The structure of 5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octane View Full Text


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Article Info

DATE

1983-06

AUTHORS

A. Zschunke, C. Mügge, M. Scheer, K. Jurkschat, A. Tzschach

ABSTRACT

From the1H,13C, and119Sn NMR spectra at different temperatures, it is concluded that the 5-alkyl-5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octanes dimerize in nonpolar solvents. The barrier for dimerization is lower (ΔG‡=40 kJ/mol) than the barrier for simultaneous dissociation-inversion (ΔG‡=70 kJ/mol). The dimers studied are sterically uniform.

PAGES

201-210

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01161514

DOI

http://dx.doi.org/10.1007/bf01161514

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043747323


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