Reaction of 6,8-di-tert-butyl-1-oxaspiro[4.5]deca-5,8-diene-2,7-dione with amines View Full Text


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Article Info

DATE

1985-05

AUTHORS

A. A. Volod'kin, V. V. Ershov, R. D. Malysheva

ABSTRACT

ConclusionsThe reaction of 6,8-di-tert-butyl-1-oxaspiro[4.5]deca-5,8-diene-2,7-dione with ammonia or amines gives 4-(β-carboxyethyl)-4-(N,N-dialkylamino)-2,6-di-tert-butyl-2,5-cyclo-hexadienones (quinamines).The thermal decomposition of these quinamines leads to the release of an amine and formation of 6,8-di-tert-butyl-1-oxaspiro [4.5 ]deca-5,8-diene-2,7-dione.The action of acid reagents on 4-(β-carboxyethyl)-4-(N,N-dialkylamino)-2,6-di-tert-butyl-2,5-cyclohexadienones splits off an amine to form phenolic compounds

PAGES

1086-1088

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01142808

DOI

http://dx.doi.org/10.1007/bf01142808

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017263489


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