The structure of 5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octane View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1983-06

AUTHORS

A. Zschunke, C. Mügge, M. Scheer, K. Jurkschat, A. Tzschach

ABSTRACT

From the1H,13C, and119Sn NMR spectra at different temperatures, it is concluded that the 5-alkyl-5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octanes dimerize in nonpolar solvents. The barrier for dimerization is lower (ΔG‡=40 kJ/mol) than the barrier for simultaneous dissociation-inversion (ΔG‡=70 kJ/mol). The dimers studied are sterically uniform.

PAGES

201-210

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01161514

DOI

http://dx.doi.org/10.1007/bf01161514

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043747323


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zschunke", 
        "givenName": "A.", 
        "id": "sg:person.015211401556.33", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015211401556.33"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "M\u00fcgge", 
        "givenName": "C.", 
        "id": "sg:person.0651156745.18", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0651156745.18"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Scheer", 
        "givenName": "M.", 
        "id": "sg:person.014142507643.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014142507643.27"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Jurkschat", 
        "givenName": "K.", 
        "id": "sg:person.01203215500.84", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01203215500.84"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tzschach", 
        "givenName": "A.", 
        "id": "sg:person.010466307713.53", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010466307713.53"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1983-06", 
    "datePublishedReg": "1983-06-01", 
    "description": "From the1H,13C, and119Sn NMR spectra at different temperatures, it is concluded that the 5-alkyl-5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octanes dimerize in nonpolar solvents. The barrier for dimerization is lower (\u0394G\u2021=40 kJ/mol) than the barrier for simultaneous dissociation-inversion (\u0394G\u2021=70 kJ/mol). The dimers studied are sterically uniform.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf01161514", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1093566", 
        "issn": [
          "1074-1542", 
          "1572-8854"
        ], 
        "name": "Journal of Chemical Crystallography", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "13"
      }
    ], 
    "keywords": [
      "NMR spectra", 
      "nonpolar solvents", 
      "different temperatures", 
      "solvent", 
      "dimers", 
      "dimerize", 
      "dimerization", 
      "spectra", 
      "structure", 
      "temperature", 
      "barriers"
    ], 
    "name": "The structure of 5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octane", 
    "pagination": "201-210", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1043747323"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf01161514"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf01161514", 
      "https://app.dimensions.ai/details/publication/pub.1043747323"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-08-04T16:50", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_171.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf01161514"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01161514'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01161514'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01161514'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01161514'


 

This table displays all metadata directly associated to this object as RDF triples.

96 TRIPLES      20 PREDICATES      36 URIs      28 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf01161514 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N393ae99ea18e4e94b52dcab9866fb6d9
4 schema:datePublished 1983-06
5 schema:datePublishedReg 1983-06-01
6 schema:description From the1H,13C, and119Sn NMR spectra at different temperatures, it is concluded that the 5-alkyl-5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octanes dimerize in nonpolar solvents. The barrier for dimerization is lower (ΔG‡=40 kJ/mol) than the barrier for simultaneous dissociation-inversion (ΔG‡=70 kJ/mol). The dimers studied are sterically uniform.
7 schema:genre article
8 schema:isAccessibleForFree false
9 schema:isPartOf N7f02db658b4f4691aaadbbbf36fef8b5
10 Nc9701eb2a4a54b8cbd9c40b3e387e2b7
11 sg:journal.1093566
12 schema:keywords NMR spectra
13 barriers
14 different temperatures
15 dimerization
16 dimerize
17 dimers
18 nonpolar solvents
19 solvent
20 spectra
21 structure
22 temperature
23 schema:name The structure of 5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octane
24 schema:pagination 201-210
25 schema:productId N4657ced1d8044c569e87904bee1b01ec
26 Nad8b262630cc4b548e2eda050333dd4f
27 schema:sameAs https://app.dimensions.ai/details/publication/pub.1043747323
28 https://doi.org/10.1007/bf01161514
29 schema:sdDatePublished 2022-08-04T16:50
30 schema:sdLicense https://scigraph.springernature.com/explorer/license/
31 schema:sdPublisher Necb227da14cf4e78a0d6b6e0da8d00e6
32 schema:url https://doi.org/10.1007/bf01161514
33 sgo:license sg:explorer/license/
34 sgo:sdDataset articles
35 rdf:type schema:ScholarlyArticle
36 N393ae99ea18e4e94b52dcab9866fb6d9 rdf:first sg:person.015211401556.33
37 rdf:rest Nf6b353f8601a458489867b0e1eeed8a2
38 N4657ced1d8044c569e87904bee1b01ec schema:name doi
39 schema:value 10.1007/bf01161514
40 rdf:type schema:PropertyValue
41 N50deceb1a2d444d5af8e2c53e7c93e72 rdf:first sg:person.014142507643.27
42 rdf:rest Ne7b9fc95f7e3417d9e3ee55159489aad
43 N6d34f5fc1a11467d9c873a9f9884c77c rdf:first sg:person.010466307713.53
44 rdf:rest rdf:nil
45 N7f02db658b4f4691aaadbbbf36fef8b5 schema:issueNumber 3
46 rdf:type schema:PublicationIssue
47 Nad8b262630cc4b548e2eda050333dd4f schema:name dimensions_id
48 schema:value pub.1043747323
49 rdf:type schema:PropertyValue
50 Nc9701eb2a4a54b8cbd9c40b3e387e2b7 schema:volumeNumber 13
51 rdf:type schema:PublicationVolume
52 Ne7b9fc95f7e3417d9e3ee55159489aad rdf:first sg:person.01203215500.84
53 rdf:rest N6d34f5fc1a11467d9c873a9f9884c77c
54 Necb227da14cf4e78a0d6b6e0da8d00e6 schema:name Springer Nature - SN SciGraph project
55 rdf:type schema:Organization
56 Nf6b353f8601a458489867b0e1eeed8a2 rdf:first sg:person.0651156745.18
57 rdf:rest N50deceb1a2d444d5af8e2c53e7c93e72
58 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
59 schema:name Chemical Sciences
60 rdf:type schema:DefinedTerm
61 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
62 schema:name Physical Chemistry (incl. Structural)
63 rdf:type schema:DefinedTerm
64 sg:journal.1093566 schema:issn 1074-1542
65 1572-8854
66 schema:name Journal of Chemical Crystallography
67 schema:publisher Springer Nature
68 rdf:type schema:Periodical
69 sg:person.010466307713.53 schema:affiliation grid-institutes:None
70 schema:familyName Tzschach
71 schema:givenName A.
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010466307713.53
73 rdf:type schema:Person
74 sg:person.01203215500.84 schema:affiliation grid-institutes:None
75 schema:familyName Jurkschat
76 schema:givenName K.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01203215500.84
78 rdf:type schema:Person
79 sg:person.014142507643.27 schema:affiliation grid-institutes:None
80 schema:familyName Scheer
81 schema:givenName M.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014142507643.27
83 rdf:type schema:Person
84 sg:person.015211401556.33 schema:affiliation grid-institutes:None
85 schema:familyName Zschunke
86 schema:givenName A.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015211401556.33
88 rdf:type schema:Person
89 sg:person.0651156745.18 schema:affiliation grid-institutes:None
90 schema:familyName Mügge
91 schema:givenName C.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0651156745.18
93 rdf:type schema:Person
94 grid-institutes:None schema:alternateName Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR
95 schema:name Department of Chemistry, Martin Luther University, Halle-Wittenberg, GDR
96 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...