Chiral complex-forming and trans-phase transfer agents. 7. Complex forming properties of podands based on 1,4∶3,6-dianhydro-D-mannitol View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1989-11

AUTHORS

M. I. Struchkova, E. A. Él'perina, L. M. Suslova, R. I. Abylgaziev, É. P. Serebryakov

ABSTRACT

In their complexation with alkali metal picrates, podands prepared from l,4∶3,6-dianhydro-D-mannitol display affinity to Na and Li cations but virtually do not bind K ions. It was shown using the1H NMR method that these podands form complexes with α-phenylethylammonium perchlorate, the composition and strength of which depends on the nature of the side-chains of the podand. The podands studied are not capable of participating in the enantioselective transfer of the chiral substrate from the aqueous phase into chloroform. More... »

PAGES

2294-2297

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01168072

DOI

http://dx.doi.org/10.1007/bf01168072

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1001571199


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