Metallocomplex catalyst of the addition reaction of CCl4 to ethylene View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1990-12

AUTHORS

E. A. Lavrent'eva, V. I. Ponomarev, I. P. Lavrent'ev

ABSTRACT

The catalyst FeIIFe2IIICl8 (DMA)6-iron(2+)diiron(3+)octachlorohexakis(dimethylacetamide), was isolated from the media of the catalytic synthesis of 1,1,1,3-tetrachloropropane (C3), and characterized by physicochemical methods. A counter synthesis of the catalyst was carried out. The telomerization of ethylene with CCl4 proceeds with a 98% selectivity with respect to C3 in its presence, while the conversion of CCl4, reaches 55–60% after 4 h. A coordination-ionic mechanism of the reaction of CCl4 with C2H4 was proposed, which followed the concept of the donor-accpetor electron-transporting systems (the DAET systems), thus accounting for its high selectivity. More... »

PAGES

2534-2537

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01184533

DOI

http://dx.doi.org/10.1007/bf01184533

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033502690


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Structural Macrokinetics, Academy of Sciences of the USSR, Chernogolovka"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lavrent'eva", 
        "givenName": "E. A.", 
        "id": "sg:person.010243635477.92", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010243635477.92"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Structural Macrokinetics, Academy of Sciences of the USSR, Chernogolovka"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ponomarev", 
        "givenName": "V. I.", 
        "id": "sg:person.010535710631.46", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010535710631.46"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Structural Macrokinetics, Academy of Sciences of the USSR, Chernogolovka"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lavrent'ev", 
        "givenName": "I. P.", 
        "id": "sg:person.010763332055.72", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010763332055.72"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1039/jr9640002408", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005171768"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/nikkashi1898.74.11_2288", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033012499"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/nikkashi1898.72.8_1822", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044472270"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-1-4615-8825-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1109705383", 
          "https://doi.org/10.1007/978-1-4615-8825-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-1-4615-8825-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1109705383", 
          "https://doi.org/10.1007/978-1-4615-8825-2"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1990-12", 
    "datePublishedReg": "1990-12-01", 
    "description": "The catalyst FeIIFe2IIICl8 (DMA)6-iron(2+)diiron(3+)octachlorohexakis(dimethylacetamide), was isolated from the media of the catalytic synthesis of 1,1,1,3-tetrachloropropane (C3), and characterized by physicochemical methods. A counter synthesis of the catalyst was carried out. The telomerization of ethylene with CCl4 proceeds with a 98% selectivity with respect to C3 in its presence, while the conversion of CCl4, reaches 55\u201360% after 4 h. A coordination-ionic mechanism of the reaction of CCl4 with C2H4 was proposed, which followed the concept of the donor-accpetor electron-transporting systems (the DAET systems), thus accounting for its high selectivity.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf01184533", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "39"
      }
    ], 
    "name": "Metallocomplex catalyst of the addition reaction of CCl4 to ethylene", 
    "pagination": "2534-2537", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "9f9937cf83a854ee42d71349428abffdfd981708eecc995085c34d47832cfad7"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01184533"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1033502690"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01184533", 
      "https://app.dimensions.ai/details/publication/pub.1033502690"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:27", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000370_0000000370/records_46738_00000001.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF01184533"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01184533'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01184533'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01184533'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01184533'


 

This table displays all metadata directly associated to this object as RDF triples.

88 TRIPLES      21 PREDICATES      31 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01184533 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nb7b64ac3b8014511a5474abce6f9a675
4 schema:citation sg:pub.10.1007/978-1-4615-8825-2
5 https://doi.org/10.1039/jr9640002408
6 https://doi.org/10.1246/nikkashi1898.72.8_1822
7 https://doi.org/10.1246/nikkashi1898.74.11_2288
8 schema:datePublished 1990-12
9 schema:datePublishedReg 1990-12-01
10 schema:description The catalyst FeIIFe2IIICl8 (DMA)6-iron(2+)diiron(3+)octachlorohexakis(dimethylacetamide), was isolated from the media of the catalytic synthesis of 1,1,1,3-tetrachloropropane (C3), and characterized by physicochemical methods. A counter synthesis of the catalyst was carried out. The telomerization of ethylene with CCl4 proceeds with a 98% selectivity with respect to C3 in its presence, while the conversion of CCl4, reaches 55–60% after 4 h. A coordination-ionic mechanism of the reaction of CCl4 with C2H4 was proposed, which followed the concept of the donor-accpetor electron-transporting systems (the DAET systems), thus accounting for its high selectivity.
11 schema:genre research_article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N62bb52588f544d4b93126378e7c84127
15 Nf989face2813464db48d7863ae03a873
16 sg:journal.1022309
17 schema:name Metallocomplex catalyst of the addition reaction of CCl4 to ethylene
18 schema:pagination 2534-2537
19 schema:productId N92c36fdb086448fd9b9014c624b06f1f
20 Nd61032ac0eb244febfc68def807c7e53
21 Ndd654ea6509249119c531b516d6f33a4
22 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033502690
23 https://doi.org/10.1007/bf01184533
24 schema:sdDatePublished 2019-04-11T13:27
25 schema:sdLicense https://scigraph.springernature.com/explorer/license/
26 schema:sdPublisher Nba494dfc692b4e7db948e3d116050eac
27 schema:url http://link.springer.com/10.1007%2FBF01184533
28 sgo:license sg:explorer/license/
29 sgo:sdDataset articles
30 rdf:type schema:ScholarlyArticle
31 N3c7ce1eb3bb24fd6a7428cb260783013 rdf:first sg:person.010763332055.72
32 rdf:rest rdf:nil
33 N62bb52588f544d4b93126378e7c84127 schema:issueNumber 12
34 rdf:type schema:PublicationIssue
35 N92c36fdb086448fd9b9014c624b06f1f schema:name doi
36 schema:value 10.1007/bf01184533
37 rdf:type schema:PropertyValue
38 Nb7b64ac3b8014511a5474abce6f9a675 rdf:first sg:person.010243635477.92
39 rdf:rest Nbd7bfe2d90ca4f899abb6c03fafae4de
40 Nba494dfc692b4e7db948e3d116050eac schema:name Springer Nature - SN SciGraph project
41 rdf:type schema:Organization
42 Nbd7bfe2d90ca4f899abb6c03fafae4de rdf:first sg:person.010535710631.46
43 rdf:rest N3c7ce1eb3bb24fd6a7428cb260783013
44 Nd61032ac0eb244febfc68def807c7e53 schema:name readcube_id
45 schema:value 9f9937cf83a854ee42d71349428abffdfd981708eecc995085c34d47832cfad7
46 rdf:type schema:PropertyValue
47 Ndd654ea6509249119c531b516d6f33a4 schema:name dimensions_id
48 schema:value pub.1033502690
49 rdf:type schema:PropertyValue
50 Nf989face2813464db48d7863ae03a873 schema:volumeNumber 39
51 rdf:type schema:PublicationVolume
52 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
53 schema:name Chemical Sciences
54 rdf:type schema:DefinedTerm
55 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
56 schema:name Physical Chemistry (incl. Structural)
57 rdf:type schema:DefinedTerm
58 sg:journal.1022309 schema:issn 1066-5285
59 1573-9171
60 schema:name Russian Chemical Bulletin
61 rdf:type schema:Periodical
62 sg:person.010243635477.92 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
63 schema:familyName Lavrent'eva
64 schema:givenName E. A.
65 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010243635477.92
66 rdf:type schema:Person
67 sg:person.010535710631.46 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
68 schema:familyName Ponomarev
69 schema:givenName V. I.
70 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010535710631.46
71 rdf:type schema:Person
72 sg:person.010763332055.72 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
73 schema:familyName Lavrent'ev
74 schema:givenName I. P.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010763332055.72
76 rdf:type schema:Person
77 sg:pub.10.1007/978-1-4615-8825-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1109705383
78 https://doi.org/10.1007/978-1-4615-8825-2
79 rdf:type schema:CreativeWork
80 https://doi.org/10.1039/jr9640002408 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005171768
81 rdf:type schema:CreativeWork
82 https://doi.org/10.1246/nikkashi1898.72.8_1822 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044472270
83 rdf:type schema:CreativeWork
84 https://doi.org/10.1246/nikkashi1898.74.11_2288 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033012499
85 rdf:type schema:CreativeWork
86 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
87 schema:name Institute of Structural Macrokinetics, Academy of Sciences of the USSR, Chernogolovka
88 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...