Ontology type: schema:ScholarlyArticle
1983-06
AUTHORSA. Zschunke, C. Mügge, M. Scheer, K. Jurkschat, A. Tzschach
ABSTRACTFrom the1H,13C, and119Sn NMR spectra at different temperatures, it is concluded that the 5-alkyl-5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octanes dimerize in nonpolar solvents. The barrier for dimerization is lower (ΔG‡=40 kJ/mol) than the barrier for simultaneous dissociation-inversion (ΔG‡=70 kJ/mol). The dimers studied are sterically uniform.
PAGES201-210
http://scigraph.springernature.com/pub.10.1007/bf01161514
DOIhttp://dx.doi.org/10.1007/bf01161514
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1043747323
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR",
"id": "http://www.grid.ac/institutes/None",
"name": [
"Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR"
],
"type": "Organization"
},
"familyName": "Zschunke",
"givenName": "A.",
"id": "sg:person.015211401556.33",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015211401556.33"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR",
"id": "http://www.grid.ac/institutes/None",
"name": [
"Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR"
],
"type": "Organization"
},
"familyName": "M\u00fcgge",
"givenName": "C.",
"id": "sg:person.0651156745.18",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0651156745.18"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR",
"id": "http://www.grid.ac/institutes/None",
"name": [
"Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR"
],
"type": "Organization"
},
"familyName": "Scheer",
"givenName": "M.",
"id": "sg:person.014142507643.27",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014142507643.27"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR",
"id": "http://www.grid.ac/institutes/None",
"name": [
"Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR"
],
"type": "Organization"
},
"familyName": "Jurkschat",
"givenName": "K.",
"id": "sg:person.01203215500.84",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01203215500.84"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR",
"id": "http://www.grid.ac/institutes/None",
"name": [
"Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR"
],
"type": "Organization"
},
"familyName": "Tzschach",
"givenName": "A.",
"id": "sg:person.010466307713.53",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010466307713.53"
],
"type": "Person"
}
],
"datePublished": "1983-06",
"datePublishedReg": "1983-06-01",
"description": "From the1H,13C, and119Sn NMR spectra at different temperatures, it is concluded that the 5-alkyl-5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octanes dimerize in nonpolar solvents. The barrier for dimerization is lower (\u0394G\u2021=40 kJ/mol) than the barrier for simultaneous dissociation-inversion (\u0394G\u2021=70 kJ/mol). The dimers studied are sterically uniform.",
"genre": "article",
"id": "sg:pub.10.1007/bf01161514",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1093566",
"issn": [
"1074-1542",
"1572-8854"
],
"name": "Journal of Chemical Crystallography",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "3",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "13"
}
],
"keywords": [
"NMR spectra",
"nonpolar solvents",
"different temperatures",
"solvent",
"dimers",
"dimerize",
"dimerization",
"spectra",
"structure",
"temperature",
"barriers"
],
"name": "The structure of 5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octane",
"pagination": "201-210",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1043747323"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf01161514"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf01161514",
"https://app.dimensions.ai/details/publication/pub.1043747323"
],
"sdDataset": "articles",
"sdDatePublished": "2022-08-04T16:50",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_171.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/bf01161514"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01161514'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01161514'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01161514'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01161514'
This table displays all metadata directly associated to this object as RDF triples.
96 TRIPLES
20 PREDICATES
36 URIs
28 LITERALS
6 BLANK NODES