Heterochain polyamides Communication 4. Investigation of kinetics of formation of mixed polyamides from salts of hexamethylenediamine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1957-09

AUTHORS

V. M. Kharitonov, T. M. Frunze, V. V. Korshak

ABSTRACT

It was established that the first stages of polycondensation of two salts of hexamethylenediamine involve formation of polyamides of the salt of the more active adipic acid; only in the later stages of the reaction is an equilibrium established at which the compositions of the original reaction mixture and of the polyamide formed are identical.It was shown that in processes of polycondensation the composition of the polymers formed in the final stages of the process is governed by the ratio between the starting substances and not by the kinetics of the individual stages of the process. More... »

PAGES

1165-1167

Journal

TITLE

Russian Chemical Bulletin

ISSUE

9

VOLUME

6

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01169402

DOI

http://dx.doi.org/10.1007/bf01169402

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030371116


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Artificial Fibers Research Institute, USSR", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Institute of Heteroorganfc Compounds of the Academy of Sciences, USSR", 
            "Artificial Fibers Research Institute, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kharitonov", 
        "givenName": "V. M.", 
        "id": "sg:person.013013127543.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013013127543.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Artificial Fibers Research Institute, USSR", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Institute of Heteroorganfc Compounds of the Academy of Sciences, USSR", 
            "Artificial Fibers Research Institute, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Frunze", 
        "givenName": "T. M.", 
        "id": "sg:person.012430016053.71", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012430016053.71"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Artificial Fibers Research Institute, USSR", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Institute of Heteroorganfc Compounds of the Academy of Sciences, USSR", 
            "Artificial Fibers Research Institute, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Korshak", 
        "givenName": "V. V.", 
        "id": "sg:person.07530254221.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07530254221.06"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf01171792", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029794673", 
          "https://doi.org/10.1007/bf01171792"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1957-09", 
    "datePublishedReg": "1957-09-01", 
    "description": "It was established that the first stages of polycondensation of two salts of hexamethylenediamine involve formation of polyamides of the salt of the more active adipic acid; only in the later stages of the reaction is an equilibrium established at which the compositions of the original reaction mixture and of the polyamide formed are identical.It was shown that in processes of polycondensation the composition of the polymers formed in the final stages of the process is governed by the ratio between the starting substances and not by the kinetics of the individual stages of the process.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf01169402", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1063-5211", 
          "1026-3500"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "9", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "6"
      }
    ], 
    "keywords": [
      "formation of polyamides", 
      "original reaction mixture", 
      "process of polycondensation", 
      "investigation of kinetics", 
      "polycondensation", 
      "salt", 
      "hexamethylenediamine", 
      "polyamides", 
      "adipic acid", 
      "reaction mixture", 
      "Communication 4", 
      "mixed polyamides", 
      "formation", 
      "reaction", 
      "composition", 
      "polymers", 
      "kinetics", 
      "heterochains", 
      "acid", 
      "mixture", 
      "equilibrium", 
      "process", 
      "substances", 
      "first stage", 
      "ratio", 
      "individual stages", 
      "investigation", 
      "final stage", 
      "stage", 
      "later stages", 
      "salts of hexamethylenediamine", 
      "active adipic acid"
    ], 
    "name": "Heterochain polyamides Communication 4. Investigation of kinetics of formation of mixed polyamides from salts of hexamethylenediamine", 
    "pagination": "1165-1167", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1030371116"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01169402"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01169402", 
      "https://app.dimensions.ai/details/publication/pub.1030371116"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-12-01T19:34", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211201/entities/gbq_results/article/article_66.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf01169402"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01169402'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01169402'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01169402'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01169402'


 

This table displays all metadata directly associated to this object as RDF triples.

105 TRIPLES      22 PREDICATES      58 URIs      50 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01169402 schema:about anzsrc-for:03
2 schema:author Nbb28e992e6054a5aa138ac0489bec226
3 schema:citation sg:pub.10.1007/bf01171792
4 schema:datePublished 1957-09
5 schema:datePublishedReg 1957-09-01
6 schema:description It was established that the first stages of polycondensation of two salts of hexamethylenediamine involve formation of polyamides of the salt of the more active adipic acid; only in the later stages of the reaction is an equilibrium established at which the compositions of the original reaction mixture and of the polyamide formed are identical.It was shown that in processes of polycondensation the composition of the polymers formed in the final stages of the process is governed by the ratio between the starting substances and not by the kinetics of the individual stages of the process.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N52c7b747dab24a85b3bd5894339f41d5
11 Nb5a4cfd4ac18485abfd2618e1b7ff5f1
12 sg:journal.1022309
13 schema:keywords Communication 4
14 acid
15 active adipic acid
16 adipic acid
17 composition
18 equilibrium
19 final stage
20 first stage
21 formation
22 formation of polyamides
23 heterochains
24 hexamethylenediamine
25 individual stages
26 investigation
27 investigation of kinetics
28 kinetics
29 later stages
30 mixed polyamides
31 mixture
32 original reaction mixture
33 polyamides
34 polycondensation
35 polymers
36 process
37 process of polycondensation
38 ratio
39 reaction
40 reaction mixture
41 salt
42 salts of hexamethylenediamine
43 stage
44 substances
45 schema:name Heterochain polyamides Communication 4. Investigation of kinetics of formation of mixed polyamides from salts of hexamethylenediamine
46 schema:pagination 1165-1167
47 schema:productId N9e8ba66d3b9f4de1bef852cb1452683d
48 Nae7d36f21db24b26ab1e9b3c651d8380
49 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030371116
50 https://doi.org/10.1007/bf01169402
51 schema:sdDatePublished 2021-12-01T19:34
52 schema:sdLicense https://scigraph.springernature.com/explorer/license/
53 schema:sdPublisher N53e749c48d57437ca9f9b420c38429bf
54 schema:url https://doi.org/10.1007/bf01169402
55 sgo:license sg:explorer/license/
56 sgo:sdDataset articles
57 rdf:type schema:ScholarlyArticle
58 N52c7b747dab24a85b3bd5894339f41d5 schema:volumeNumber 6
59 rdf:type schema:PublicationVolume
60 N53e749c48d57437ca9f9b420c38429bf schema:name Springer Nature - SN SciGraph project
61 rdf:type schema:Organization
62 N9e8ba66d3b9f4de1bef852cb1452683d schema:name doi
63 schema:value 10.1007/bf01169402
64 rdf:type schema:PropertyValue
65 Nae7d36f21db24b26ab1e9b3c651d8380 schema:name dimensions_id
66 schema:value pub.1030371116
67 rdf:type schema:PropertyValue
68 Nb5a4cfd4ac18485abfd2618e1b7ff5f1 schema:issueNumber 9
69 rdf:type schema:PublicationIssue
70 Nbb28e992e6054a5aa138ac0489bec226 rdf:first sg:person.013013127543.93
71 rdf:rest Ne092bbec73e84e738064a890c87b2345
72 Ne092bbec73e84e738064a890c87b2345 rdf:first sg:person.012430016053.71
73 rdf:rest Nf8a26673644f4e6f90e547ca9c26aab3
74 Nf8a26673644f4e6f90e547ca9c26aab3 rdf:first sg:person.07530254221.06
75 rdf:rest rdf:nil
76 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
77 schema:name Chemical Sciences
78 rdf:type schema:DefinedTerm
79 sg:journal.1022309 schema:issn 1026-3500
80 1063-5211
81 schema:name Russian Chemical Bulletin
82 schema:publisher Springer Nature
83 rdf:type schema:Periodical
84 sg:person.012430016053.71 schema:affiliation grid-institutes:None
85 schema:familyName Frunze
86 schema:givenName T. M.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012430016053.71
88 rdf:type schema:Person
89 sg:person.013013127543.93 schema:affiliation grid-institutes:None
90 schema:familyName Kharitonov
91 schema:givenName V. M.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013013127543.93
93 rdf:type schema:Person
94 sg:person.07530254221.06 schema:affiliation grid-institutes:None
95 schema:familyName Korshak
96 schema:givenName V. V.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07530254221.06
98 rdf:type schema:Person
99 sg:pub.10.1007/bf01171792 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029794673
100 https://doi.org/10.1007/bf01171792
101 rdf:type schema:CreativeWork
102 grid-institutes:None schema:alternateName Artificial Fibers Research Institute, USSR
103 schema:name Artificial Fibers Research Institute, USSR
104 Institute of Heteroorganfc Compounds of the Academy of Sciences, USSR
105 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...