Intramolecular rearrangements of cyclooctadienerhodium(I) fragments supported on a vanadium oxide cluster as evidenced by dynamic17O NMR spectroscopy View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1994-12

AUTHORS

Masaaki Abe, Kiyoshi Isobe, Katsuhiko Kida, Akira Nagasawa, Atsushi Yagasaki

ABSTRACT

Variable-temperature17O NMR together with51V and103Rh NMR studies on newly prepared vanadium oxide-supported organorhodium(I) fragment(s), [(RhCOD)n(V4O12)](4−n)− (n = 1, 2; COD =η4-1,5-cyclooctadiene) indicate that intramolecular rearrangements of RhCOD fragment(s) on a vanadium oxide surface occur in solution.

PAGES

565-571

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01171386

DOI

http://dx.doi.org/10.1007/bf01171386

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012298848


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