf01184892", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1356886", 
        "issn": [
          "0009-3122", 
          "1573-8353"
        ], 
        "name": "Chemistry of Heterocyclic Compounds", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "10", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "30"
      }
    ], 
    "name": "Amidoalkylation of 2- and 4-hydroxy-pyrimidines with N-(1,2,2,2-tetra-chloroethyl)amides of carboxylic acids", 
    "pagination": "1235-1239", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "4ee7e4d2fbc7023e968d74e7219fa27008ee357987c62ed6cc99a4c271230872"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01184892"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1016560597"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01184892", 
      "https://app.dimensions.ai/details/publication/pub.1016560597"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T14:57", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8663_00000495.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/BF01184892"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01184892'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01184892'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01184892'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01184892'


 

This table displays all metadata directly associated to this object as RDF triples.

81 TRIPLES      20 PREDICATES      27 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01184892 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author Nf6d3efae3ae041bcabb2ed14f62c1913
4 schema:datePublished 1994-10
5 schema:datePublishedReg 1994-10-01
6 schema:description The reaction of 2- and 4-hydroxypyrimidines with N-(1,2,2,2-tetrachloroethyl)amides of carboxylic acids in the presence of sodium hydroxide or triethylamine leads to products of amidoalkylation a the N(1) and N(3) atoms respectively. In addition, 2-alkyl-4-hydroxy-pyrimidines give products of O- or C-amidoalkylation with the reagents indicated, evidently caused by steric factors and by kinetic and thermodynamic control.
7 schema:genre research_article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N3e8310d6e431437f83ea47645dc69873
11 N82f070477730475bb41040d1f4cbc750
12 sg:journal.1356886
13 schema:name Amidoalkylation of 2- and 4-hydroxy-pyrimidines with N-(1,2,2,2-tetra-chloroethyl)amides of carboxylic acids
14 schema:pagination 1235-1239
15 schema:productId N5807369ae0a549c592b4b9b35b710d07
16 N73427a1bb2b14ea4bd47c87c7e75e4a9
17 N8a5d1b4a8c9941e3b4c9eb73d2933a13
18 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016560597
19 https://doi.org/10.1007/bf01184892
20 schema:sdDatePublished 2019-04-10T14:57
21 schema:sdLicense https://scigraph.springernature.com/explorer/license/
22 schema:sdPublisher N699d7787b8304c70999a30ebc162b0ec
23 schema:url http://link.springer.com/10.1007/BF01184892
24 sgo:license sg:explorer/license/
25 sgo:sdDataset articles
26 rdf:type schema:ScholarlyArticle
27 N381243977a854cd4b96fc2cc4118c669 rdf:first sg:person.012241771317.04
28 rdf:rest N628925dd598a4a789072becfc6b211de
29 N3e8310d6e431437f83ea47645dc69873 schema:issueNumber 10
30 rdf:type schema:PublicationIssue
31 N5807369ae0a549c592b4b9b35b710d07 schema:name doi
32 schema:value 10.1007/bf01184892
33 rdf:type schema:PropertyValue
34 N628925dd598a4a789072becfc6b211de rdf:first sg:person.015654206317.39
35 rdf:rest rdf:nil
36 N699d7787b8304c70999a30ebc162b0ec schema:name Springer Nature - SN SciGraph project
37 rdf:type schema:Organization
38 N73427a1bb2b14ea4bd47c87c7e75e4a9 schema:name dimensions_id
39 schema:value pub.1016560597
40 rdf:type schema:PropertyValue
41 N82f070477730475bb41040d1f4cbc750 schema:volumeNumber 30
42 rdf:type schema:PublicationVolume
43 N8a5d1b4a8c9941e3b4c9eb73d2933a13 schema:name readcube_id
44 schema:value 4ee7e4d2fbc7023e968d74e7219fa27008ee357987c62ed6cc99a4c271230872
45 rdf:type schema:PropertyValue
46 Nbbf2318f764948b3b1c35fd4568df44c rdf:first sg:person.015035075453.55
47 rdf:rest N381243977a854cd4b96fc2cc4118c669
48 Ne3bf28da435f4c319fc5bde63abab512 rdf:first sg:person.012510644357.54
49 rdf:rest Nbbf2318f764948b3b1c35fd4568df44c
50 Nf6d3efae3ae041bcabb2ed14f62c1913 rdf:first sg:person.011154717107.95
51 rdf:rest Ne3bf28da435f4c319fc5bde63abab512
52 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
53 schema:name Chemical Sciences
54 rdf:type schema:DefinedTerm
55 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
56 schema:name Organic Chemistry
57 rdf:type schema:DefinedTerm
58 sg:journal.1356886 schema:issn 0009-3122
59 1573-8353
60 schema:name Chemistry of Heterocyclic Compounds
61 rdf:type schema:Periodical
62 sg:person.011154717107.95 schema:familyName Prikazchikova
63 schema:givenName L. P.
64 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011154717107.95
65 rdf:type schema:Person
66 sg:person.012241771317.04 schema:familyName Pirozhenko
67 schema:givenName V. V.
68 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012241771317.04
69 rdf:type schema:Person
70 sg:person.012510644357.54 schema:familyName Rybchenko
71 schema:givenName L. I.
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012510644357.54
73 rdf:type schema:Person
74 sg:person.015035075453.55 schema:familyName Klyuchko
75 schema:givenName S. V.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015035075453.55
77 rdf:type schema:Person
78 sg:person.015654206317.39 schema:familyName Drach
79 schema:givenName B. S.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015654206317.39
81 rdf:type schema:Person
 




Preview window. Press ESC to close (or click here)


...