Crystal structure of form 1, magnetic properties and polymorphism of bis (NN-di-(n-propyl)dithiocarbamato iron (III) iodide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1988-02

AUTHORS

Bijan Etemadi Abdol Abadi, Rex A. Palmer, Brian W. Fitzsimmons

ABSTRACT

The crystal structure of bis (NN-di(n-propyl)dithiocarbamato iron(III) iodide, FeIII(S2CN6H14)2I, has been determined by the heavy-atom method and refined toR=0.055 for 3487 reflections withI(hkl)>3σI(hkl). The crystals are triclinic,C¯1,Z=8,a=27.644(6),b=19.186(4),c=8.694(2) Å,α=87.79(1),β=88.72(1), γ=101.87(2)°. The I-Fe bond lengths are different in the two moleculesA andB in the asymmetric unit, having values of 2.642 Å (2.655) and 2.612 Å (2.634) respectively (libration-corrected values given in parentheses). The measured effective magnetic momentμeff≈3.89 BM, independent of temperature (93-353K), suggests a spinS of 3/2 with three unpaired electrons for FeIII. More... »

PAGES

35-53

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01171023

DOI

http://dx.doi.org/10.1007/bf01171023

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018411931


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