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    "description": "It was found using the1H and13C NMR methods that (2R, 12R)-disubstituted derivatives of 18-crown-6-ether containing the residues of l,3\u22362,4-di-O-ethylidene(Ia) and 1,3\u22362,4-di-O-benzylidene-D-sorbitol (IIa) as substituents and 1,4\u22363,6dianhydro-D-mannito-18-crown-6 (III) form stable 1\u22361 complexes with \u03b1-phenylethylammonium, O-methyl-\u03b1-phenylglycinium, O-methylalaninium, O-methyl-\u03b1-phenylalaninium, O-methylglycinium hexafluorophosphates, and display an enantiodifferentiating ability with respect to racemates of these salts. In the extraction of the chiral ammonium salts, coronand (Ia) exhibits a low (DCE 1.091.10) enantioselectivity with respect to (R)-enantiomers of \u03b1-phenylethyl ammonium and O-methyl-\u03b1-phenylglycinium hexafluorophosphates, while coronand (IIa) displays enantioselectivity with respect to (S)-enantiomer of the latter (DCE 0.82). Coronand (III) does not display enantioselectivity in complexes with racemates of these salts.", 
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